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The implementations of the Tier 2 and LEVII emission levels require fast catalyst light-off and fast closed loop control through high-speed engine management. The paper describes the development of innovative catalyst designs. During the development thermal and mechanical boundary conditions were collected and component tests conducted on test rigs to identify the emission and durability performance. The products were evaluated on a Super Imposed Test Setup (SIT) where thermal and mechanical loads are applied to the test piece simultanously and results are compared to accelerated vehicle power train endurance runs. The newly developed light-off catalyst with Perforated Foil Technology (PE) showed superior emission light-off characteristic and robustness.

An experiment was performed with a 1.3L catalytic converter design containing a front and rear catalyst each having a volume of 0.65 liters. This investigation varied the front catalyst parameters to study the effects of 1) substrate diameter, 2) substrate cell density, 3) Pd loading and 4) Rh loading on the FTP emissions on three different vehicles. Engine displacement varied from 2.4L to 4.7L. Eight different converters were built defined by a Taguchi L-8 array. Cold flow converter restriction results show the tradeoff in converter restriction between substrate cell density and substrate diameter. Vehicle FTP emissions show how the three vehicles are sensitive to the four parameters investigated. Platinum Group Metals (PGM) prices and Federal Test Procedure (FTP) emissions were used to define the emission value between the substrate properties of diameter and cell density to palladium (Pd) and rhodium (Rh) concentrations.

Vehicle exhaust flow is difficult to measure accurately and with high precision due to the highly transient nature of the cyclic events which are dependent on engine combustion parameters, varying exhaust gas compositions, pulsation effects, temperature and pressure. Bag mini-diluter (BMD) is becoming one of the few technologies chosen for SULEV and PZEV exhaust emission measurement and certification. A central part of the BMD system is an accurate and reliable exhaust flow measurement which is essential for proportional bag fill. A new device has been developed to accurately and reliably calibrate exhaust flow measurement equipments such as the E-Flow. The calibration device uses two different size laminar flow elements (LFE), a 40 CFM (1.13 m3/min) LFE for low end calibration and a 400 CFM (11.32 m3/min) LFE for higher flows. A blower is used to push flow through a main flow path, which then divides into two flow pathways, one for each of the two LFE's.

Automakers in the United States have started using bag mini-diluters (BMD) for developing, testing and certifying vehicles, to meet PZEV and SULEV regulation requirements. The BMD system which is a new technology developed by AIGER, is being used as an alternative to the traditional CFV/CVS system for accurate ultra low-level emission measurement. BMD system has shown to have considerable advantage over CFV/CVS system, especially at ULEV/SULEV emission levels. This paper details modifications and diagnostic checks conducted with the existing BMD system at the DaimlerChrysler Tech Center emissions facility, Auburn Hills, Michigan. This paper also discusses possible scenarios where the BMD system at DaimlerChrysler could give erroneous results due to system setup, optimization issues and equipment limitations.

In order to match catalyst OBDII conditions the common procedure is oven aging with air, which is not suitable for complete converter systems due to mantle corrosion. The goal was, therefore, to find an alternative procedure to ensure a defined catalyst aging that would match 1,75 times the emission standard and is also good for SULEV. The new procedure currently being developed allows the aging of metal and ceramic catalysts as well as complete catalyst systems. The paper will present the aging process, emission data of fresh and aged catalysts and the feedback to the test car OBDII system.

Catalyst systems utilizing ceramic and metallic substrates were compared to assess the influence of various substrate parameters on the exhaust gas conversion efficiency and flow restriction. In particular, the substrate surface area, substrate specific heat capacity, and substrate volume were all evaluated for their importance in estimating the conversion efficiency of the catalyst system. Additionally, substrate open frontal area and cell hydraulic diameter were compared against exhaust restriction performance.

The future of diesel-engine-powered passenger cars and light-duty vehicles in the United States depends on their ability to meet Federal Tier 2 and California LEV2 tailpipe emission standards. The experimental purpose of this work was to examine the potential role of fuels; specifically, to determine the sensitivity of engine-out NOx and particulate matter (PM) to gross changes in fuel formulation. The fuels studied were a market-average California baseline fuel and three advanced low sulfur fuels (<2 ppm). The advanced fuels were a low-sulfur-highly-hydrocracked diesel (LSHC), a neat (100%) Fischer-Tropsch (FT100) and 15% DMM (dimethoxy methane) blended into LSHC (DMM15). The fuels were tested on modern, turbocharged, common-rail, direct-injection diesel engines at DaimlerChrysler, Ford and General Motors. The engines were tested at five speed/load conditions with injection timing set to minimize fuel consumption.

Adding oxygenates to diesel fuel has shown the potential for reducing particulate (PM) emissions in the exhaust. The objective of this study was to select the most promising oxygenate compounds as blending components in diesel fuel for advanced engine testing. A fuel matrix was designed to consider the effect of molecular structure and boiling point on the ability of oxygenates to reduce engine-out exhaust emissions from a modern diesel engine. Nine test fuels including a low-sulfur (∼1 ppm), low-aromatic hydrocracked base fuel and 8 oxygenate-base fuel blends were utilized. All oxygenated fuels were formulated to contain 7% wt. of oxygen. A DaimlerChrysler OM611 CIDI engine for light-duty vehicles was controlled with a SwRI Rapid Prototyping Electronic Control System. The base fuel was evaluated in four speed-load modes and oxygenated blends only in one mode. Each operating mode and fuel combination was run in triplicate.

