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For internal combustion engines and industrial machinery, it is well recognized that the most cost-effective way of reducing energy consumption and extending service life is through lubricant development. This presentation summarizes our recent R&D achievements on developing a new class of candidate lubricants or oil additives ionic liquids (ILs). Features of ILs making them attractive for lubrication include high thermal stability, low vapor pressure, non-flammability, and intrinsic high polarity. When used as neat lubricants, selected ILs demonstrated lower friction under elastohydrodynamic lubrication and less wear at boundary lubrication benchmarked against fully-formulated engine oils in our bench tests. More encouragingly, a group of non-corrosive, oil-miscible ILs has recently been developed and demonstrated multiple additive functionalities including anti-wear and friction modifier when blended into hydrocarbon base oils.

The paper will discuss the design and development of heavy-duty diesel engines to meet the US EPA 2010 on-highway standards - 0.2 g/HP-hr NOx and 0.01 g/HP-hr particulate matter (PM). In meeting these standards a combination of in-cylinder control and aftertreatment control for both NOx and particulate has been used. For NOx control, a combination of cooled exhaust gas recirculation (EGR) and selective catalytic reduction (SCR) is used. The SCR catalyst uses copper zeolite to achieve high levels of NOx conversion efficiency with minimal ammonia slip and unparalleled thermal durability. For particulate control, a diesel particulate filter (DPF) with upstream oxidation catalyst (DOC) is used. While the DPF may be actively regenerated when required, it operates predominantly with passive regeneration - enabled by the high NOx levels between the engine and the DPF, associated with high efficiency SCR systems and NO₂ production across the DOC.

This review summarizes the latest developments in diesel emissions regarding regulations, engines, NOx (nitrogen oxides) control, particulate matter (PM) reductions, and hydrocarbon (HC) and CO oxidation. Regulations are advancing with proposals for PN (particle number) regulations that require diesel particulate filters (DPFs) for Euro VI in 2013-14, and SULEV (super ultra low emission vehicle) fleet average light-duty (LD) emissions likely to be proposed in California for ~2017. CO₂ regulations will also impact diesel engines and emissions, probably long into the future. Engine technology is addressing these needs. Heavy-duty (HD) research engines show 90% lower NOx at the same PM or fuel consumption levels as a reference 2007 production engine. Work is starting on HD gasoline engines with promising results. In light duty (LD), engine downsizing is progressing and deNOx is emerging as a fuel savings strategy.

Two hybrid powertrain configurations, including parallel and series hybrids, were simulated for fuel economy, component energy loss, and emissions control in Class 8 trucks over both city and highway driving conditions. A comprehensive set of component models describing engine fuel consumption, emissions control, battery energy, and accessory power demand interactions was developed and integrated with the simulated hybrid trucks to identify heavy-duty (HD) hybrid technology barriers. The results show that series hybrid is absolutely negative for fuel-economy improvement of long-haul trucks due to an efficiency penalty associated with the dual-step conversions of energy (i.e. mechanical to electric to mechanical).

Response surface methodology (RSM) techniques were applied to develop a predictive model of electric vehicle (EV) energy consumption over the Environmental Protection Agency's (EPA) standardized drive cycles. The model is based on measurements from a synthetic composite drive cycle. The synthetic drive cycle is a minimized statistical composite of the standardized urban (UDDS), highway (HWFET), and US06 cycles. The composite synthetic drive cycle is 20 minutes in length thereby reducing testing time of the three standard EPA cycles by over 55%. Vehicle speed and acceleration were used as model inputs for a third order least squared regression model predicting vehicle battery power output as a function of the drive cycle. The approach reduced three cycles and 46 minutes of drive time to a single test of 20 minutes.

In this work, a dynamically loaded hydrodynamic journal bearing test rig is developed and introduced. The rig is a novel design, using a hydraulic actuator with fast acting spool valves to apply load to a connecting rod. This force is transmitted through the connecting rod to the large end bearing which is mounted on a spinning shaft. The hydraulic actuator allows for fully variable control and can be used to apply either static load in compression or tension, or dynamic loading to simulate engine operation. A variable speed electric motor controls shaft speed and is synchronized to the hydraulic actuator to accurately simulate loading to represent all four engine strokes. A high precision torque meter enables direct measurements of friction torque, while shaft position is measured via a high precision encoder.

A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.

India BS6 Stage2 (2023) regulations demand all gasoline direct injection (GDI) vehicles to meet particulate number emissions (PN) below 6x10+11# per km. Gasoline particulate filters (GPF) are a proven technology and enable high PN filtration efficiencies throughout the entire vehicle lifetime. One challenge for GPF applications could be the changing emission performance characteristics as a function of mileage due to collected ash and/or soot deposits with implications on back pressure losses. The main objective of this technical contribution is to study the above-mentioned challenges while applying Indian driving conditions and typical Indian climate and other ambient conditions. The substrate technology selected for this study is a high porosity GPF designed to enable the integration of a three-way functionality into the GPF, commonly described as catalyzed GPF (cGPF).

