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This summary covers the developments from 2007 in diesel regulations, engine technology, and NOx and PM control. Regulatory developments are now focused on Europe, where heavy-duty regulations have been proposed for 2013. The regulations are similar in technology needs to US2010. Also, the European Commission proposed the first CO2 emission limits of 130 g/km, which are nearly at parity to the Japanese fuel economy standards. Engines are making very impressive progress, with clean combustion strategies in active development mainly for US light-duty application. Heavy-duty research engines are more focused on traditional approaches, and will provide numerous engine/aftertreatment options for hitting the tight US 2010 regulations. NOx control is centered on SCR (selective catalytic reduction) for diverse applications. Focus is on cold operation and system optimization. LNT (lean NOx traps) durability is quantified, and performance enhanced with a sulfur trap.

Diesel particulate filters are expected to be used on most passenger car applications designed to meet coming European emission standards, EU5 and EU6. Similar expectations hold for systems designed to meet US Tier 2 Bin 5 standards. Among the various products oxide filter materials, such as cordierite and aluminum titanate, are gaining growing interest due to their unique properties. Besides the intrinsic robustness of the filter products a well designed operating strategy is required for the successful use of filters. The operating strategy is comprised of two elements: the soot estimation and the regeneration strategy. In this paper the second element is discussed in detail by means of theoretical considerations as well as dedicated engine bench experiments. The impact the key operating variables, soot load, exhaust mass flow, oxygen content and temperature, have on the conditions inside the filter are discussed.

This review paper summarizes major developments in vehicular emissions regulations and technologies (light-duty, heavy-duty, gasoline, diesel) in 2012. First, the paper covers the key regulatory developments in the field, including finalized criteria pollutant tightening in California; and in Europe, the development of real-world driving emissions (RDE) standards. The US finalized LD (light-duty) greenhouse gas (GHG) regulation for 2017-25. The paper then gives a brief, high-level overview of key developments in LD and HD engine technology, covering both gasoline and diesel. Marked improvements in engine efficiency are summarized for gasoline and diesel engines to meet both the emerging NOx and GHG regulations. HD engines are just starting to demonstrate 50% brake thermal efficiency. NOx control technologies are then summarized, including SCR (selective catalytic reduction) with ammonia, and hydrocarbon-based approaches.

The effect of web thickness on emission performance, pressure drop, and mechanical properties was investigated for a series of catalyzed ceramic monolith substrates having cell densities of 900, 600 and 400 cpsi. As expected, thinner webs provide better catalyst light off performance and lower pressure drop, but mechanical strength generally decreases as web thickness is reduced. Good correlations were found between emission performance and geometric parameters based on bare and coated parts. An improved method for estimating the effects of cell density and web thickness on bare substrate strength is described, and the effect of porosity on material strength is also examined. New mechanical strength correlations for ceramic honeycombs are presented. The availability of a range of ceramic product geometries provides options for gasoline exhaust emission design and optimization, especially where increased levels of performance are desired.

This paper employs a systematic approach to packaging design and testing of a system and its components in order to determine the long term durability of light duty diesel filters. This effort has utilized a relatively new aluminum titanate filter technology as well as an advanced support mat technology engineered to provide superior holding force at lower temperatures while maintaining its high temperature performance. Together, these two new technologies form a system that addresses the unique operating conditions of diesel engines. Key physical properties of both the filter and the mat are demonstrated through laboratory testing. The system behavior is characterized by various laboratory techniques and validation procedures.

In this paper we present a comparison of two different approaches to model three-way catalyst. First, a numerical sample case simulating light-off is used to compare the 1D and the 2D models. The advantages of each code are discussed with respect to required input data, detail level of the output, comparability, and computation time. Thus, the 2D model reveals significant radial temperature gradients inside the monolith during light-off. In a second step, the 2D model is compared with experimental data. One set of data consists of an air/fuel ratio varying sweep at isothermal conditions. Another set was gained by emission measurements during a real driving MVEG tests with varying substrate cell density & inlet conditions. From these experiments the applicability of the model to numerical parameter studies is discussed.

In this paper, we report the modeling of the selective catalytic reduction (SCR) of NOx using ammonia on a commercial vanadia-titania based catalyst. The model combines a steady-state two-dimensional channel model with a transient two- or three-dimensional monolith model of the whole catalytic monolith converter. The reaction mechanism includes the standard and fast SCR reactions and also the high-temperature oxidation of ammonia to model the decrease in conversion observed at higher temperatures. We used in-house experimental data spanning a wide range of inlet compositions and temperatures to validate the model. The model was found to be in excellent quantitative agreement with the experimental data.

