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Hydrogen is widely considered a promising fuel for future transportation applications for both, internal combustion engines and fuel cells. Due to their advanced stage of development and immediate availability hydrogen combustion engines could act as a bridging technology towards a wide-spread hydrogen infrastructure. Although fuel cell vehicles are expected to surpass hydrogen combustion engine vehicles in terms of efficiency, the difference in efficiency might not be as significant as widely anticipated [1]. Hydrogen combustion engines have been shown capable of achieving efficiencies of up to 45 % [2]. One of the remaining challenges is the reduction of nitric oxide emissions while achieving peak engine efficiencies. This paper summarizes research work performed on a single-cylinder hydrogen direct injection engine at Argonne National Laboratory.

Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

It is widely understood that cold ambient temperatures increase vehicle fuel consumption due to heat transfer losses, increased friction (increased viscosity lubricants), and enrichment strategies (accelerated catalyst heating). However, relatively little effort has been dedicated to thoroughly quantifying these impacts across a large set of real world drive cycle data and ambient conditions. This work leverages experimental dynamometer vehicle data collected under various drive cycles and ambient conditions to develop a simplified modeling framework for quantifying thermal effects on vehicle energy consumption. These models are applied over a wide array of real-world usage profiles and typical meteorological data to develop estimates of in-use fuel economy. The paper concludes with a discussion of how this integrated testing/modeling approach may be applied to quantify real-world, off-cycle fuel economy benefits of various technologies.

In the next years, the upcoming emission legislations are expected to introduce further restrictions on the admittable level of pollutants from vehicles measured on homologation cycles and real drive tests. In this context, the strict control of pollutant emissions at the cold start will become a crucial point to comply with the new regulation standards. This will necessarily require the implementation of novel strategies to speed-up the light-off of the reactions occurring in the after-treatment system, since the cold start conditions are the most critical one for cumulative emissions. Among the different possible technological solutions, this paper focuses on the evaluation of the potential of a burner system, which is activated before the engine start. The hypothetical burner exploits the lean combustion of an air-gasoline mixture to generate a high temperature gas stream which is directed to the catalyst section promoting a fast heating of the substrate.

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

Striving for sustainable transportation solutions, hydrogen is often identified as a promising energy carrier and internal combustion engines are seen as a cost effective consumer of hydrogen to facilitate the development of a large-scale hydrogen infrastructure. Driven by efficiency and emissions targets defined by the U.S. Department of Energy, a research team at Argonne National Laboratory has worked on optimizing a spark-ignited direct injection engine for hydrogen. Using direct injection improves volumetric efficiency and provides the opportunity to properly stratify the fuel-air mixture in-cylinder. Collaborative 3D-CFD and experimental efforts have focused on optimizing the mixture stratification and have demonstrated the potential for high engine efficiency with low NOx emissions. Performance of the hydrogen engine is evaluated in this paper over a speed range from 1000 to 3000 RPM and a load range from 1.7 to 14.3 bar BMEP.

Energy security and climate change are two of the main drivers for development of sustainable and renewable transportation solutions. Entities around the globe have been working on strategic plans to reduce energy consumption and curb greenhouse gas emissions. In this context hydrogen is frequently mentioned as the fuel and energy carrier of the future. The U.S. Department of Energy's (DOE's) FreedomCAR and Vehicle Technologies (FCVT) Program has identified hydrogen-powered internal combustion engine (ICE) vehicles as an important mid-term technology on the path to a large-scale hydrogen economy. DOE has set challenging goals for hydrogen internal combustion engines including 45% peak brake thermal efficiency (BTE). This paper summarizes recent research engine test results employing hydrogen direct injection with different injection strategies.

