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This paper examines the issues concerning particulate matter (PM) emissions measurement at the 3 mg/mi level proposed as the future LEV III standard. These issues are general in nature, but are exacerbated at the low levels contemplated for upcoming emissions standards. They are discussed in the context of gasoline direct injection (GDI) engines, where they can have an important impact on the continued development of this technology for improved fuel economy. GDI particulate emissions, just as engine-out diesel PM, contain a high fraction of soot. But the total PM mass is significantly lower than from diesel engines, and there can be significant variations in emissions rate and apparent PM composition between cold-start and running emissions. PM emissions levels depend on sampling method and location. As a result, there can be substantial differences in PM sampled and diluted directly at the exhaust pipe, as opposed to measurements from a dilution tunnel.

Future LEV-III tailpipe (TP) emission regulations pose an enormous challenge forcing the fleet average of light-duty vehicles produced in the 2025 model year to perform at the super ultralow emission vehicle (SULEV-30) certification levels (versus less than 20% produced today). To achieve SULEV-30, regulated TP emissions of non-methane organic gas (NMOG) hydrocarbons (HCs) and oxygenates plus oxides of nitrogen (NOx) must be below a combined 30 mg/mi (18.6 mg/km) standard as measured on the federal emissions certification cycle (FTP-75). However, when flex-fuel vehicles use E85 fuel instead of gasoline, NMOG emissions at cold start are nearly doubled, before the catalytic converter is active. Passive HC traps (HCTs) are a potential solution to reduce TP NMOG emissions. The conventional HCT design was modified by changing the zeolite chemistry so as to improve HC retention coupled with more efficient combustion during the desorption phase.

The high conversion efficiency required by the modern three-way catalyst (TWC) is dependent on oxygen storage material functionality and capacity. To successfully model a TWC, it is critical that the oxygen storage function in the catalyst be adequately represented. The original oxygen storage model (a simple “bucket” model) included in one of Ford's TWC models, SIMTWC, was developed for vehicle programs meeting LEV emission standards. Application of SIMTWC to test data from vehicles targeting more stringent emission standards, such as ULEV and PZEV, revealed limitations in the accuracy of the original bucket model. To address these limitations, an improved kinetic model of oxygen storage is being developed. This new model is more kinetically-detailed than the old model.

Global concerns involving smog, ozone formation, carcinogens and greenhouse gases have produced increasingly stringent governmental emission regulations worldwide. In the United States, the Environmental Protection Agency (EPA) introduced Tier II emissions regulations and the California Air Resources Board (CARB) established Low Emission Vehicles (LEV II) and Partial Zero Emission Vehicles (PZEV) legislation. These initiatives have created the most stringent emissions regulations to date. Vehicle manufacturers have had to improve their evaporative emission control systems to comply with these standards. The evaporative emission control system is engineered to protect our environment from fuel vapor emissions. The carbon canister is the most important component of the evaporative emissions system due to its ability to capture fuel vapors continuously during the life of the vehicle. Ford Motor Company redesigned its carbon canisters after utilizing Experimental Design techniques.

Vehicle exhaust flow is difficult to measure accurately and with high precision due to the highly transient nature of the cyclic events which are dependent on engine combustion parameters, varying exhaust gas compositions, pulsation effects, temperature and pressure. Bag mini-diluter (BMD) is becoming one of the few technologies chosen for SULEV and PZEV exhaust emission measurement and certification. A central part of the BMD system is an accurate and reliable exhaust flow measurement which is essential for proportional bag fill. A new device has been developed to accurately and reliably calibrate exhaust flow measurement equipments such as the E-Flow. The calibration device uses two different size laminar flow elements (LFE), a 40 CFM (1.13 m3/min) LFE for low end calibration and a 400 CFM (11.32 m3/min) LFE for higher flows. A blower is used to push flow through a main flow path, which then divides into two flow pathways, one for each of the two LFE's.

Automakers in the United States have started using bag mini-diluters (BMD) for developing, testing and certifying vehicles, to meet PZEV and SULEV regulation requirements. The BMD system which is a new technology developed by AIGER, is being used as an alternative to the traditional CFV/CVS system for accurate ultra low-level emission measurement. BMD system has shown to have considerable advantage over CFV/CVS system, especially at ULEV/SULEV emission levels. This paper details modifications and diagnostic checks conducted with the existing BMD system at the DaimlerChrysler Tech Center emissions facility, Auburn Hills, Michigan. This paper also discusses possible scenarios where the BMD system at DaimlerChrysler could give erroneous results due to system setup, optimization issues and equipment limitations.

In order to match catalyst OBDII conditions the common procedure is oven aging with air, which is not suitable for complete converter systems due to mantle corrosion. The goal was, therefore, to find an alternative procedure to ensure a defined catalyst aging that would match 1,75 times the emission standard and is also good for SULEV. The new procedure currently being developed allows the aging of metal and ceramic catalysts as well as complete catalyst systems. The paper will present the aging process, emission data of fresh and aged catalysts and the feedback to the test car OBDII system.

