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Exposure of hydrocarbons (HCs) and particulate matter (PM) under certain real-world operating conditions leads to carbonaceous deposit formation on V-SCR catalysts and causes reversible degradation of its NOx conversion. In addition, uncontrolled oxidation of such carbonaceous deposits can also cause the exotherm that can irreversibly degrade V-SCR catalyst performance. Therefore carbonaceous deposit mitigation strategies, based on their characterization, are needed to minimize their impact on performance. The nature and the amount of the deposits, formed upon exposure to real-world conditions, were primarily carried out by the controlled oxidation of the deposits to classify these carbonaceous deposits into three major classes of species: i) HCs, ii) coke, and iii) soot. The reversible NOx conversion degradation can be largely correlated to coke, a major constituent of the deposit, and to soot which causes face-plugging that leads to decreased catalyst accessibility.

Copper- and Iron- based metal-zeolite SCR catalysts are widely used in US and European diesel aftertreatment systems to achieve drastic reduction in NOx emission. These catalysts are highly selective to N2 under wide range of operating conditions. Nevertheless, the type of transition metal has a significant impact on the key performance and durability parameters such as NOx conversion, selectivity towards N2O, hydrothermal stability, and sensitivity to fuel sulfur content. In this study, we explained the differences in the performance characteristics of these catalysts based on their relative acidic-basic nature of transition metal present in these catalysts using practically relevant gas species present in diesel exhaust such as NO2, SOx, and NH3. These experiments show that Fe-zeolite has relatively acidic nature as compared to Cu-zeolite that causes NH3 inhibition and hence explains low NOx conversion on Fe-zeolite at low temperature under standard SCR conditions.

Traditionally, most charge air coolers (CACs) have been constructed using the Nocolok aluminum brazing process. The Nocolok process uses flux, some of which remains after the manufacturing process, and migrates through the intake tract to the engine during normal use. This migration and deposition on engine components can cause a variety of issues with engine operation. Currently the only alternative to Nocolok brazed CACs for engines sensitive to flux migration is vacuum brazing, which comes at a significant price increase. In the effort to reduce cost and increase efficiency, there is interest in whether a Nocolok brazed CAC with a reduced amount of flux residue can be successfully applied to flux-sensitive engines.

Real-world operation of diesel oxidation catalysts (DOCs), used in a variety of aftertreatment systems, subjects these catalysts to a large number of permanent and temporary deactivation mechanisms. These include thermal damage, induced by generating exotherm on the catalyst; exposure to various inorganic species contained in engine fluids; and the effects of soot and hydrocarbons, which can mask the catalyst in certain operating modes. While some of these deactivation mechanisms can be accurately simulated in the lab, others are specific to particular engine operation regimes. In this work, a set of DOCs, removed from prolonged service in the field, has been subjected to a detailed laboratory study. Samples obtained from various locations in these catalysts were used to characterize the extent and distribution of deactivation.

Mitigation of ammonia slip from SCR system is critical to meeting the evolving NH₃ emission standards, while achieving maximum NOx conversion efficiency. Ammonia slip catalysts (ASC) are expected to balance high activity, required to oxidize ammonia across a broad range of operating conditions, with high selectivity of converting NH₃ to N₂, thus avoiding such undesirable byproducts as NOx or N₂O. In this work, new insights into the behavior of an advanced ammonia slip catalyst have been developed by using accelerated progressive catalyst aging as a tool for catalyst property interrogation. The overall behavior was deconstructed to several underlying functions, and referenced to an active but non-selective NH₃ oxidation function of a diesel oxidation catalyst (DOC) and to the highly selective but minimally active NH₃ oxidation function of an SCR catalyst.

Over the last two decades, global emission regulations have become more stringent and have required the use of more advanced fuel injection systems. This includes the use of tighter tolerances, more rapid injections and internal components actuated by weaker injection forces. Unfortunately, these design features make the entire system more susceptible to fuel contaminants. Over the last six years, the composition of these contaminants has evolved from hard insoluble debris, such as dust and rocks, to soluble chemical contaminants. Recent research by the diesel engine manufacturers, fuel injection equipment suppliers and the fuel and fuel additive industry has discovered a major source of the soluble chemical contaminant that leads to injector deposits to be derived from cost effective and commonly used additives used to protect against pipeline corrosion.

The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.

