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In this study, tailpipe-sampling was used to sample the exhaust aerosol of a Stage IV tractor equipped with Diesel Oxidation Catalyst (DOC) and Selective Catalytic Reduction (SCR) aftertreatment systems. The particle emissions were characterized in terms of number concentration (particle size of > 2.5 nm), mass concentration (particle size of 6-612 nm) BC mass concentration and chemical composition (particle size of > 30 nm). The measurements were conducted on-road by setting a mobile laboratory on a trailer and pulling it with the tractor. In addition to driving, heavy-lift work cycles were tested, where separate lifts of a 1000 kg weight were conducted with the front fork of the tractor with two minutes of idling between consecutive lifts. Both a Porous Tube Diluter (PTD) with ambient temperature dilution air as well as an ejector diluter with hot dilution air were used to sample the exhaust aerosol.

Modern ‘DOC-cDPF’ systems for diesel exhaust are employing Pt-, Pd- as well as Pt/Pd alloy- based coatings to ensure high conversion efficiency of CO, HC even at low temperatures. Depending on the target application, these coatings should be also optimized towards NO2 generation which is involved in low temperature soot oxidation as well as in SCR-based deNOx. Zeolite materials are also frequently used to control cold-start HC emissions. Considering the wide variety of vehicles, engines and emission targets, there is no single optimum coating technology. The main target is therefore to maximize synergies rather than to optimize single components. At the same time, the system designer has nowadays a wide range of technologies to choose from, including PGM alloyed combinations (Pt/Pd), multiple layers and zones applicable to both DOCs and DPFs.

In this article we present a design of a new miniaturized sensor with the capacity to measure exhaust particle concentrations on board vehicles and engines. The sensor is characterized by ultra-fast response time, high sensitivity, and a wide dynamic range. In addition, the physical dimensions of the sensor enable its placement along the exhaust line. The concentration response and temporal performance of a prototype sensor are discussed and characterized with aerosol laboratory test measurements. The sensor performance was also tested with actual engine exhaust in both chassis and engine dynamometer measurements. These measurements demonstrate that the sensor has the potential to meet and even exceed any requirements around the world in terms of on-board diagnostic (OBD) sensitivity and frequency of monitoring.

The Pegasor Particle Sensor (PPS) is a small and lightweight sensor that can be used directly in raw exhaust to provide the mass and number concentration of exhaust aerosol. Its operation principle is based on the electrical charging of exhaust aerosol and determination of particle concentration by measuring the charge accumulated on the particles. In this paper we have applied the PPS in a variety of vehicle exhaust configurations to evaluate its performance characteristics. First, the output signal of the instrument was calibrated with diesel exhaust to deliver either the mass or the number concentration of exhaust aerosol. Linear response with the soot mass concentration measured by a Photo Acoustic Soot Sensor and number concentration measured by an Electrical Low Pressure Impactor was established.

The Particle Measurement Programme (PMP) developed an exhaust particle number measurement protocol that has been adopted by current light duty vehicle emission regulations in Europe. This includes thermal treatment of the exhaust aerosol to isolate solid particles only and a number counting device with a lower cutpoint of 23 nm to avoid measurement of smaller particles that may affect the repeatability of the measurement. In this paper, we examine a potential alternative to the PMP system, where the thermal treatment is replaced by a catalytic stripper (CS). This offers oxidation and not just evaporation of the volatile components. Alternative sampling systems, either fulfilling the PMP recommendations or utilizing a CS, have been explored in terms of their volatile particle removal efficiency. Tests have been conducted on diesel exhaust, diesel equipped with DPF and gasoline direct injection emissions.

Modern diesel vehicles utilize two technologies, one fuel based and one hardware based, that have been motivated by recent European legislation: diesel fuel blends containing Fatty Acid Methyl Esters (FAME) and Diesel Particulate Filters (DPF). Oxygenates, like FAME, are known to reduce PM formation in the combustion chamber and reduce the amount of soot that must be filtered from the engine exhaust by the DPF. This effect is also expected to lengthen the time between DPF regenerations and reduce the fuel consumption penalty that is associated with soot loading and regeneration. This study investigated the effect of FAME content, up to 50% v/v (B50), in diesel fuel on the DPF regeneration frequency by repeatedly running a Euro 5 multi-cylinder bench engine over the European regulatory cycle (NEDC) until a specified soot loading limit had been reached.

The Pegasor Particle Sensor (PPS) has been earlier presented by Ntziachristos et al. (SAE Paper 2011-01-0626) as a novel small and robust instrument that can be directly installed in the exhaust line to measure exhaust particles without any dilution. The instrument is based on the electrical detection of aerosol. It is increasingly being used to measure exhaust particles from engines and vehicles with different exhaust configurations. In this study, a number of tests have been conducted using two sensors in parallel, one directly installed in the tailpipe and one installed in the CVS, side by side to the PM sampling filter. Aim of the study was to make recommendations on the proper use of the sensor and to check how the sensor signal compares to particulate mass, soot concentration, and particle number. A first finding is that external heating has to be provided to the sensor to avoid condensation.

