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Trivalent chromium passivation is used after zinc plating for enhancing corrosion resistance of parts. In the passivating process, the amount of dissolved metal ions (for example zinc and iron) in the passivation solution increases the longer the solution is used. This results in a reduced corrosion resistance at elevated temperatures. Adding a top coat after this process improves the corrosion resistance but has an increased cost. To combat this, we strove to clarify the mechanism of decreased corrosion resistance and to develop a trivalent chromium passivation with a higher corrosion resistance at elevated temperatures. At first, we found that in parts produced from an older solution, the passivation layer has cracks which are not seen in parts from a fresh/new solution. These cracks grow when heated at temperatures over 120 degrees Celsius.

In recent years, due to a growing demand for improvement in the performance and reliability of automotive fuel pumps and the advancement of globalization, automotive fuel pumps are being used with inferior gasolines that include more sulfur, organic acids or compounds, compared to gasolines used in general regions. Conventionally, bearings in these fuel pumps have mainly been made of sintered bronze alloy. With this bronze alloy, however, it is difficult to achieve a significant improvement in the tribology characteristics of bearings, in order to meet the demands for performance improvement, etc., and corrosion is severe in inferior gasolines that contain highly-concentrated organic acids or sulfur and the corrosion products that accompany them. Therefore, in order to obtain fine tribology characteristics and superior corrosion resistance in gasolines with highly-concentrated organic acids and sulfur, various copper-based alloys were studied using the powder metallurgy process.

PBT (polybutylene terephthalate) and epoxy adhesive, which both have superior heat resistance and environmental resistance, are a representative combination now being applied to many parts. Generally, PBT is annealed after molding at a temperature above the glass transition temperature to ensure dimensional stability when in use. But in this case, this process decreases the adhesive strength between PBT and epoxy. This study analyzes the adhesion degradation mechanism in this system and a countermeasure technology is proposed. Regarding this PBT-epoxy adhesion degradation mechanism, focus is placed on changes in the fracture surface, which is analyzed before and after annealing. From this analysis it becomes clear that generation of a WBL (weak boundary layer) is caused by non-crystallization and a migration of the PBT functional group on the adhesion surface layer.

Stringent emission regulations call for advanced catalyst substrates with thinner walls and higher cell density. However, substrates with higher cell density increase backpressure, thinner cell wall substrates have lower mechanical characteristics. Therefore we will focus on cell configurations that will show a positive effect on backpressure and emission performance. We found that hexagonal cells have a greater effect on emission and backpressure performance versus square or round cell configurations. This paper will describe in detail the advantage of hexagonal cell configuration versus round or square configurations with respect to the following features: 1 High Oxygen Storage Capacity (OSC) performance due to uniformity of the catalyst coating layer 2 Low backpressure due to the large hydraulic diameter of the catalyst cell 3 Quick light off characteristics due to efficient heat transfer and low thermal mass

Changes to OBDII regulations in North America are requiring more frequent leak checks to the evaporative emissions system. Conventional methods are unable to comply with the required 0.26 performance ratio due to various factors such as unstable tank pressure and fuel evaporation. These strict regulations require an innovative detection device. Utilizing a vacuum pump, a leak check module with high detection frequency, leak diagnostic accuracy, and reliability has been developed. In the present paper, the details of ELCM based on the depressurization method are reported together with the results of study on the pressurization method.

Combustion-pressure-data-based feedback control of fuel injection and EGR is the most promising diesel system, since it can reduce fuel consumption and emissions, as well as noise and vibration, and improve the evaluation efficiency for adapting engine performance to. We developed a combustion pressure sensor installed inside the glow plug. This is superior in maintainability and ease of installation, and can detect the combustion pressure in each cylinder at high accuracy and low cost, with no need for engine modification.

Tightening global emissions standards are driving automotive Original Equipment Manufacturer’s (OEM’s) to utilize Three Way Catalyst (TWC) aftertreatment systems that can perform with greater efficiency and greater measured control of Precious Group Metals (PGM) use. At the same time, TWC aftertreatment systems minimize exhaust system pressure drops. This study will determine the influence of catalyst substrate cell geometry on emission and PGM usage. Additionally, a study of lightoff and backpressure comparisons will be conducted. The two substrate configurations used are hex/750cpsi and square/750cpsi.

