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Cycle-resolved end-gas temperatures were measured using dual-broadband rotational CARS in a single-cylinder spark-ignition engine. Simultaneous cylinder pressure measurements were used as an indicator for knock and as input data to numerical calculations. The chemical processes in the end-gas have been analysed with a detailed kinetic mechanism for mixtures of iso-octane and n-heptane at different Research Octane Numbers (RON'S). The end-gas is modelled as a homogeneous reactor that is compressed or expanded by the piston movement and the flame propagation in the cylinder. The calculated temperatures are in agreement with the temperatures evaluated from CARS measurements. It is found that calculations with different RON'S of the fuel lead to different levels of radical concentrations in the end-gas. The apperance of the first stage of the autoignition process is marginally influenced by the RON, while the ignition delay of the second stage is increased with increasing RON.

It is generally accepted that knocking combustion influences the heat transfer in SI engines. However, the effects of heat transfer on the onset of knock is still not clear due to lack of experimental data of the thermal boundary layer close to the combustion chamber wall. This paper presents measurements of the temperature in the thermal boundary layer under knocking and non-knocking conditions. The temperature was measured using dual-broadband rotational Coherent anti-Stokes Raman Spectroscopy (CARS). Simultaneous time-resolved measurements of the cylinder pressure, at three different locations, and the heat flux to the wall were carried out. Optical access to the region near the combustion chamber wall was achieved by using a horseshoe-shaped combustion chamber with windows installed in the rectangular part of the chamber. This arrangement made CARS temperature measurements close to the wall possible and results are presented in the range 0.1-5 mm from the wall.