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The subject of this work is 3D numerical simulations of combustion and soot emissions for a passenger car diesel engine. The CFD code STAR-CD version 3.26 [1] is used to resolve the flowfield. Soot is modeled using a detailed kinetic soot model described by Mauss [2]. The model includes a detailed description of the formation of polyaromatic hydrocarbons. The coupling between the turbulent flowfield and the soot model is achieved through a flamelet library approach, with transport of the moments of the soot particle size distribution function as outlined by Wenzel et al. [3]. In this work we extended this approach by considering acetylene feedback between the soot model and the combustion model. The model was further improved by using new gas-phase kinetics and new fitting procedures for the flamelet soot library.

Combination of an NOx storage and reduction catalyst (NSRC, called also lean NOx trap, LNT) and a catalyst for the selective catalytic reduction of NOx by NH₃ (NH₃-SCR) offers a potential to significantly increase the efficiency of NSRC-based exhaust gas aftertreatment systems. Under most situations the SCR catalyst is able to adsorb the NH₃ peaks generated in the NSRC during the regeneration and utilize it for additional NOx reduction in the course of the consequent lean phase. This synergy becomes more important with the aged NSRC, where generally lower NOx conversions and higher NH₃ yields in wider range of operating temperatures are observed (in comparison with the fresh or de-greened NSRC). In this paper we present global kinetic models for the NSRC (Pt/Ba/Ce/gγ-Al₂O₃ catalyst type) and NH₃-SCR (Fe-ZSM5 catalyst type).

The future emission regulation (BS V) in India is expected to create new challenges to meet the particulate matter (PM) limit for diesel cars. The upcoming emission norms will bring down the limit of PM by 80 % when compared to BS IV emission norms. The diesel particulate filter (DPF) is one of the promising technologies to achieve this emission target. The implementation of DPF system into Indian market poses challenges against fuel quality, driving cycles and warranty. Hence, it is necessary to do a detailed on-road evaluation of the DPF system with commercially available fuel under country specific drive cycles. Therefore, we conducted full vehicle durability testing with DPF system which is available in the European market to evaluate its robustness and reliability with BS III fuel (≤350ppm sulfur) & BS IV (≤50ppm sulfur) fuel under real Indian driving conditions.

A powerful and efficient turbocharger turbine benefits the engine in many aspects, such as better transient response, lower NOx emissions and better fuel economy. The turbine performance can be further improved by employing secondary flow injection through an injector over the shroud section. A secondary flow injection system can be integrated with a conventional turbine without affecting its original design parameters, including the rotor, volute, and back disk. In this study, a secondary flow injection system has been developed to fit for an asymmetric twin-scroll turbocharger turbine, which was designed for a 6-cylinder heavy-duty diesel engine, aiming at improving the vehicle’s performance at 1100 rpm under full-loading conditions. The shape of the flow injector is similar to a single-entry volute but can produce the flow angle in both circumferential and meridional directions when the flow leaves the injector and enters the shroud cavity.

A numerical model for a diesel oxidation catalyst (DOC) is presented. It is based on a spatially 1D, physical and chemically based modeling of the relevant processes within the catalytic monolith. A global reaction kinetic approach has been chosen to describe the chemical reactions. Water condensation and evaporation was also considered, in order to predict the cold start behavior. Reaction kinetic parameters have been evaluated from a series of laboratory experiments. A correlation between the kinetic parameters and the noble metal loading was developed. The model was used in combination with a SCR-Model to study the influence of changes of noble metal loading and DOC volume on the overall transient NOx performance of a DOC+DPF+SCR system.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

While the market share for diesel engines for LD vehicles in Europe has grown continuously in the past years, the market share in North America is still negligible. Until now, it has been possible to fulfill the limits for nitrogen oxides (NOx) both in Europe and in North America by engine measures alone, without using an active NOx aftertreatment system. With the introduction of Tier II Bin 8 and Tier II Bin 5 emissions legislation in the US in 2007, most new diesel applications will now require NOx aftertreatment. One of the possible technologies for the reduction of nitrogen oxides in lean exhaust gas is the NOx storage catalyst which has become the generally-accepted choice for engines with gasoline direct injection systems and which is also utilized in the current diesel Bluetec I systems from Daimler. For heavier applications urea-SCR is the preferred technology to fulfill NOx legislation limits.