In order to comply with emission regulation, reach their profitability targets and minimise the in-use cost of their vehicles, OEMs are seeking solutions to optimise their aftertreatment systems. For Selective Catalytic Reduction (SCR) system engineers, one of the most important challenges is to reduce the system's cost, while keeping its high level of NOx emission reduction performance. Ways to achieve this cost reduction include 1. using an engine out NOx estimation model instead of a NOx sensor upstream of the SDPF (DPF coated with SCR) catalyst and 2. eliminating the Ammonia Slip Catalyst (ASC) downstream of the SDPF catalyst. Achieving these challenging targets requires actions on the complete SCR system, from the optimisation of mixing and uniformity in the SDPF catalyst to the development of robust controls. To face these challenges, a novel exhaust reverse flow concept with a blade mixer was developed.

New 2A/F systems different from usual A/F-O2 systems are being developed to cope with strict regulation of exhaust gas. In the 2A/F systems, 2A/F sensors are equipped in front and rear of a three-way catalyst. The A/F-O2 systems are ideas which use a rear O2 to detect exhaust gas leaked from three-way catalyst early and feed back. On the other hand, the 2A/F systems are ideas which use a rear A/F sensor to detect nearly stoichiometric gas discharged from the three-way catalyst accurately, and to prevent leakage of exhaust gas from the three-way catalyst. Therefore, accurate detection of nearly stoichiometric gas by the rear A/F sensor is the most importrant for the 2A/F systems. In general, the A/F sensors can be classified into two types, so called, one-cell type and two-cell type. Because the one-cell type A/F sensors don’t have hysteresis, they have potential for higher accuracy.

For the purpose of improving vehicle fuel efficiency, it is necessary to reduce energy loss in the alternator. We have lowered the resistance of the rectifying device and connecting components, and control the rectifying device with an IC to reduce rectification loss. For the package design, we have changed the structure of the part on which the rectifying device is mounted into a high heat dissipation type. The new structure has enabled optimizing the size of the rectifying device, resulting in the reduction of size of the package. In addition, the rectifying device is mounted using a new soldering material and a new process, which has improved the reliability of the connection. Moreover, since the alternator has introduced a new system, the controller IC has a function for preventing malfunction of the rectifying device and a function for detecting abnormalities, in order to ensure safety.

Exhaust Gas Recirculation (EGR) systems reduce exhaust emissions and improve fuel efficiency. Recently, the number of EGR system installed vehicles has been increasing, especially for gasoline engine systems. One of the major causes of decreasing EGR function is deposit accumulation on a gas passage. The deposit consists mainly of hydrocarbons which are degradation products of fuel, thus the amount of deposit seems to be strongly affected by fuel compositions. Unfortunately there are not as many studies on EGR deposits with gasoline fuel as there are with diesel fuel. In this study, the influence of gasoline fuel compositions, especially aromatics which are major components of EGR gas, on chemical structures of the deposit were investigated. To clarify the accumulation mechanism of EGR deposits, a thermal oxidative degradation test with an autoclave unit and an actual gasoline engine test were employed.

The number of idle-stop vehicles is rapidly increasing in recent years, and air-conditioning technologies that extend engine stopped time while maintaining the cabin comfort are required. When the engine stops during idle- stop mode, the air conditioner also stops functioning. To maintain cabin comfort, the engine is restarted to work the air-conditioning cycle, which reduces the fuel saving effects. As a countermeasure, a cold storage air conditioning system has been proposed. The system extends engine non-operation time by using cold storage for generating cool air while the engine is stopped. We have integrated this technology into an evaporator, which is used in the air-conditioning cycle, and the system has a short cold storage period and a necessary cold release period. This report describes its concept and effects.

As a method of maintaining thermal sensation and comfort inside a passenger compartment, not only a conventional HVAC system but also a combination of a HVAC system and other devices such as seat heaters, a steering wheel heater, ventilation seats are increasing. This research developed a method to evaluate thermal sensation of a human body when using these various thermal control devices. This method can evaluate the heat balance of the human body by calculating the amount of heat exchange between a human body and the external environment, and it takes into consideration the influence of heat exchange by heat conduction with seats or a steering wheel. The human thermal model is made by dividing a human body into various segments, and it is the model that considers heat transport by blood flow for each segment.