Particle emissions have been generally associated to diesel engines. However, spark-ignition direct injection (SI-DI) engines have been observed to produce notable amounts of particulate matter as well. The upcoming Euro 6 legislation for passenger cars (effective in 2014, stricter limit in 2017) will further limit the particulate emissions from SI engines by introducing a particle number emission (PN) limit, and it is not probable that the SI-DI engines are able to meet this limit without resorting to additional aftertreatment systems. In this study, the solid particle emissions of a SI-DI passenger car with and without an installed Particle Oxidation Catalyst (POC®) were studied over the New European Driving Cycle (NEDC) on a chassis dynamometer and over real transient acceleration situations on road. It was observed that a considerable portion of particle number emissions occurred during the transient acceleration phases of the cycle.

The relationship between ethanol and iso-butanol fuel concentrations and vehicle particulate matter emissions was investigated. This study utilized a gasoline direct injection (GDI) flexible fuel vehicle (FFV) with wall-guided fueling system tested with four fuels, including E10, E51, E83, and an iso-butanol blend at a proportion of 55% by volume. Emission measurements were conducted over the Federal Test Procedure (FTP) driving cycle on a chassis dynamometer with an emphasis on the physical and chemical characterization of particulate matter (PM) emissions. The results indicated that the addition of higher ethanol blends and the iso-butanol blend resulted in large reductions in PM mass, soot, and total and solid particle number emissions. PM emissions for the baseline E10 fuel were characterized by a higher fraction of elemental carbon (EC), whereas the PM emissions for the higher ethanol blends were more organic carbon (OC) in nature.

The effect of “Start & Stop” and “Gear Shift Indicator” - two widespread fuel saving technologies - on fuel consumption and particle emissions of a Euro 5 passenger car is evaluated in this paper. The vehicle was subjected to a series of different driving cycles, including the current (NEDC) and future (WLTC) cycles implemented in the European type approval procedure at cold and hot start condition and particle number was measured with an AVL Particle Counter. In addition, we have utilized two Pegasor Particle Sensor units positioned in different locations along the sampling line to assess the impact of the sampling location on the particle characteristics measured during highly transient events. The results showed that the particle number emission levels over the WLTC were comparable to the NEDC ones, whereas NOx emissions were more than twofold higher. Both fuel saving technologies can lead to reduced fuel consumption and, subsequently CO2 emissions, in the order of 5%.

The latest generation of internal combustion engines may emit significant levels of sub-23 nm particles. The main objective of the Horizon 2020 “DownToTen” project was to develop a robust methodology and provide policy recommendations towards the particle number (PN) emissions measurements in the sub-23 nm region. In order to achieve this target, a new portable exhaust particle sampling system (PEPS) was developed, being capable of measuring exhaust particles down to at least 10 nm under real-world conditions. The main design target was to build a system that is compatible with current PMP requirements and is characterized by minimized losses in the sub-23 nm region, high robustness against artefacts and high flexibility in terms of different PN modes investigation, i.e. non-volatile, volatile and secondary particles.

Cellular exposure to diluted exhaust gas is a promising method to assess the adverse effects of road traffic on human health. To fully understand the potential correlation between emission patterns, vehicle technologies and cellular toxicity in real-world scenarios, further research is needed. This study evaluates the toxicity of exhaust emissions from two advanced technology vehicles in real-world driving conditions. One vehicle is a gasoline direct injection (GDI) with a particle filter (GPF), while the other is a gasoline port fuel injection (PFI) hybrid without a GPF. The vehicles were tested on a chassis dyno using a Real Driving Emissions (RDE) test cycle that replicates on-road conditions. The test cycle included both cold and hot starting engine conditions. Human epithelial A549 cells were exposed to diluted exhaust using an Air Liquid Interface (ALI) system to assess toxicity. Τhe particle dose during cell exposure simulated human inhalation in an urban environment.

The proposed Euro 7 emission standard foresees that the emission behaviour of Euro 7 vehicles is monitored via an on-board monitoring (OBM) system. In Euro 7 vehicles, OBM systems will monitor the emissions of nitrogen oxides (NOX), ammonia (NH3) and particulate matter (PM) for every trip through a combination of measured and modelled data. Sensors employed to support on-board diagnostics (OBD) in current vehicles may be used to support OBM. According to the Euro 7 OBM concept presented in this paper, OBM will serve a dual purpose: the first is to warn the user of a vehicle about the need to perform repairs on the engine or the pollution control systems when these are needed. If these repairs are not performed in a timely manner, the OBM system will be able to ultimately prevent engine restart, akin to the existing low-reagent driver warning system in some compression ignition vehicles. The second purpose of OBM is to monitor the compliance of vehicle types with the emission limits.