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The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.

Current progress in the development of diesel engines substantially contributes to the reduction of NOx and Particulate Matter (PM) emissions but will not succeed to eliminate the application of Diesel Particulate Filters (DPFs) in the future. In the past we have introduced a Multi-Functional Reactor (MFR) prototype, suitable for the abatement of the gaseous and PM emissions of the Low Temperature Combustion (LTC) engine operation. In this work the performance of MFR prototypes under both conventional and advanced combustion engine operating conditions is presented. The effect of the MFR on the fuel penalty associated to the filter regeneration is assessed via simulation. Special focus is placed on presenting the performance assessment in combination with the existing differences in the morphology and reactivity of the soot particles between the different modes of diesel engine operation (conventional and advanced). The effect of aging on the MFR performance is also presented.

It is the objective of this work to characterize mixture formation in the sprays emanating from Multi-Layer (ML) nozzles under approximately engine-like conditions by quantitative, spatially, and temporally resolved fuel-air ratio and temperature measurements. ML nozzles are cluster nozzles which have more than one circle of orifices. They were introduced previously, in order to overcome the limitations of conventional nozzles. In particular, the ML design yields the potential of variable spray interaction, so that mixture formation could be controlled according to the operating condition. In general, it was also a primary aim of the cluster-nozzle concepts to combine the enhanced atomization and pre-mixing of small nozzle holes with the longer spray penetration lengths of large holes. The applied diagnostic, which is based on 1d spontaneous Raman scattering, yields the quantitative stoichiometric ratio and the temperature in the vapor phase.

In this study the fuel influence of several bio-fuel candidates on homogeneous engine combustion systems with direct injection is investigated. The results reveal Ethanol and 2-Butanol as the two most knock-resistant fuels. Hence these two fuels enable the highest efficiency improvements versus RON95 fuel ranging from 3.6% - 12.7% for Ethanol as a result of a compression ratio increase of 5 units. Tetrahydro-2-methylfuran has a worse knock resistance and a decreased thermal efficiency due to the required reduction in compression ratio by 1.5 units. The enleanment capability is similar among all fuels thus they pose no improvements for homogeneous lean burn combustion systems despite a significant reduction in NOX emissions for the alcohol fuels as a consequence of lower combustion temperatures.

Natural Gas engines are viewed as an alternative to diesel power in the quest to reduce heavy duty vehicle emissions in polluted urban areas. In particular, it is acknowledged that natural gas has the potential to reduce the inventory of particulate matter, and this has encouraged the use of natural gas engines in transit bus applications. Extensive data on natural gas and diesel bus emissions have been gathered using two Transportable Heavy Duty Vehicle Emissions Testing Laboratories, that employ chassis dynamometers to simulate bus inertia and road load. Most of the natural gas buses tested prior to 1997 were powered by Cummins L-10 engines, which were lean-burn and employed a mechanical mixer for fuel introduction. The Central Business District (CBD) cycle was used as the test schedule.

Homogeneous Charge Compression Ignition (HCCI) combustion has the potential to produce low NOx and low particulate matter (PM) emissions while providing high efficiency. In HCCI combustion, the start of auto-ignition of premixed fuel and air depends on temperature, pressure, concentration history during the compression stroke, and the unique reaction kinetics of the fuel/air mixture. For these reasons, the choice of fuel has a significant impact on both engine design and control strategies. In this paper, ten (10) gasoline-like testing fuels, statistically representative of blends of four blending streams that spanned the ranges of selected fuel properties, were tested in a single cylinder engine equipped with a hydraulic variable valve train (VVT) and gasoline direct injection (GDI) system.

The HSDI Diesel engine contributes substantially to the decrease of fleet fuel consumption thus to the reduction of CO2 emissions. This results in the rising market acceptance which is supported by desirable driving performance as well as greatly improved NVH behavior. In addition to the above mentioned requirements on driving performance, fuel economy and NVH behavior, continuously increasing demands on emissions performance have to be met. From today's view the Diesel particulate trap presents a safe technology to achieve the required reduction of the particle emission of more than 95%. However, according to today's knowledge a further, substantial NOx engine-out emission reduction for the Diesel engine is counteracts with the other goal of reduced fuel consumption. To comply with current and future emission standards, Diesel engines will require DeNOx technologies.