In SI engines with port injection system, the injected fuel spray adheres surely on the port wall and the inlet valve, consequently, the spray-wall interaction process leads to the generation of unburned hydrocarbons and uncontrollable mixture formation. This paper deals with the fuel mixture preparation process including basic research on characteristics of the wall-wetted fuel film on a flat wall inside a constant volume vessel. In the experiments, iso-octane mixed with biacetyl as a tracer dopant was injected through a pintle type injector against a flat glass wall under the ambient conditions of atmospheric pressure and room temperature. The thickness of the adhered fuel film on the wall was quantitatively measured by using laser induced fluorescence (LIF) technique, which provides 2-D distribution information with high special resolution as a function of the injection duration, the impingement distance from the injector to the wall, and the impingement angle against the wall.

With the global adoption of diesel common rail systems and the wide variation in composition of local commercial fuels, modern fuel injection systems must be robust against diverse fuel properties. To bridge the knowledge gap on the effects of compositional variation for real commercial fuels on spray combustion characteristics, the present work quantifies ignition and soot formation/oxidation in three unique, international diesel blends. Schlieren imaging, excited-state hydroxyl radical (OH*) chemiluminescence imaging and diffused back-illumination extinction imaging were employed to quantify vapor penetration, ignition, and soot formation and oxidation for high-pressure sprays in a constant-volume, pre-burn chamber. The three fuels were procured from Finland, Japan and Brazil and have cetane numbers of 64.1, 56.1 and 45.4, respectively.

This paper presents an improvement in the accuracy of NOx sensors at high NOx concentration regions by optimizing the manufacturing process, sensor electrode materials and structure, in order to suppress the deterioration mechanism of sensor electrodes. Though NOx sensors generally consist of Pt/Au alloy based oxygen pump electrodes and Pt/Rh alloy based sensor electrodes, detailed experimental analysis of aged NOx sensors showed changes in the surface composition and morphology of the sensor electrode. The surface of the sensor electrode was covered with Au, which is not originally contained in the electrode, resulting in a diminished active site for NOx detection on the sensor electrode and a decrease in sensor output. Theoretical analysis using CAE with molecular dynamics supported that Au tends to be concentrated on the surface of the sensor electrode.

In recent years, from a viewpoint of global warming and energy issues, the need to improve vehicle fuel economy to reduce CO2 emission has become apparent. One of the ways to improve this is to enhance engine thermal efficiency, and for that, automakers have been developing the technologies of high compression ratio and dilute combustion such as exhaust gas recirculation (EGR), and lean combustion. Since excessive dilute combustion causes the failure of flame propagation, combustion promotion by intensifying in-cylinder turbulence has been indispensable. However, instability of flame kernel formation by gas flow fluctuation between combustion cycles is becoming an issue. Therefore, achieving stable flame kernel formation and propagation under a high dilute condition is important technology.

A new exhaust emission control system has been developed which complies with the world's most severe emission standard: CARB PZEV. Leaner combustion in cold condition was enabled and rapid warm-up of a close-coupled catalyst was realized by utilizing a newly developed Intake Air Control Valve (IACV) system and hyper-atomization fuel injector. In addition, the newly developed HC adsorbing type 3-way catalyst realized cold HC reduction at lower cost. For further reduction of the exhaust emission, the Variable Valve Timing-Intelligent (VVT-i) system was positively operated immediately after the cold start. By the suitable operation of Variable Valve Timing (VVT), the blow-back from the cylinder enhanced the fuel atomization and re-burning of remaining unburned hydrocarbons (HCs), and increased in-cylinder residual gas reduces NOx.

Emission regulations in many countries and regions around the world are becoming stricter in reaction to the increasing awareness of environment protections, and it has now become necessary to improve the performance of catalytic converters to achieve these goals. A catalytic converter is composed of a catalytically active material coated onto a ceramic honeycomb-structured substrate. Honeycomb substrates play the role of ensuring intimate contact between the exhaust gas and the catalyst within the substrate’s flow channels. In recent years, high-load test cycles have been introduced which require increased robustness to maintain low emissions during the wide range of load changes. Therefore, it is extremely important to increase the probability of contact between the exhaust gas and catalyst. To achieve this contact, several measures were considered such as increasing active sites or geometrical surface areas by utilizing substrates with higher cell densities or larger volumes.

Toyota Motor Corporation has developed the new compact-class hybrid vehicle (HV). This vehicle incorporates a new hybrid system for the improvement of fuel efficiency. For this system, a new Power Control Unit (PCU) is developed. The feature of the PCU is downsizing, lightweight, and high efficiency. In expectation of rapid popularization of HV, the aptitude for mass production is also improved. The PCU, which plays an important role in the new system, is our main focus in this paper. Its development is described.