The objective of this effort was to develop an understanding of how different converter substrate cell structures impact tailpipe emissions and pressure drop from a total systems perspective. The cell structures studied were the following: The catalyst technologies utilized were a new technology palladium only catalyst in combination with a palladium/rhodium catalyst. A 4.0-liter, 1997 Jeep Cherokee with a modified calibration was chosen as the test platform for performing the FTP test. The experimental design focused on quantifying emissions performance as a function of converter volume for the different cell structures. The results from this study demonstrate that the 93 square cell/cm2 structure has superior performance versus the 62 square cell/cm2 structure and the 46 triangle cell/cm2 structure when the converter volumes were relatively small. However, as converter volume increases the emissions differences diminish.

This paper describes efforts to use computational fluid dynamics (CFD) to provide some general insights on how wall-based protuberances affect the flow and thermal fields in substrates exposed to typical diesel engine exhaust conditions. The channel geometries examined included both square and round bumps as well as an extreme tortuous path design. Three different 2d CFD laminar-flow analyses were performed: (1) a transient fluid analysis to identify the existence of any vortex shedding in the vicinity of the bumps, (2) a steady-state fluid analysis to examine the velocity and pressure fields as well as momentum transport characteristics, and (3) a thermal analysis to examine the heat transport characteristics. The model predicts no vortex shedding behind the bumps for the conditions and geometries examined, confirming the validity of a steady state approach and eliminating this possible transport mechanism.

The characterization of the thermal and vibration environment of the exhaust systems of three modern day diesel engines, with displacements ranging from 1.9 liter to 12.7 liter, was carried out to support the development of exhaust after treatment components. Tri-axial accelerometer and in pipe thermocouple measurements were recorded at several locations along the exhaust systems during vehicle acceleration and steady driving conditions up to 70 mph. The vehicles were loaded to various gross weight configurations to provide a wide range of engine load conditions. Narrow band and octave band vibration power spectral densities are presented and conclusions are drawn as to the spectral content of the exhaust vibration environment and its distribution along the exhaust system. Temperature time histories during vehicle acceleration runs are likewise presented to indicate expected peak exhaust temperatures.

This paper provides elastic analysis of compressive stresses in the matrix and skin regions of automotive substrates during 3D- and 2D-isostatic strength testing. The matrix region is treated as transversely isotropic material and the skin region as isotropic material, each with their independent elastic properties. Such a solution helps quantify load sharing by the matrix and skin regions which, in turn, affect compressive stresses in each region. The analysis shows that the tangential compressive stresses in the skin and matrix differ significantly at the interface due to high stiffness ratio of skin versus matrix. The resulting strain in the skin is more severe for thin and ultrathin wall substrates and may lead to localized bending of interfacial cells thereby inducing premature failure. Methods to reduce compressive strain in both the matrix and skin without affecting performance-related advantages are discussed.

Diesel Oxidation Catalyst in conjunction with large frontal area substrates is a key element in HDV Diesel emission control systems. This paper describes and reviews tests on a set of various Diesel Oxidation Catalyst configurations (for example cell densities), all with the same catalyst coating. The Diesel Oxidation Catalyst specimens were subjected to the European Stationary Cycle (ESC), the European Transient Cycle (ETC), and the US heavy duty Federal Test Procedure (US FTP). The focus was to study relative emissions, pressure drop, and light-off performance. All tests were conducted using the same Detroit Diesel Series 60 engine operating on ultra low sulfur diesel fuel. In addition to this, the exhaust was regulated so that the backpressure on the engine, upstream of the catalyst was also the same for all catalysts.

This paper describes a study of ternary V2O5/WO3/TiO2 SCR catalysts coated on standard Celcor® and new highly porous cordierite substrates. At temperatures below 275°C, where NOx conversion is kinetically limited, high catalyst loadings are required to achieve high conversion efficiencies. In principle there are two ways to achieve high catalyst loadings: 1. On standard Celcor® substrates the washcoat thickness can be increased. 2. With new highly porous substrates a high amount of washcoat can be deposited in the walls. Various catalyst loadings varying from 120g/l to 540 g/l were washcoated on both standard Celcor® and new high porosity cordierite substrates with standard coating techniques. Simulated laboratory testing of these samples showed that high catalyst loadings improved both low temperature conversion efficiency and high temperature ammonia storage capacity and consequently increased the overall conversion efficiency.