In one-dimensional engine simulation programs the simulation of engine performance is mostly done by parameter fitting in order to match simulations with experimental data. The extensive fitting procedure is especially needed for emissions formation - CO, HC, NO, soot - simulations. An alternative to this approach is, to calculate the emissions based on detailed kinetic models. This however demands that the in-cylinder combustion-flow interaction can be modeled accurately, and that the CPU time needed for the model is still acceptable. PDF based stochastic reactor models offer one possible solution. They usually introduce only one (time dependent) parameter - the mixing time - to model the influence of flow on the chemistry. They offer the prediction of the heat release, together with all emission formation, if the optimum mixing time is given.

Synthetic fuels are expected to play an important role for future mobility, because they can be introduced seamlessly alongside conventional fuels without the need for new infrastructure. Thus, understanding the interaction of GTL fuels with modern engines, and aftertreatment systems, is important. The current study investigates potential benefits of GTL fuel in respect of diesel particulate filters (DPF). Experiments were conducted on a Euro 4 TDI engine, comparing the DPF response to two different fuels, normal diesel and GTL fuel. The investigation focused on the accumulation and regeneration behavior of the DPF. Results indicated that GTL fuel reduced particulate formation to such an extent that the regeneration cycle was significantly elongated, by ∼70% compared with conventional diesel. Thus, the engine could operate for this increased time before the DPF reached maximum load and regeneration was needed.

Fuels derived from biomass will most likely contain oxygen due to the high amount of hydrogen needed to remove oxygen in the production process. Today, alcohol fuels (e. g. ethanol) are well understood for spark ignition engines. The Institute for Combustion Engines at RWTH Aachen University carried out a fuel investigation program to explore the potential of alcohol fuels as candidates for future compression ignition engines to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. The soot formation and oxidation process when using alcohol fuels in diesel engines is not yet sufficiently understood. Depending on the chain length, alcohol fuels vary in cetane number and boiling temperature. Decanol possesses a diesel-like cetane number and a boiling point in the range of the diesel boiling curve. Thus, decanol was selected as an alcohol representative to investigate the influence of the oxygen content of an alcohol on the combustion performance.

Within the Cluster of Excellence “Tailor-Made Fuels from Biomass” at RWTH Aachen University, the Institute for Combustion Engines carried out an investigation program to explore the potential of future biofuel components in Diesel blends. In this paper, thermodynamic single cylinder engine results of today's and future biofuel components are presented with respect to their engine-out emissions and engine efficiency. The investigations were divided into two phases: In the first phase, investigations were performed with rapeseed oil methyl ester (B100) and an Ethanol-Gasoline blend (E85). In order to analyze the impact of different fuel blends, mixtures with 10 vol-% of B100 or E85 and 90 vol-% of standardized EN590 Diesel were investigated. Due to the low cetane number of E85, it cannot be used purely in a Diesel engine.

The DEXA Cluster consisted of three closely interlinked projects. In 2003 the DEXA Cluster concluded by demonstrating the successful development of critical technologies for Diesel exhaust particulate after-treatment, without adverse effects on NOx emissions and maintaining the fuel economy advantages of the Diesel engine well beyond the EURO IV (2000) emission standards horizon. In the present paper the most important results of the DEXA Cluster projects in the demonstration of advanced particulate control technologies, the development of a simulation toolkit for the design of diesel exhaust after-treatment systems and the development of novel particulate characterization methodologies, are presented. The motivation for the DEXA Cluster research was to increase the market competitiveness of diesel engine powertrains for passenger cars worldwide, and to accelerate the adoption of particulate control technology.

Environmental concern demands that emissions and fuel consumption of vehicles have to improve considerably in the next 10 years. New technologies for gasoline engines, downsizing with high boosting, direct injection and fully variable valve train systems, are being developed. For Diesel engines, improved components including piezobased injectors and particle filters are expected. In the drive train new starter-generator systems as well as automated manual transmissions are being developed. In parallel alternative fuels are investigated and the use of hybrid drives and fuel cells are developed. This paper reports the progress made in the recent years and gives a comparative assessment on the different technologies with a prediction of the introduction dates and volumes into the market.

The introduction of the new emission standards in 2002/04 for heavy-duty diesel engines requires a substantial reduction of the NOx emissions while the particulate emissions remain on a constant level. The application of cooled EGR appears to be the most common approach in order to achieve the required target, although other means such as advanced combustion systems and the application of emission control devices to reduce NOx emissions have to be taken into account as well. The purpose of this study is to investigate the potential of such alternative solutions in comparison with cooled EGR to meet the upcoming emission standards.

