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The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.

Current progress in the development of diesel engines substantially contributes to the reduction of NOx and Particulate Matter (PM) emissions but will not succeed to eliminate the application of Diesel Particulate Filters (DPFs) in the future. In the past we have introduced a Multi-Functional Reactor (MFR) prototype, suitable for the abatement of the gaseous and PM emissions of the Low Temperature Combustion (LTC) engine operation. In this work the performance of MFR prototypes under both conventional and advanced combustion engine operating conditions is presented. The effect of the MFR on the fuel penalty associated to the filter regeneration is assessed via simulation. Special focus is placed on presenting the performance assessment in combination with the existing differences in the morphology and reactivity of the soot particles between the different modes of diesel engine operation (conventional and advanced). The effect of aging on the MFR performance is also presented.

Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.

The HSDI Diesel engine contributes substantially to the decrease of fleet fuel consumption thus to the reduction of CO2 emissions. This results in the rising market acceptance which is supported by desirable driving performance as well as greatly improved NVH behavior. In addition to the above mentioned requirements on driving performance, fuel economy and NVH behavior, continuously increasing demands on emissions performance have to be met. From today's view the Diesel particulate trap presents a safe technology to achieve the required reduction of the particle emission of more than 95%. However, according to today's knowledge a further, substantial NOx engine-out emission reduction for the Diesel engine is counteracts with the other goal of reduced fuel consumption. To comply with current and future emission standards, Diesel engines will require DeNOx technologies.

The future worldwide emission regulations will request a drastic decrease of Diesel engine tailpipe emissions. Depending on the planned application and the real official regulations, a further strong decrease of engine out emissions is necessary, even though the utilized exhaust after-treatment systems are very powerful. To reduce NOx emissions internally, the external exhaust gas recirculation (EGR) is known as the most effective way. Due to the continuously increasing requirements regarding specific power, dynamic behavior and low emissions, future air path systems have to fulfill higher requirements and, consequently, become more and more complex, e.g. arrangements with a 2-stage turbo charging or 2-stage EGR system with different stages of cooling performance.

This paper describes an alternative catalyst aging process using a hot gas test stand for thermal aging. The solution presented is characterized by a burner technology that is combined with a combustion enhancement, which allows stoichiometric and rich operating conditions to simulate engine exhaust gases. The resulting efficiency was increased and the operation limits were broadened, compared to combustion engines that are typically used for catalyst aging. The primary modification that enabled this achievement was the recirculation of exhaust gas downstream from catalyst back to the burner. The burner allows the running simplified dynamic durability cycles, which are the standard bench cycle that is defined by the legislation as alternative aging procedure and the fuel shut-off simulation cycle ZDAKW. The hot gas test stand approach has been compared to the conventional engine test bench method.

Synthetic fuels are expected to play an important role for future mobility, because they can be introduced seamlessly alongside conventional fuels without the need for new infrastructure. Thus, understanding the interaction of GTL fuels with modern engines, and aftertreatment systems, is important. The current study investigates potential benefits of GTL fuel in respect of diesel particulate filters (DPF). Experiments were conducted on a Euro 4 TDI engine, comparing the DPF response to two different fuels, normal diesel and GTL fuel. The investigation focused on the accumulation and regeneration behavior of the DPF. Results indicated that GTL fuel reduced particulate formation to such an extent that the regeneration cycle was significantly elongated, by ∼70% compared with conventional diesel. Thus, the engine could operate for this increased time before the DPF reached maximum load and regeneration was needed.

The European research co-operation Lotus is presented. The main objectives of the project were i) to show the potential for a urea-based SCR system to comply with the EU standard of years 2005 and 2008 for heavy-duty Diesel engines for different driving conditions with optimal fuel consumption, ii) to reach 95 % conversion of NOx at steady state at full load on a Euro III engine, iii) to reach 75 % NOx reduction for exhaust temperatures between 200-300°C, and 85 % average NOx reduction between 200-500°C. The energy content of the consumed urea should not exceed 1.0 %, calculated as specific fuel consumption. These targets were met in May 2003 and the Lotus SCR system fulfilled the Euro V NOx legislative objectives for year 2008.