The development of diesel powered passenger cars is driven by the enhanced emission legislation. To fulfill the future emission limits there is a need for advanced aftertreatment devices. A comprehensive study was carried out focusing on the improvement of the DOC as one part of these systems, concerning high HC/CO conversion rates, low temperature light-off behaviour and high temperature aging stability, respectively. The first part of this study was published in [1]. Further evaluations using a high temperature DPF aging were carried out for the introduced systems. Again the substrate geometry and the catalytic coating were varied. The results from engine as well as vehicle tests show advantages in a highly systematic context by changing either geometrical or chemical factors. These results enable further improvement for the design of the exhaust system to pass the demanding emission legislation for high performance diesel powered passenger cars.

Measuring vehicle exhaust volumetric flow rate accurately and precisely is critical in calculating the correct vehicle modal and bag mini-diluter exhaust emission constituent masses. It is also instrumental in engine calibration practices. Currently, DaimlerChrysler's Emission and Certification Lab in Auburn Hills, Michigan utilizes constant volume sampling bag systems to certify vehicles but the automotive technological trend is heading toward the bag mini-diluter for greater precision at low emission levels. The bag mini-diluters, as well as the modal sampling system, used extensively in vehicle development testing, rely on exhaust flow rate measurement by means of a direct vehicle exhaust flow meter named E-Flow. The E-Flow has few limitations such as flow profile instability at low idle flow rates and reaction to resonating pressure waves in the exhaust system.

A Robust Engineering experiment was performed to determine the effects PGM loading and placement on the FTP emissions of a 4 cylinder 2.4L and two 8 cylinder 4.7L vehicles. 1.3L catalytic converters were used containing a front and rear catalyst of equal volume. The experiment is defined by a Taguchi L-8 array. Eight different combinations of catalyst PGM loadings were aged and evaluated. Results show that nmHC and NOx emissions are predominately affected by the PGM loading of the front catalyst. The rear catalyst is insensitive to either Pt or Pd which can be used at low concentrations. Results also compare the benefits of Pd and Rh to reduce emissions. Confirmation runs suggest that significant reductions in PGM cost can be achieved over baseline designs.

A new family of automotive three-way conversion (TWC) catalyst technologies has been developed using a Precision Metal Addition (PMA) process. Precious metal (PGM) fixation onto the support occurs during the PMA step when the PGM is added to the slurry immediately prior to application to the monolith substrate. PMA slurries can be prepared with high precision and the slurry manufacturing process is greatly simplified. Further, it has been found that with the use of new generation washcoat (WC) materials, the same WC composition can be used for all three PGMs - Pt, Pd & Rh. Negative interactions between Pd and Rh in the same WC layer do not occur, providing advantages over older technologies. Thus, new WC compositions coupled with the PMA process offers precious metal flexibility. This FlexMetal family of catalyst technologies includes single layer Pd-only, Pd/Rh and Pt/Rh and dual layer bi-metal Pd/Rh and Pt/Rh and tri-metal Pt/Pd/Rh.

Tests were conducted at independent laboratories on a patented ashless additive technology designed generically for Fuel Charter I, II and III diesel fuels as defined by, AAMA (American Automobile Manufacturers Association), ACEA (European Automobile Manufacturers Association), EMA (Engine Manufacturers Association) & JAMA (Japan Automobile Manufacturers Association). The instantaneous effect of these additives in 6 light and 2 heavy duty engines in reducing particle number and particle mass emissions were measured as were mileage accumulation effects. Emission tests confirmed PM reduction of up to 19 % from both light duty vehicles tested under ECE15+EUDC or MVEG cycles and heavy-duty engines tested under the R49 or FiGE cycle. The results also indicated that such reduction had negligible or possibly a beneficial effect on NOx emissions.

In a consortium of European industrial partners and research institutes, a combination of industrial development and scientific research was organised. The objective was to improve the catalytic NOx conversion for lean burn cars and heavy-duty trucks, taking into account boundary conditions for the fuel consumption. The project lasted for three years. During this period parallel research was conducted in research areas ranging from basic research based on a theoretical approach to full scale emission system development. NOx storage catalysts became a central part of the project. Catalysts were evaluated with respect to resistance towards sulphur poisoning. It was concluded that very low sulphur fuel is a necessity for efficient use of NOx trap technology. Additionally, attempts were made to develop methods for reactivating poisoned catalysts. Methods for short distance mixing were developed for the addition of reducing agent.

Computer controls are increasingly being employed in systems ranging from simple to very complex. A new trend is to extend these computer systems to include monitoring schemes to detect malfunctions. An example is provided by new automobiles sold in the US, Canada, and Europe. By law they must include “on-board diagnostics” designed to detect certain malfunctions in the powertrain system that may cause excessive emissions. The present article outlines some of the fundamental concepts of system's monitoring and general principles for the design of such monitors.

Since several decades, passenger cars and light duty vehicles (LDV) with spark-ignited engines reach full pollutant conversion during warm up conditions; the major challenge has been represented by the cold start and warming up strategies. The focus on technology developments of exhaust after treatment systems have been done in the thermal management in order to reach the warm up conditions as soon as possible. A new challenge is now represented by the Real Driving Emission (RDE) Regulation as this bring more various, and not any longer cycle defined, cold start conditions. On the other hand, once the full conversion has been reached, it would be beneficial for many Exhaust After Treatment System (EATS) components, e.g. for overall durability if the exhaust gas temperature could be lowered. To take significant further emission steps, approaching e.g. zero emission concepts, we investigate the use of Electrical Heating Catalyst (EHC) also including pre-heating.