Advanced flow-reactor capabilities created at Cummins were applied to the study of the diesel particulate matter (soot) oxidation process. This approach complemented the on-engine studies with a number of important features, including accurate control of gas composition and soot layer temperature. Using the developed methodology for quantitative soot oxidation studies in a broad range of temperatures (200-700°C), an initial set of experiments was performed to compare the behavior of the real and model soot samples under the identical conditions (10%vol. of O2, 0-15%vol. of H2O). It was found that presence of H2O vapor synergistically enhances the rate of oxidation by O2 of the diesel soot sample. However, the behavior of the model soot sample (carbon black) was virtually not affected by H2O. Kinetic analysis of the obtained results revealed an unusual type of behavior, with the activation energy of soot oxidation increasing in the course of the experiment.

The amount of ammonia stored on the walls of the catalyst (or ammonia storage) is a parameter with significant impact on NOx reduction efficiency and undesired ammonia slip of Selective Catalytic Reduction catalysts. This makes the ammonia storage interesting for utilization in urea injection control. However, ammonia storage is not directly measurable onboard vehicles, it can only be estimated. Model-based online estimation requires models that are capable of capturing the main phenomena of the SCR and at the same time can be computed onboard vehicle. While the modeling of SCR and model-based control is well present in the literature, it is apparent that few attempts of implementing the models on production ECUs were published. This paper reviews literature on ammonia storage, outlet NH3 and NOx concentration estimation in SCR and SCR/DPF systems-including the estimation of NOx sensor cross-sensitive to NH3-in order to present the state of the art.

Oxygen storage capacity (OSC) is one of the most critical characteristics of a three-way catalyst (TWC) and is closely related to the catalyst aging and performance. In this study, a dynamic OSC model involving two oxygen storage sites with distinct kinetics was developed. The dual-site OSC model was validated on a bench reactor and a natural gas engine. The model was capable of predicting temperature dependence on OSC with H2, CO and CH4 as reductants. Also, the effects of oxygen concentration and space velocity on the amount of OSC were captured by the model. The validated OSC model was applied to simulate lean breakthrough phenomena with varied space velocities and oxygen concentrations. It is found that OSC during lean breakthrough is not a constant for a particular TWC catalyst and is dependent on space velocity and oxygen concentration. Specifically, breakthrough time exhibits a non-linear, inverse correlation to oxygen flux.

Commercial Cu-Zeolite SCR catalyst can store and subsequently release significant amount of H2O. The process is accompanied by large heat effects. It is critical to model this phenomenon to design aftertreatment systems and to provide robust tuning strategies to meet cold start emissions and low temperature operation. The complex reaction mechanism of water adsorption and desorption over a Cu-exchanged SAPO-34 catalyst at low temperature was studied through steady state and transient experiments. Steady state isotherms were generated using a gravimetric method and then utilized to predict water storage interactions with respect to feed concentration and catalyst temperature. Transient temperature programmed desorption (TPD) experiments provided the kinetic information required to develop a global kinetic model from the experimental data. The model captures fundamental characteristics of water adsorption and desorption accompanied by the heat effects.

Engine noise is one of the significant aspects of product quality for light and medium duty diesel engine market applications. Gear whine is one of those noise issues, which is considered objectionable and impacts the customer’s perception of the product quality. Gear whine could result due to defects in the gear manufacturing process and/or due to inaccurate design of the gear macro and micro geometry. The focus of this technical paper is to discuss gear whine considerations from the production plant perspective. This includes quick overview of the measurement process, test cell environment, noise acceptance criteria considerations. A gear whine case study is presented based on the data collected in the test cell at the engine plant. Gear whine data acquired on current product and next generation of prototype engines is analyzed and presented. This paper concludes by highlighting the lessons learned from the case study.

Plug flow reactors, simulating engine exhaust gas, are widely used in emissions control research to gain insight into the reaction mechanisms and engineering aspects that controls activity, selectivity, and durability of catalyst components. The choice of relevant hydrocarbon (HC) species is one of the most challenging factor in such laboratory studies, given the variety of compositions that can be encountered in different application scenarios. Furthermore, this challenge is amplified by the experimental difficulties related to introducing heavier and multi-component HCs and analyzing the reaction products.

The aging impact on oxygen storage capacity (OSC) and catalyst performance was investigated on one degreened and one aged (hydrothermally aged at 955 °C for 50 h) commercial three-way catalyst (TWC) by experiments and modeling. The difference of OSC between the degreened and aged TWCs was dependent on catalyst temperature. The largest difference was found at 600 °C, at which the amount of OSC decreased by 45.5%. Catalyst performance was evaluated through lightoff tests at two simulated engine exhaust conditions (lean and rich) on a micro-reactor. The aging impact on the catalyst performance was different under lean and rich environments and investigated separately. At the lean condition, oxidation of CO and C3H6 was significantly suppressed while oxidation of C3H8 was relatively less degraded. At the rich condition, the inhibition effect was more pronounced on the aged TWC and inhibiting hydrocarbon species from C3H6 partial oxidation can survive at temperatures up to 450 °C.