As an energy carrier, hydrogen has the potential to deliver clean and renewable power for transportation. When powered by hydrogen, internal combustion engine technology may offer an attractive alternative to enable the transition to a hydrogen economy. Port-injected hydrogen engines generate extremely low emissions and offer high engine efficiencies if operated in a lean combustion strategy. This paper presents experimental data for different constant air/fuel ratio engine combustion strategies and introduces variable air/fuel ratio strategies for engine control. The paper also discusses the shift strategy to optimize fuel economy and contrasts the different engine control strategies in the conventional vehicle environment. The different strategies are evaluated on the urban driving cycle, then engine behaviors are explained and fuel economy is estimated. Finally, the paper projects the potential of hybridization and discusses trends in powertrain cycle efficiencies.

Hydrogen is considered one of the most promising future energy carriers and transportation fuels. Because of the lack of a hydrogen infrastructure and refueling stations, widespread introduction of vehicles powered by pure hydrogen is not likely in the near future. Blending hydrogen with methane could be one solution. Such blends take advantage of the unique combustion properties of hydrogen and, at the same time, reduce the demand for pure hydrogen. In this paper, the authors analyze the combustion properties of hydrogen/methane blends (5% and 20% methane [by volume] in hydrogen equal to 30% and 65% methane [by mass] in hydrogen) and compare them to those of pure hydrogen as a reference. The study confirms that only minor adjustments in spark timing and injection duration are necessary for an engine calibrated and tuned for operation on pure hydrogen to run on hydrogen/methane blends.

In order to achieve the targets for hydrogen engines set by the U.S. Department of Energy (DOE) - a brake thermal efficiency of 45% and nitrogen oxide (NOx) emissions below 0.07 g/mi - while maintaining the same power density as comparable gasoline engines, researchers need to investigate advanced mixture formation and combustion strategies for hydrogen internal combustion engines. Hydrogen direct injection is a very promising approach to meeting DOE targets; however, there are several challenges to be overcome in order to establish this technology as a viable pathway toward a sustainable hydrogen infrastructure. This paper describes the use of endoscopic imaging as a diagnostic tool that allows further insight into the processes that occur during hydrogen combustion. It also addresses recent progress in the development of advanced direct-injected hydrogen internal combustion engine concepts.

The favorable physical properties of hydrogen (H2) make it an excellent alternative fuel for internal combustion (IC) engines and hence it is widely regarded as the energy carrier of the future. Hydrogen direct injection provides multiple degrees of freedom for engine optimization and influencing the in-cylinder combustion processes. This paper compares the results in the mixture formation and combustion behavior of a hydrogen direct-injected single-cylinder research engine using two different injector locations as well as various injector nozzle designs. For this study the research engine was equipped with a specially designed cylinder head that allows accommodating a hydrogen injector in a side location between the intake valves as well as in the center location adjacent to the spark plug.

Fuel cell vehicles are undergoing extensive research and development because of their potential for high efficiency and low emissions. Because fuel cell vehicles remain expensive and there is limited demand for hydrogen at present, very few fueling stations are being built. To try to accelerate the development of a hydrogen economy, some original equipment manufacturers in the automotive industry have been working on a hydrogen-fueled internal combustion engine (ICE) as an intermediate step. This paper compares the fuel economy potential of hydrogen powertrains to conventional gasoline vehicles. Several timeframes are considered: 2010, 2015, 2030, and 2045. To address the technology status uncertainty, a triangular distribution approach was implemented for each component technology. The fuel consumption and cost of five powertrain configurations will be discussed and compared with the conventional counterpart.

Fuel cell vehicles are the subject of extensive research and development because of their potential for high efficiency and low emissions. Because fuel cell vehicles remain expensive and the demand for hydrogen is therefore limited, very few fueling stations are being built. To try to accelerate the development of a hydrogen economy, some original equipment manufacturers (OEM) in the automotive industry have been working on a hydrogen-fueled internal combustion engine (ICE) as an intermediate step. Despite its lower cost, the hydrogen-fueled ICE offers, for a similar amount of onboard hydrogen, a lower driving range because of its lower efficiency. This paper compares the fuel economy potential of hydrogen-fueled vehicles to their conventional gasoline counterparts. To take uncertainties into account, the current and future status of both technologies were considered.