This review paper summarizes major developments in vehicular emissions regulations and technologies from 2014. The paper starts with the key regulatory advancements in the field, including newly proposed Non-Road Mobile Machinery regulations for 2019-20 in Europe, and the continuing developments towards real driving emissions (RDE) standards. An expert panel in India proposed a roadmap through 2025 for clean fuels and tailpipe regulations. LD (light duty) and HD (heavy-duty) engine technology continues showing marked improvements in engine efficiency. Key developments are summarized for gasoline and diesel engines to meet both the emerging NOx and GHG regulations. HD engines are demonstrating more than 50% brake thermal efficiency using methods that can reasonably be commercialized. Next, NOx control technologies are summarized, including SCR (selective catalytic reduction), lean NOx traps, and combination systems. Emphasis is on durability and control.

A 1-dimensional analytic solution has been developed to evaluate the pressure drop and filtration performance of ceramic wall-flow partial diesel particulate filters (PFs). An axially resolved mathematical model for the static pressure and velocity profiles prevailing inside wall-flow filters, with such unique plugging configurations, is being proposed for the first time. So far, the PF models that have been developed are either iterative/numerical in nature [1], or based on commercial CFD packages [7]. In comparison, an analytic solution approach is a transparent and computationally inexpensive tool that is capable of accurately predicting trends as well as, offering explanations to fundamental performance behavior. The simple mathematical expressions that have been obtained facilitate rational decision-making when designing partial filters, and could also reduce the complexity of OBD logic necessary to control onboard filter performance.

Human exposure to vehicle exhaust during engine start-up can be encountered on a daily basis in parking lots, home garages, and vehicle stop/star traffic environment. This work is the first pilot study to characterize solid particle number and size distribution during engine start-up using various light-duty vehicles with different technology engines. A total of 84 vehicles were tested in this pilot study, consisting of post-2007 diesel engines equipped with high efficiency diesel particulate filters (DPFs) as well as modern gasoline port fuel injected (PFI) and gasoline direct injected (GDI) engines equipped with three-way-catalysts (TWCs). Particle concentration from DPF equipped diesel engines were found to be the lowest, while GDI and 8-cylinder PFI engines had the highest particle emissions.

Advanced combustion strategies used to improve efficiency, emissions, and performance in internal combustion engines (IC) alter the chemical composition of engine-out emissions. The characterization of exhaust chemistry from advanced IC engines requires an analytical system capable of measuring a wide range of compounds. For many years, the widely accepted Coordinating Research Council (CRC) Auto/Oil procedure[1,2] has been used to quantify hydrocarbon compounds between C1 and C12 from dilute engine exhaust in Tedlar polyvinyl fluoride (PVF) bags. Hydrocarbons greater than C12+ present the greatest challenge for identification in diesel exhaust. Above C12, PVF bags risk losing the higher molecular weight compounds due to adsorption to the walls of the bag or by condensation of the heavier compounds. This paper describes two specialized exhaust gas sampling and analytical systems capable of analyzing the mid-range (C10 - C24) and the high range (C24+) hydrocarbon in exhaust.

This review paper summarizes major and representative developments in vehicular emissions regulations and technologies from 2015. The paper starts with the key regulatory advancements in the field, including newly proposed Euro 6 type regulations for Beijing, China, and India in the 2017-20 timeframe. Europe is continuing developments towards real driving emissions (RDE) standards with the conformity factors for light-duty diesel NOx ramping down to 1.5X by 2021. The California heavy duty (HD) low-NOx regulation is advancing and may be proposed in 2017/18 for implementation in 2023+. LD (light duty) and HD engine technology continues showing marked improvements in engine efficiency. Key developments are summarized for gasoline and diesel engines to meet both the emerging criteria and greenhouse gas regulations. LD gasoline concepts are achieving 45% BTE (brake thermal efficiency or net amount of fuel energy gong to the crankshaft) and closing the gap with diesel.

A major driving force for change in light-duty vehicle design and technology is the National Highway Traffic Safety Administration (NHTSA) and the U.S. Environmental Protection Agency (EPA) joint final rules concerning Corporate Average Fuel Economy (CAFE) and greenhouse gas (GHG) emissions for model years 2017 (MY17) through 2025 (MY25) passenger cars and light trucks. The chief goal of this current study is to compare the already rapid pace of fuel economy improvement and technological change over the previous decade to the required rate of change to meet regulations over the next decade. EPA and NHTSA comparisons of the model year 2005 (MY05) US light-duty vehicle fleet to the model year 2015 (MY15) fleet shows improved fuel economy (FE) of approximately 26% using the same FE estimating method mandated for CAFE regulations. Future predictions by EPA and NHTSA concerning ensemble fleet fuel economy are examined as an indicator of required vehicle rate-of-change.