This paper presents an experimental setup and an equivalent FEM simulation methodology to accurately predict the response of Engine Control Module (ECM) assembly mounted on a commercial vehicle subjected to road vibrations. Comprehensive vibration study is carried out. It involved Modal characteristics determination followed by random vibration characterization of the ECM assembly. A hammer impact experiment is first performed in lab to estimate the natural frequencies and mode shapes of ECM assembly. Mounting conditions in test specimen are kept similar to the actual mounting settings on vehicle. Natural frequencies and mode shapes predicted from free vibration experiment are compared with finite element (FE) based modal analysis. The importance of capturing the assembly stiffness more accurately by incorporating pre-stress effects like bolt-pretension and gravity, is emphasized.

Despite drastic reduction of sulfur content in diesel fuel in the recent years, especially with the introduction of Ultra-Low Sulfur Diesel (ULSD), sulfur poisoning remains one of the most significant factors impacting performance of various catalysts in diesel aftertreatment systems. This is because even with ULSD, cumulative exposure of a catalyst over its lifetime in a heavy-duty diesel system may amount to kilograms of sulfur. In this study, we have found that the impact of sulfur poisoning on the performance of various diesel oxidation catalysts (DOC) strongly depends on the catalyst's operation history. For example, exposing a DOC to limited amounts of freshly deposited sulfur in bench reactor testing was shown to have a substantial detrimental effect. On the other hand, several samples which returned from vehicle or test-cell aging with high sulfur loading, have shown no signs of poisoning.

Automotive timing gear trains, transmission gearboxes, and wind turbine gearboxes are some of the application examples known to use interference-fit to attach the gear to the rotating shaft. This paper discusses the interference-fit joint design and the finite element analysis to demonstrate the distortion. The mechanism of tooth profile distortion due to the interference-fit assembly in gear trains is discussed by demonstrating the before and after assembly gear profile measurements. An algorithm to calculate the profile slope deviation change is presented. The effectiveness of the computational algorithm to predict the distortion is demonstrated by comparing with measurements. Finally, steps to mitigate the interference assembly effects are discussed.

An operational challenge associated with SCR catalysts is the NH3 slip control, particularly for commercial small pore Cu-zeolite formulations as a consequence of their significant ammonia storage capacity. The desorption of NH3 during increasing temperature transients is one example of this challenge. Ammonia slipping from SCR catalyst typically passes through a platinum based ammonia oxidation catalyst (AMOx), leading to the formation of the undesired byproducts NOx and N2O. We have discovered a distinctive characteristic, an overlapping NH3 desorption and oxidation, in a state-of-the-art Cu-zeolite SCR catalyst that can minimize NH3 slip during temperature transients encountered in real-world operation of a vehicle.

Experimental evaluation of soot trapping and oxidation behaviors of various diesel particulate filters (DPF) has been traditionally hampered by several experimental difficulties, such as the deposition of soot particles with well-characterized and consistent properties, and the tracking of the soot oxidation rate in real time. In the present study, an integrated bench flow-reactor system with a soot generator has been developed and its capabilities were demonstrated with regards to: Consistently and controllably loading soot on DPF samples; Monitoring the exhaust gas composition by FTIR, including quantification of the soot oxidation rate using CO and CO2; Measuring soot oxidation characteristics of various DPF samples. Soot particles were produced from a laminar propane co-flow diffusion flame.

The ammonia slip catalyst (ASC), typically composed of Pt oxidation catalyst overlaid with SCR catalyst, is employed for the mitigation of NH3 slip originating from SCR catalysts. Oxidation and SCR functionalities in an ASC can degrade through two key mechanisms i) irreversible degradation due to thermal aging and ii) reversible degradation caused by sulfur-oxides. The impact of thermal aging is well understood and it mainly degrades the SCR function of the ASC and increases the NH3 conversion to undesired products [1]. This paper describes the impact of sulfur-oxides on critical functions of ASC and on NH3 oxidation activity and selectivity towards N2, NOx and N2O. Furthermore impact of desulfation under selected conditions and its extent of ASC performance recovery is explained.