This paper reports on research activities aiming to improve the efficiency of direct injected, hydrogen powered internal combustion engines. In a recent major change in the experimental setup the hydrogen single cylinder research engine at Argonne National Laboratory was upgraded to a new engine geometry providing increased compression ratio and a longer piston stroke compared to its predecessor. The higher compression ratio and the more advantageous volume to surface ratio of the combustion chamber are both intended to improve the overall efficiency of the experimental setup. Additionally, a new series of faster acting, piezo-activated injectors is used with the new engine providing increased flexibility for the optimization of DI injection strategies. This study focuses on the comparison of experimental data of the baseline versus the improved single cylinder research engine for similar engine operating conditions.

In order to determine any synergistic effects from reforming multicomponent fuels and to determine the effects of fuel additives and impurities we have investigated the autothermal reforming of fuel blends, including paraffin-aromatic, paraffin-naphthene, paraffin-oxygenate, and paraffin-detergent binary mixtures. The results indicate that aromatic, naphthenic, and detergent components adversely effect the reforming of paraffinic species. The results suggest that competitive adsorption at the catalyst sites decreases conversion rates of the paraffinic species. The paraffinic species are displaced by more strongly adsorbing species, leading to decreased kinetics for paraffin conversion.

Different blends of gasoline range hydrocarbons were investigated to determine the effect of aromatic, naphthenic, and paraffinic content on performance in an autothermal reformer. In addition, we investigated the effects of detergent, antioxidant, and oxygenate additives. These tests indicate that composition effects are minimal at temperatures of 800°C and above, but at lower temperatures or at high gas hourly space velocities (GHSV approaching 100,000 h-1) composition can have a large effect on catalyst performance. Fuels high in aromatic and naphthenic components were more difficult to reform. In addition, additives, such as detergents and oxygenates were shown to decrease reformer performance at lower temperatures.

Gasoline is a complex fuel. Many of the constituents of gasoline that are beneficial for the internal combustion engine (ICE) are expected to be challenging for on-board reformers in fuel-cell vehicles. To address these issues, the autothermal reforming of gasoline and individual components of gasoline has been investigated. The results indicate that aromatic components require higher temperatures and longer contact times to reform than paraffinic components. Napthenic components require higher temperatures to reform, but can be reformed at higher space velocities than paraffinic components. The effects of sulfur are dependent on the catalyst. These results suggest that further evolution of gasoline could reduce the demands on the reformer and provide a better fuel for a fuel-cell vehicle.

The physical and morphological properties of the particulate matter emitted from a 1.7-liter light-duty diesel engine were characterized by observing its evolution in size and fractal geometry along the exhaust system. A common-rail direct-injection diesel engine, the exhaust system of which was equipped with a turbocharger, EGR, and two oxidation catalysts, was powered with a California low-sulfur diesel fuel at various engine-operating conditions. A unique thermophoretic sampling system, a high-resolution transmission electron microscope (TEM), and customized image processing/data acquisition systems were key instruments that were used for the collection of particulate matter, subsequent imaging of particle morphology, and detailed analysis of particle dimensions and fractal geometry, respectively. The measurements were carried out at four different positions along the exhaust pipe.

This paper reports an effort to measure particulate emissions from a modern light duty CIDI engine equipped with a common-rail fuel injection system, a closed loop EGR system and a state-of-the-art aftertreatment system. Particulate emissions both upstream and downstream of the catalyst were measured using an SMPS system and a TEOM while operating the engine at various steady-state conditions. The measurements upstream of the catalyst show that the particulate emissions are strongly dependent on the engine speed, load and EGR conditions. The measurements downstream of the catalyst show the effectiveness of the catalyst in reducing particulate mass emissions by 20-80%, with reductions in particulate mean diameters averaging about 10%. The trends observed are discussed in terms of previously established particulate formation and destruction mechanisms.