Flow control by fluidic devices - without moving parts - offers advantages of reliability and low cost. As an example of their automobile application based on authors'' long-time experience the paper describes a fluidic valve for switching exhaust gas flow in a NOx absorber into a by-pass during regeneration phase. The unique feature here is the fluidic valve being of monostable and of axisymmetric design, integrated into the absorber body. After development in aerodynamic laboratory, the final design was tested on engine test stand and finally in a car. This proved that the performance under high temperature and pulsation existing in exhaust systems is reliable and promising. Fluidic valves require, however, close matching with aerodynamic load. To optimize the exhaust system layout for the whole load-speed range and reaching minimum counter- pressure, both the components of exhaust system and control strategy have to be properly adopted.

Today, SULEV legislation represents the most stringent emission standard for vehicles with combustion engines, and it will be introduced starting by Model Year 2003. In order to meet such standards, even higher effort is required for the development of the exhaust gas emission concept of SI engines. Beyond a facelift of the combustion system, exhaust gas aftertreatment, and the engine management system, new approaches are striven for. The principle keys are well known: low HC feed gas, high thermal load for quick light-off, exhaust system with low heat capacity and highly effective exhaust gas aftertreatment.

For the measurement of NO and NO2 the CLD-analyzer (chemiluminescense detector) has been used for more than twenty-five years. The disadvantage of the CLD is that NO can be measured only. To obtain total NOX (NO+NO2) the exhaust gas sample has to flow through a catalytic converter, which reduces NO2 to NO. The converter has a efficiency between 90 and 100%. For precise NO and NO2 values it is an advantage to analyze NO and NO2 directly. This paper describes a new UV NOX-analyzer for the simultaneous measurement of NO and NO2. Two different configurations, for high and low concentrations, eg. CVS-bag analysis are presented. The performance of the analyzers is documented in comparison to the UV-RAS analyzer with converter for NOX [1] and the conventional CLD-analyzer. The benefits of the new analyzer compared to analyzers equipped with a converter are given in detailed test results.

The California LEV1 II program will be introduced in the year 2003 and requires a further reduction of the exhaust emissions of passenger cars. The cold start emissions represent the main part of the total emissions of the FTP2-Cycle. Cold start emissions can be efficiently reduced by injecting secondary air (SA) in the exhaust port making compliance with the most stringent standards possible. The thermochemical conditions (mixing rate and temperature of secondary air and exhaust gas, exhaust gas composition, etc) prevailing in the exhaust system are described in this paper. This provides knowledge of the conditions for auto ignition of the mixture within the exhaust manifold. The thus established exothermal reaction (exhaust gas post-combustion) results in a shorter time to light-off temperature of the catalyst. The mechanisms of this combustion are studied at different engine idle conditions.

More stringent emissions regulations, space limitations for catalytic converters in modern automotive applications, and new engine technologies constitute design challenges for today's engineers. In that context high cell density thinwall and ultrathinwall ceramic substrates have been designed into advanced catalytic converters. Whereas the majority of these substrates have a square cell geometry, a potential for further emissions improvement has been predicted for hexagonal cell structures. In order to verify these predictions, a ceramic substrate has been developed combining the features of high cell density, ultrathin cell walls, and hexagonal cell structure. Based on modeling data, the actual cell density and wall thickness of the hexagonal cell substrate will be defined. The performance of that substrate will be assessed by comparing experimental emissions results using two modern Volkswagen engines.