A concern has been expressed regarding the durability of the ceramic thin wall and ultra-thin wall substrates under severe thermal and mechanical conditions. Damage that might result from these conditions would most likely lead to a reduction in catalyst performance. One of the potential damage mechanisms for automotive catalysts is erosion resulting from the impingement of particles onto the front face of the catalyst system. A basic study of the particulate erosion phenomenon of cellular ceramic substrates was undertaken in order to determine, in a controlled setting, the substrate, particulate, and flow conditions that might bring this damage about. This report will discuss a room temperature study of the effects of particle size, particle density, gas flow rate, cellular part orientation, and cellular design parameters on the erosion of ceramic substrates.

The diesel oxidation catalyst is required to remove hydrocarbons and carbon monoxide from the diesel engine exhaust stream while minimizing the impact of all other features such as cost, space, pressure drop, weight, fuel consumption, etc. The challenge of designing a catalytic converter for a particular application then becomes to: first, understand the emissions and other performance targets and requirements for the engine; second, understand the influence each of the converter parameters has on the overall system performance and; third, optimize the system using these relationships. This paper will explore some of the considerations with respect to the second of the above challenges.

Recently, SiC has been investigated and pursued as an alternative material for diesel particulate filter (DPF) applications. SiC has acceptable physical properties such as good thermal conductivity, refractoriness, and chemical durability. Materials for DPF applications require a particular mean pore size, porosity, and permeability. In addition, these material attributes must be coupled to an appropriate thermal design so that the filter can survive the extreme temperature gradients generated during the regeneration process. In this report several approaches to making porous SiC will be discussed and performance data based on material properties and thermal design will be presented.

There is currently a need for a practical solution for NOx abatement in automotive diesel engines. Technologies developed thus far suffer from inherent technical limitations. The selective catalytic reduction (SCR) of NOx under lean conditions has been proven to be successful for stationary applications. A new approach is described to efficiently remove NOx from the exhaust of a diesel engine powered vehicle and convert it to nitrogen and oxygen. The key to the approach is the development of an on board (in-situ) ammonia generating catalyst. The ammonia is then used as a reagent to react with exhaust NO over a secondary SCR catalyst downstream. The system can remove over 85% of the exhaust NO under achievable diesel engine operating conditions, while eliminating the potential for ammonia slip with a minimal system of sensors and feedback controls.

Driven by the worldwide automotive emission regulations, ceramic substrates were developed to serve as catalyst support. Since the introduction of Standard wall substrates in 1974, substrates with thinner walls and higher cell densities have been developed to meet the tighter emission requirements; Worldwide, the amount of Thinwall and Ultrathinwall substrates in series applications is increasing continuously. The properties of the substrates determine their performance regarding pressure drop, heat-up and conversion efficiency. These properties are analyzed, as well as the packaging process for Thinwall and Ultrathinwall substrates; A new packaging technique with lower pressure load is described.

This paper examines the relative thermal shock requirements for ceramic catalysts in underbody vs. close-coupled positions. The higher operating temperature in the latter position may imply higher coefficient of thermal expansion and higher thermal stresses, depending on substrate/washcoat interaction, than those for underbody position. An analysis of thermal stresses, using relevant physical properties and temperature gradients, is presented for both close-coupled and underbody catalysts. Three different high temperature close-coupled catalysts, employing advanced ceramic substrates with 600/3, 600/4 and 900/2 cell structure, and an underbody catalyst with 400/6.5 standard ceramic substrate are examined. Such an analysis is valuable for designing the optimum aspect ratio (length/diameter) and packaging system, which will minimize thermal and mechanical stresses over the desired lifetime of 120K vehicle miles.

As demand for wall-flow Diesel particulate filters (DPF) increases, accurate predictions of DPF behavior, and in particular of the accumulated soot mass, under a wide range of operating conditions become important. This effort is currently hampered by a lack of a systematic knowledge of the accumulated particulate deposit microstructural properties. In this work, an experimental and theoretical study of the growth process of soot cakes in honeycomb ceramic filters is presented. Particular features of the present work are the application of first- principles measurement and simulation methodology for accurate determination of soot cake packing density and permeability, and their systematic dependence on the filter operating conditions represented by the Peclet number for mass transfer. The proposed measurement methodology has been also validated using various filters on different Diesel engines.