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The transport sector is experiencing a shift to zero-carbon powertrains driven by aggressive international policies aiming to fight climate change. Battery electric vehicles (BEVs) will play the main role in passenger car applications, while diversified solutions are under investigation for the heavy-duty sector. Within this framework, Light Commercial Vehicles (LCVs) impact is not negligible and accountable for about 2.5% of greenhouse gas (GHG) emissions in Europe. In this regard, few LCV comparative assessments on green powertrains are available in the scientific literature and justified by the fact that several factors and limitations should be considered and addressed to define optimal powertrain solutions for specific use cases. The proposed research study deals with a comparative numerical assessment of different zero-carbon powertrain solutions for LCV. BEVs are compared to hydrogen-based fuel cells (FC) and internal combustion engines (ICE) powered vehicles.