Electromechanical valve trains in camless engines enable virtually fully variable valve timing that offers large potential for both part load fuel economy and high low end torque. Based upon the principle of a spring-mass-oscillator, the actuator stores the energy to open and close the valves in springs. However, the motion of the valves and the electromechanical actuation suffers from parasitic losses, such as friction and ohmic resistance. Besides eddy current losses, gas forces obviously play a further important role in the control of exhaust valve opening especially at high engine speeds and loads. Based on engine test bench data, computational simulations (3D CFD, gas exchange process and electromechanical system) are carried out to analyze the effects of exhaust valve gas forces on the dynamic motion of valve and actuator. The modeling approach and results of this investigation are discussed in this paper.

The sound quality and performance of an automotive engine are both significantly influenced by the “air-to-air” system, i.e., the intake system, the exhaust system, and the engine gas dynamics. Only a full systems approach can result in an optimized air-to-air system, which fulfills engine performance requirements, overall sound pressure level targets for airborne vehicle noise, as well as sound quality demands. This paper describes an approach, which considers the intake system, engine, and exhaust system within one CAE model that can be utilized for engine performance calculations as well as acoustic simulations. Examples comparing simulated and measured sound are discussed. Finally, the simulated sound (e.g., at the tailpipe of the exhaust system) is combined with an interior noise simulation technique to evaluate its influence inside the vehicle's interior.

Both, the continuous strengthening of the exhaust emission legislation and the striving for a substantial reduction of carbon dioxide output in the traffic sector depict substantial requirements for the development of future diesel engines. These engines will comprise not only the mandatory diesel oxidation catalyst (DOC) and particulate filter DPF but a NOx aftertreatment system as well - at least for heavier vehicles. The oxidation catalysts as well as currently available NOx aftertreatment technologies, i.e., LNT and SCR, rely on sufficient exhaust gas temperatures to achieve a proper conversion. This is getting more and more critical due to the fact that today's and future measures for CO₂ reduction will result in further decrease of engine-out temperatures. Additionally this development has to be considered in the light of further engine electrification and hybridization scenarios.

An oxidizing catalytic converter was evaluated in the exhaust train of a 3.73 kW (5 hp) natural gas engine. The engine was developed for use in a gas engine-driven heat pump and is designed for operation at lean air/fuel ratios. The converter tested had a metallic substrate with a cell density of 31 cells/cm2. Converter tests measured emission performance as a function of the key engine variables: speed, load, spark advance and air/fuel ratio. As expected, CO conversion averaged well above 90 percent. Hydrocarbon conversion varied between 68.6 and 89.8 percent over a range of eight speed and load combinations selected to cover the normal operating range of the engine. Conversion of individual hydrocarbon species was examined also. Although the converter tests were not designed to isolate the key converter variables, a simple mathematical model allowed us to explore the effect of these variables on conversion.

The new opoc™ diesel engine concept was presented at the SAE 2005 World Congress [1]. Exceptional power density of >1hp/lb and >40% efficiency have been predicted for the 2-stroke opoc™ diesel engine concept. Intensive CAE simulations have been performed during the concept and design phase in order to define the baseline scavenging and combustion parameters, such as port timing, turbocharger configuration and fuel injection nozzle design. Under a DARPA contract, first prototype engines have been built and have undergone a validation testing program. The main goal of the first testing phase was to demonstrate the power output capability of the new engine concept. In close relationship and interaction of testing and CAE simulation, the uniflow scavenging process and parameters of the special diesel direct side injection have been optimized. This paper discusses the latest results of the opoc engine development.

A uniform flow distribution at converter inlet is one of the fundamental requirements to meet high catalytic efficiency. Commonly used tools for optimization of the inlet flow distribution are flow measurements as well as CFD analysis. This paper puts emphasis on the experimental procedures and results. The interaction of flow measurements and CFD is outlined. The exhaust gas flow is transient, compressible and hot, making in-situ flow measurements very complex. On the other hand, to utilize the advantages of flow testing at steady-state and cold conditions the significance of these results has to be verified first. CFD analysis under different boundary conditions prove that - in a first approach - the flow situation can be regarded as a sequence of successive, steady-state situations. Using the Reynolds analogy a formula for the steady-state, cold test mass flow is derived, taking into account the cylinder displacement and the rated speed.