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Nowadays, alcoholic fuels gain increased interest as alternative transportation biofuel even in compression ignition engines due to the fact that they contain oxygen and can be produced in a sustainable way. Furthermore, due to their lower CN (Cetane Number) they suit better for premixed combustion applications. Experimental research was conducted on a single cylinder engine provided with modern engine architecture modified for DF (Dual-Fuel) purposes. The authors have investigated the use of ethanol in a DF engine in order to exploit its well-known advantages in premixed combustion mode. The DF approach appears to be a promising solution because it permits flexible control of the premixed fuel fraction regardless from the operating conditions. This improves the exploitation of the ethanol potential according the engine working conditions.