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Technical Paper

A Study of Emission Durability and Ash Accumulation of “Advanced Three-way Catalyst Integrated on Gasoline Particulate Filter” for BS6 (Stage2) Applications

2021-09-22
2021-26-0182
India BS6 Stage2 (2023) regulations demand all gasoline direct injection (GDI) vehicles to meet particulate number emissions (PN) below 6x10+11# per km. Gasoline particulate filters (GPF) are a proven technology and enable high PN filtration efficiencies throughout the entire vehicle lifetime. One challenge for GPF applications could be the changing emission performance characteristics as a function of mileage due to collected ash and/or soot deposits with implications on back pressure losses. The main objective of this technical contribution is to study the above-mentioned challenges while applying Indian driving conditions and typical Indian climate and other ambient conditions. The substrate technology selected for this study is a high porosity GPF designed to enable the integration of a three-way functionality into the GPF, commonly described as catalyzed GPF (cGPF).
Technical Paper

Fatigue and Performance Data for Advanced Thin Wall Ceramic Catalysts

1998-02-23
980670
With stricter emissions standards, low back pressure requirements, and 100,000 mile durability specifications, ceramic catalysts have undergone significant developments over the past few years. The thrust in the ceramics area has centered on thin-wall structures to minimize back pressure and on high cell density for rapid light-off in close-coupled applications. The thin-wall structures are extruded from low expansion cordierite ceramic with adequate strength and thermal shock resistance equivalent to those of standard cordierite substrate. Examples of thin-wall substrate include 350XT which is extruded from a very low expansion dense cordierite ceramic, and 400/4 and 600/4 cell structures extruded from a low expansion modified cordierite ceramic. This paper will focus on the high fatigue resistance, excellent conversion efficiency, and low back pressure of 350 XT substrates with advanced washcoat system.
Technical Paper

Technique for the Analysis of FTP Emissions

1992-02-01
920724
Previous papers have considered the role of the substrate in the catalyst system. It has been shown that the total catalyzed surface area of the substrate (defined as the substrate geometric surface area multiplied by the substrate volume) can act as a surrogate for the catalyst performance. The substrate affects the back pressure of the exhaust system and therefore, the available power. Relationships have been developed between the substrate physical characteristics, and both the pressure drop and total surface area of the substrate. The substrate pressure drop has also been related to power loss. What has been lacking is a means of quantitatively relating the substrate properties to the conversion efficiency. This paper proposes a simple relationship between the substrate total surface area and the emissions of the vehicle as measured on the FTP cycle.
Technical Paper

Review of Vehicle Engine Efficiency and Emissions

2021-04-06
2021-01-0575
For more than two decades [1,2], Corning has served the community with an annual review of global regulatory and technological advances pertaining to emissions from internal combustion engine (ICE) driven vehicles and machinery. We continue with a review for the year 2020, which will be remembered by COVID and the significant negative impact it had on the industry. However, it also provided a glimpse of the possible improvement in air quality with reduced anthropogenic emissions. It was a year marked by goals set for climate change mitigation via reduced fossil fuel use by the transportation sector. Governments stepped up plans to accelerate the adoption of zero tailpipe emitting vehicles. However, any transformation of the transportation sector is not going to happen overnight due to the scale of the infrastructure and technology challenges. A case in point is China, which announced a technology roadmap which envisions half of the vehicles to be hybrids in 2035.
Technical Paper

High Porosity Substrates for Fast-Light-Off Applications

2015-04-14
2015-01-1009
Regulations that limit emissions of pollutants from gasoline-powered cars and trucks continue to tighten. More than 75% of emissions through an FTP-75 regulatory test are released in the first few seconds after cold-start. A factor that controls the time to catalytic light-off is the heat capacity of the catalytic converter substrate. Historically, substrates with thinner walls and lower heat capacity have been developed to improve cold-start performance. Another approach is to increase porosity of the substrate. A new material and process technology has been developed to significantly raise the porosity of thin wall substrates (2-3 mil) from 27-35% to 55% while maintaining strength. The heat capacity of the material is 30-38% lower than existing substrates. The reduction in substrate heat capacity enables faster thermal response and lower tailpipe emissions. The reliance on costly precious metals in the washcoat is demonstrated to be lessened.
Technical Paper

Diesel Emission Control - Last 12 Months in Review

2000-10-16
2000-01-2817
The key diesel emission control papers of the last 12 months have been summarized. In addition, the emerging US and European light-duty and heavy-duty tailpipe regulations are compared. Results are reported on light-duty diesel filtration regeneration systems and experiences, including effects of ash build-up and some recent modeling work. On the heavy-duty side, optimization of SCR catalysts and systems are described, as well as experiences with the first integrated SCR/filter systems, which are already achieving “Euro V” 2008 standards. An update on NOx adsorbers is also provided. The results with new NOx formulations are described, as well as the system performance in a light-duty diesel application.
Technical Paper

Optical Advantages of Thin Window Hybrid Windshields

2018-04-03
2018-01-0468
The adoption of head-up displays (HUDs) is increasing in modern automobiles. Yet integrating this technology into vehicles with standard windshield (WS) laminates can create negative effects for drivers, primarily due to the thickness of glass used. The double ghosting in HUD images is typically overcome by employing a wedged PVB between the two glass plies of the laminate. Another solution is to reduce the thickness of the glass without impacting the overall windshield toughness. Although this still requires the use of a wedged PVB to eliminate HUD ghosting, the thinner glass provides opportunity to increase the image size. However, reducing the thickness of a soda-lime glass (SLG) ply or plies in a conventional soda-lime glass (SLG) laminate can significantly impact the robustness of the laminate to external impact events.
Technical Paper

Challenges of Particulate Number above 10nm Emissions for a China 6 Compliant Vehicle to Meet Future Regulation

2023-04-11
2023-01-0377
As the official proposal for emission regulation Euro 7 has been released by European Commission, PN above 10nm is taken into consideration for the ultrafine particulate emissions control. The challenges of GPF filtration efficiency emerge for the light-duty manufactures to meet the future emission standards. In the present study, a China 6 compliant vehicle was tested to reveal its performance over the China 6 standards and potential to meet the upcoming Euro 7. Three GPF product types (Gen 1, Gen 2, and concept Gen 3) were mounted to the tested vehicle. WLTC tests were conducted on chassis dynamometer in laboratory as well as a self-designed aggressive cycle (“Base Cycle”) tests. To explore the GPFs performance for PN emissions above 10nm against the proposed limit 6.0E11 #/km, PN emission above 10nm were measured in our laboratory tests for both engine out and tailpipe as well as the PN emission above 23nm.
Journal Article

Review of Vehicle Engine Efficiency and Emissions

2022-03-29
2022-01-0540
This review covers advances in regulations and technologies in the past year in the field of vehicular emissions. We cover major developments towards reducing criteria pollutants and greenhouse gas emissions from both light- and heavy-duty vehicles and off-road machinery. To suggest that the transportation is transforming rapidly is an understatement, and many changes have happened already since our review last year [1]. Notably, the US and Europe revised the CO2 standards for light-duty vehicles and electrification mandates were introduced in various regions of the world. These have accelerated plans to introduce electrified powertrains, which include hybrids and pure electric vehicles. However, a full transformation to electric vehicles and the required grid decarbonization will take time, and policy makers are accordingly also tightening criteria pollutant standards for internal combustion engines.
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