Diesel engines have a strong contribution to the CO2 reduction in Europe in the past years. To enable these C02 reduction potential to the US market Mercedes Benz developed the BLUETEC technology for light duty diesel engines. The BLUETEC technology contains an optimized diesel engine and combustion system, an aftertreatment system with DOC, DPF and an active SCR catalyst with AdBlue Dosing System and an enhanced ECU functionality and calibration. For fulfilling the world strongest emission limits of the US legislation there have to be solutions developed for the handling of AdBlue under cold climate below -11°C, managing the refilling event, and the onboard diagnostic. To ensure the emission stability over full useful life on high NOx conversions level, intensive testing of the catalyst technology had to be done. In addition there are self learning functionalities for adapting the dosing strategy to ensure the maximum NOx performance.

The new Sprinter targets the USA and Canada markets nationwide to reconfirm Daimlers statement for Diesel engine in vans. Consequentially, the MY2007 Sprinter follows his successful predecessor as again the first - and up to now the only - Diesel vehicle in its class now meeting even the strict EPA07 requirement in California. For the growing market in North America an unique development for the successor for the previous 5-cylinder Diesel Sprinter had been made. The new 3 liter V6 Diesel engine is based on numerous corporate wide versions from Mercedes and Chrysler Passenger cars and SUVs and has its roots also in smaller and larger Mercedes vans. Effective January 2007 the NAFTA04 requirements have been replaced by the NAFTA07 values. Meeting those led to significant changes of the latest Sprinter in European EURO4 version. Both, engine and exhaust hardware as well as the ECU-data had been modified consequentially.

Catalyzed wall-flow particulate filters are increasingly applied in diesel exhaust after-treatment for multiple purposes, including low-temperature catalytic regeneration, CO and hydrocarbon conversion, as well as exothermic heat generation during forced regeneration. In order to optimize Precious Metals usage, it may be advantageous to apply the catalytic coating non-uniformly in the DPF, a technology referred to as “catalyst zoning”. In order to simulate the behavior of such a filter, one has to consider coupled transport-reaction modeling. In this work, a previously developed model is calibrated versus experimental data obtained with full-scale catalyzed filters on the engine dynamometer. In a next step, the model is validated under a variety of operating conditions using engine experiments with zoned filters. The performance of the zoned catalyst is analyzed by examining the transient temperature and species profiles in the inlet and outlet channels.

In order to control NOx reduction with NOx storing lean NOx traps (LNT), a gas sensor downstream of the LNT is presently preferred. It is a disadvantage that no means are available to gauge directly the LNT NOx loading level and the catalyst quality. The presented novel sensor consists of interdigital electrodes that are deposited on a planar substrate. On its reverse side, a temperature sensor is applied. Both sides are covered with the original catalyst coating, allowing detecting directly electrical impedance and temperature of the coating. Such sensors were integrated in different positions of an LNT. It is shown in synthetic exhausts as well as in engine tests that in-situ measurements of the electrical impedance of the LNT coating are appropriate to determine directly the catalyst status. Hence, the local degree of NOx loading as well as the local regeneration status can be measured. Furthermore, sulfur poisoning, desulfurization, and thermal ageing can be directly seen.

Beginning in 2010, Daimler's well-known Diesel Sprinter van has to fulfill the new and clearly tighter NOx emission standards of NAFTA10 (EPA, CARB). This requires an integrated approach of further engine optimizations and the implementation of an innovative exhaust aftertreatment technology. The goal was to develop an overall concept which meets simultaneously the tightened emission standards (including OBD limits) and the increasing customer demands of more power and torque without losing the high fuel efficiency of the small and highly efficient 3-liter V6 diesel engine OM642, which already has been installed in the NAFTA07 Sprinter. In the early stages of the concept phase, the most appropriate NOx aftertreatment technology and certification form (engine or vehicle) had to be selected for this specific vehicle class in the van segment with enhanced requirements to durability, economical efficiency and specific driving behavior.

For medium- and heavy-duty diesel engines, the development of new catalyst technologies and particulate filters is necessary to fulfill increasingly stringent emission regulations. An important aspect is the durability of the after-treatment system and therefore its efficiency over lifetime. Lubrication oil additives contain components such as phosphorous or zinc to ensure engine durability. Diesel oxidation catalyst (DOC) and coated diesel particulate filter (cDPF) catalytic coatings are negatively influenced by contamination on the surface with these components (chemical ageing). The components have a negative impact on the exhaust after-treatment systems performance. Additionally the cDPF is filled with oil ash. Engine tests are conducted to analyze the effect of lubrication oil additives on after-treatment system performance. In one study, lubrication oil with increased sulfur ash content is used.

Mercedes-Benz BlueTEC passenger cars have been on the cutting edge of clean diesel technology since 2006. These BlueTEC vehicles furthermore passed millions of kilometers in the hands of customers. SCR-equipped passenger cars already meet the most stringent exhaust emissions standards in international markets such as the USA, Europe and Japan. Diesel engines with BlueTEC technology also reduce CO₂ emissions and provide the high torque and performance associated with the diesel engine in addition to keeping exhaust emissions at the lowest possible level. Nowadays the requirements for SCR emission concepts are increasing continuously. In fact the emission legislation is getting stricter with the LEVIII emission standards in 2015. Additionally the requirements and effort for on-board diagnosis are increasing year after year. In combination with ambitious CO₂ targets all these issues constitute the further challenges of BlueTEC SCR emission concepts for worldwide markets.