The increasing use of diesel and gasoline particulate filters requires advanced on-board diagnostics (OBD) to prevent and detect filter failures and malfunctions. Early detection of upstream (engine-out) malfunctions is paramount to preventing irreversible damage to downstream aftertreatment system components. Such early detection can mitigate the failure of the particulate filter resulting in the escape of emissions exceeding permissible limits and extend the component life. However, despite best efforts at early detection and filter failure prevention, the OBD system must also be able to detect filter failures when they occur. In this study, radio frequency (RF) sensors were used to directly monitor the particulate filter state of health for both gasoline particulate filter (GPF) and diesel particulate filter (DPF) applications.

California Air Resources Board (CARB) has instituted requirements for on-board diagnostics (OBD) that makes a spark-plug sized exhaust particulate matter (PM) sensor a critical component of the OBD system to detect diesel particulate filter (DPF) failure. Currently, non-real-time resistive-type sensors are used by engine OEMs onboard vehicles. Future OBD regulations are likely to lower PM OBD thresholds requiring higher sensitivity sensors with better data yield for OBD decision making. The focus of this work was on the experimental evaluation of a real-time PM sensor manufactured by EmiSense Technologies, LLC that may offer such benefits. A 2011 model year on-highway heavy-duty diesel engine fitted with a diesel oxidation catalyst (DOC) and a catalyzed DPF followed by urea-based selective catalytic reducer (SCR) and ammonia oxidation (AMOX) catalysts was used for this program.

Gasoline Direct Injection (GDI) engines have been widely adopted by manufacturers in the light-duty market due to their fuel economy benefits. However, several studies have shown that GDI engines generate higher levels of particulate matter (PM) emissions relative to port fuel injected (PFI) engines and diesel engines equipped with optimally functioning diesel particulate filters (DPF). With stringent particle number (PN) regulations being implemented in both, the European Union and China, gasoline particulate filters (GPF) are expected to be widely utilized to control particulate emissions. Currently, evaluating GPF technologies on a vehicle can be challenging due to a limited number of commercially available vehicles that are calibrated for a GPF in the United States as well as the costs associated with vehicle procurement and evaluations utilizing a chassis dynamometer facility.

A production calibrated GTDI 1.6L Ford Fusion was used to demonstrate low HC, CO, NOx, PM (particulate mass), and PN (particulate number) emissions using advanced catalyst technologies with newly developed high porosity substrates and coated GPFs (gasoline particulate filters). The exhaust system consisted of 1.2 liters of TWC (three way catalyst) in the close-coupled position, and 1.6L of coated GPF in the underfloor position. The catalysts were engine-aged on a dynamometer to simulate 150K miles of road aging. Results indicate that ULEV70 emissions can be achieved at ∼$40 of PGM, while also demonstrating PM tailpipe performance far below the proposed California Air Resources Board (CARB) LEV III limit of 1 mg/mi. Along with PM and PN analysis, exhaust system backpressure is also presented with various GPF designs.

Regeneration of diesel particulate filters poses major challenges in developing the particulate matter emission control technology to meet EPA 2007/2010 emissions regulations. The problem areas are multifold due to the complexity involved in designing the filter system, developing regeneration strategies and controlling the regeneration process. This paper discusses the need for active regeneration systems. It also addresses several key limitations and trade-offs between the regeneration strategy, chemical kinetics, exhaust gas temperature and the regeneration efficiency. Passive regeneration of diesel particulate filter systems is known to be highly dependent on the engine-out [NOx/PM] ratio as well as exhaust temperature over the duty cycle. Using catalytic oxidation of auxiliary fuel injected into the system, the exhaust gas temperature can be successfully enhanced for filter regeneration.

In the present study a reduced chemical reaction mechanism for biodiesel surrogate fuel was developed and validated for multi-dimensional engine combustion simulations. An existing detailed methyl butanoate mechanism that contained 264 species and 1219 reactions was chosen to represent the oxygenated portion of the fuel. The reduction process included flux analysis, ignition sensitivity analysis, and optimization of reaction rate constants under constant volume conditions. The current reduced mechanism consists of 41 species and 150 reactions and gives predictions in excellent agreement with those of the comprehensive mechanism. In order to validate the mechanism under biodiesel-fueled engine conditions, it was combined with another skeletal mechanism for n-heptane oxidation. This combined reaction mechanism can be used to adjust the energy content of the fuel, and account for diesel/biodiesel blend engine simulations.