Within the European research programme IDEA (Integrated Diesel European Action), detailed experimental and theoretical studies of the fundamental phenomena of the Diesel engine like flow, injection, mixture formation, auto-ignition, combustion and pollutant formation were carried out to improve knowledge and to set up models for a simulation code. Because this basic research of the Diesel combustion process is very complex and cost intensive, it was carried out jointly by the JRC (Joint Research Committee), an association of European car manufacturers (Fiat, Peugeot SA, Renault, Volvo and Volkswagen). The activities were also subsidized by the Commission of the European Communities and the Swedish National Board of Technical Development. The results of the research work will support the design of even more efficient engines and the further reduction of soot and NOx emissions and will also enable the companies to reduce time and cost in developing new engines.

The formation of soot during the first phase and the oxidation of soot during the later phase of the combustion in a direct-injection diesel engine have been investigated in detail by an extinction method. The experiments were performed in a 1.9 l near-production high-speed four-cylinder in-line direct-injection diesel engine for passenger cars for different rates of exhaust gas recirculation (EGR) and for different fuels. The measurements result in crank angle resolved and cycle-averaged soot mass concentrations in the piston bowl and the combustion chamber. The results show that with increasing EGR-rates the amount of soot formed is increased only slightly but the amount of soot oxidized during combustion decreases significantly. This is assumed to be the main reason for the increase of soot in the exhaust gas with increasing EGR-rates.

Strategic Materials at Reaction Temperatures (SMART) is an approach used to design washcoat systems for passive 4-way emission control catalysts. Light duty diesel vehicles need to meet the European Motor Vehicle Emissions Group (MVEG) cycle or U. S. Federal test procedure (FTP 75). Emissions that are monitored include hydrocarbon (HC), nitrogen oxides (NOx), carbon monoxide (CO) and total particulate matter (TPM). Low engine-exhaust temperatures (< 200°C during city driving) and high temperatures (> 500-800°C under full load and wide-open throttle) make emission control a formidable task for the catalyst designer Gas phase HC, CO and NOx reactions must be balanced with the removal of the soluble organic fraction for the vehicle to be in compliance with regulations. The SMART approach uses model gases under typical operating conditions in the laboratory to better understand the function of individual washcoat components.

This paper reports the test results from the DPF (diesel particulate filter) portion of the DECSE (Diesel Emission Control - Sulfur Effects) Phase 1 test program. The DECSE program is a joint government and industry program to study the impact of diesel fuel sulfur level on aftertreatment devices. A systematic investigation was conducted to study the effects of diesel fuel sulfur level on (1) the emissions performance and (2) the regeneration behavior of a continuously regenerating diesel particulate filter and a catalyzed diesel particulate filter. The tests were conducted on a Caterpillar 3126 engine with nominal fuel sulfur levels of 3 parts per million (ppm), 30 ppm, 150 ppm and 350 ppm.

A vehicle investigation programme was initiated to evaluate the influence of diesel fuel sulfur content on the performance of a DeNOx catalyst for NOx control. The programme was conducted with a passive DeNOx catalyst, selected for its good NOx reduction performance and two specially prepared fuels with different sulfur contents. Regulated emissions were measured and analysed during the course of the programme. The NOx conversion efficiency of the DeNOx catalyst increased from 14 to 26% over the new European test cycle when the sulfur content of the diesel fuel was reduced from 49 to 6 wt.-ppm. In addition the number and size of particles produced using 6 wt.-ppm sulfur fuel were measured by two different techniques: mobility diameter by SMPS and aerodynamic diameter by impactor. The influence of the assumed density of the particulate on the apparent diameters measured by the two techniques is discussed.

In the recent years diesel engine developers and manufacturers achieved a great progress in reducing the most important diesel engine pollutants, NOX and particulates. But nevertheless big efforts in diesel engine development are necessary to meet with the more stringent future emission regulations. To improve the knowledge about particle formation and emission an insight in the cylinder is necessary. By using the fast gas sampling technique samples from the cylinder were taken as a function of crank angle and analyzed regarding the soot particle size distribution and the particle mass. The particle size distribution was measured by a conventional SMPS. Under steady state conditions the influence of aromatic and oxygen content in the fuel on in-cylinder particle size distribution and particle mass inside a modern 4V-CR-DI-diesel-engine were determined. After injection and ignition, mainly small soot particles were formed which grow and in the later combustion phase coagulate.