The objective of this work was the development of a real-time capable in-cylinder pressure based diesel engine-out PM estimator. Two types of experimental passenger car DI diesel engines, equipped with in-cylinder pressure sensors have been used for the PM estimator development. Measurements have been taken during steady state and transient operation on an engine test bench. Using the Engine ECU signals and in-cylinder pressure data new parameters have been derived and used as inputs for an exponential zero dimensional modeling approach. Good correlation between the estimated and measured PM has been achieved for various experiments, not only for steady state operation points but also for transient measurements. Particularly, the model delivers good qualitative results, as well as good quantitative results in some regions. PM gradients, that is, the tendency of PM to increase or decrease from one engine operating point to another are represented successfully.

Lubricant oil derived ash deposits still represent a major issue in diesel particulate filter operation in vehicles. In literature various ash deposition patterns are described. The two boundary deposition patterns are (a) wall layer and (b) filling at the back end of the inlet channels. The patterns are often associated with different regeneration methods. Continuous regeneration is supposed to result in a homogeneous ash layer, whereas periodic (active) regeneration is reported to result in back end filling. The current contribution describes the basic mechanisms associated with ash transport phenomena in particle filters. On the basis of (a) frequency of ash exposure to flow (b) ash particle structure re-entrainment and finally (c) axial ash transport the different deposition pattern can be explained. Exposure to flow accomplished by periodical soot removal, either by passive or active regeneration is the first step.

In the field of heavy-duty applications almost all engines apply the compression ignition principle, spark ignition is used only in the niche of CNG engines. The main reason for this is the high efficiency advantage of diesel engines over SI engines. Beside this drawback SI engines have some favorable properties like lower weight, simple exhaust gas aftertreatment in case of stoichiometric operation, high robustness, simple packaging and lower costs. The main objective of this fundamental research was to evaluate the limits of a SI engine for heavy-duty applications. Considering heavy-duty SI engines fuel consumption under full load conditions has a high impact on CO₂ emissions. Therefore, downsizing is not a promising approach to improve fuel consumption and consequently the focus of this work lies on the enhancement of thermal efficiency in the complete engine map, intensively considering knocking issues.

In the digital prototype development process of a new Mercedes-Benz, thermal protection is an important task that has to be fulfilled. In the early stages of development, numerical methods are used to detect thermal hotspots in order to protect temperature sensitive parts. These methods involve transient full Vehicle Thermal Management (VTM) simulations to predict dynamic vehicle heat-up during critical load cases. In order to simulate thermal control mechanisms, a coupled 1D to 3D thermal vehicle model is built in which the coolant and oil circuit of the engine, as well as the exhaust flow are captured in detail. When performing a transient 3D VTM analysis, the conduction and radiation phenomena are simulated using a transient structure model while the convective phenomena are co-simulated in a steady state fluid model. Both models are brought to interaction at predetermined points by an automatized coupling method.

The automotive industry uses supercharging in combination with various EGR strategies to meet the increasing demand for Diesel engines with high efficiency and low engine emissions. The charge air is heated by the EGR and the compression in the turbocharger to such an extent that high NOx emissions and a reduction in engine performance occurs. For this reason, the charge air cooler cools down the charge air before it enters the air intake manifold. In case of low pressure EGR, the charge air possesses a high moisture content and under certain operating conditions an accumulation of condensate takes place within the charge air cooler. During demanding engine loads, the condensate is entrained from the charge air cooler into the combustion chamber, resulting in misfiring or severe engine damage.

A raise of efficiency is the strongest selling point concerning the total cost of ownership (TCO), especially for commercial vehicles (CV). Accompanied by legislations, with contradictive development demands, satisfying solutions have to be found. The analysis of energy losses in modern engines shows three influencing parameters. Wall heat transfer (WHT) losses are awarded with the highest optimization potential. Critical for the occurrence of these losses is the WHT, which can be described by representing coefficients. To reduce WHT accompanying losses a decrease of energy transfer between combustion gas and combustion chamber wall is necessary. A measurement of heat fluxes is necessary to determine the WHT relations of the combustion chamber in an engine. As this has not been done for a Heavy-Duty (HD) engine, with peak pressures up to 250 bar, an increased in-cylinder turbulence and high exhaust gas recirculation (EGR)-rates before, it is presented in the following.