The future of diesel-engine-powered passenger cars and light-duty vehicles in the United States depends on their ability to meet Federal Tier 2 and California LEV2 tailpipe emission standards. The experimental purpose of this work was to examine the potential role of fuels; specifically, to determine the sensitivity of engine-out NOx and particulate matter (PM) to gross changes in fuel formulation. The fuels studied were a market-average California baseline fuel and three advanced low sulfur fuels (<2 ppm). The advanced fuels were a low-sulfur-highly-hydrocracked diesel (LSHC), a neat (100%) Fischer-Tropsch (FT100) and 15% DMM (dimethoxy methane) blended into LSHC (DMM15). The fuels were tested on modern, turbocharged, common-rail, direct-injection diesel engines at DaimlerChrysler, Ford and General Motors. The engines were tested at five speed/load conditions with injection timing set to minimize fuel consumption.

The Flame Ionization Detector (FID) used to measure hydrocarbon content in emission samples uses a hydrogen flame that produces little ionization. Hydrocarbons introduced into this flame produce large numbers of ions with ionization proportional to the number of carbon atoms present. This proportionality can be skewed by variations in oxygen content. Oxygen variation in emission samples, cylinders of air or span/calibration gas, and zero air systems are investigated and their effects on emission results are discussed. The oxygen content of the gas under analysis will affect the hydrocarbon concentration reported by the FID. In the example examined in this paper, the oxygen effect was shown to decrease the FTP (Federal Test Procedure) weighted NMHC (Non-Methane Hydrocarbon) results by as much as 7 % for a BMD (Bag Mini-Diluter) sample and 13% for a CVS (Constant Volume Sampling) sample.

The Automotive Industry/Government Emissions Research CRADA (AIGER) has been working to develop a new methodology for the direct determination of nonmethane hydrocarbons (DNMHC) in vehicle testing. This new measurement technique avoids the need for subtraction of a separately determined methane value from the total hydrocarbon measurement as is presently required by the Code of Federal Regulations. This paper will cover the historical aspects of the development program, which was initiated in 1993 and concluded in 2002. A fast, gas chromatographic (GC) column technology was selected and developed for the measurement of the nonmethane hydrocarbons directly, without any interference or correction being caused by the co-presence of sample methane. This new methodology chromatographically separates the methane from the nonmethane hydrocarbons, and then measures both the methane and the backflushed, total nonmethane hydrocarbons using standard flame ionization detection (FID).

Future vehicle North American emissions standards (e.g., North American Tier 3 Bin 30 or LEVIII SULEV 30) require the exhaust catalyst to be greater than 80% efficient by 20 seconds after the engine has been started in the Federal Test Procedure. Turbocharged engines are especially challenged to deliver fast catalyst light-off since the presence of the turbocharger in the exhaust flow path significantly increases exhaust system heat losses. A solution to delivering cost effective SULEV 30 emissions in turbocharged engines is to achieve fast catalyst light-off by reducing exhaust system heat losses in cold start, without increasing catalyst thermal degradation during high load operation. A CAE methodology to assess the thermal performance of exhaust system hardware options, from the exhaust port to the catalyst brick face is described, which enables compliance with future emissions regulations.

In Fall of 2001, a new emissions test cell was installed at Ford Motor Company that was specifically designed for precise low-level measurements (as described in Reference 6). The primary design focus for this cell was to ensure that optimal measurement capability was available to test vehicles that meet the stringent Partial Zero Emission Vehicle (PZEV) tailpipe requirements (NMOG = 10 mg/mile, NOx = 20 mg/mile). Over the past four years, there have been numerous improvements to the operational and Quality Assurance (QA) practices used in the PZEV Test Cell. Several investigations have also been performed to demonstrate the quality of its emissions measurements. Finally, a number of “lessons learned” have been documented from our experiences with PZEV measurements and with testing hybrid-electric vehicles. This paper summarizes these findings as a reference for others interested in low-level emissions measurements.

As a first step towards the development of a fuel cell powered production vehicle, Ford Motor Company has developed the P2000 fuel cell electric vehicle (FCEV). This prototype fuel cell powered vehicle achieves full passenger car performance and is truly a zero emission vehicle with the only by-product being pure water. Road and dynamometer driving tests show excellent performance results, which supports the continued interest in the realization of a production fuel cell vehicle. However, a significant amount of R&D remains to be done before fuel cells can achieve the levels of reliability and cost of internal combustion engines (ICE).

Current and proposed emissions standards in the United States, Europe and Japan are creating unique markets for the introduction of new powertrain technology. Adding to the complexity of the evolving tailpipe emission standards are differing vehicle and dynamometer test cycles and increased emphasis on CO2 reduction and higher vehicle fuel economy. In addressing the challenges posed by increasingly more stringent emissions standards and demands for high efficiency powertrain technologies, partitioning the tailpipe emissions requirements has the potential to identify and dimension significant design, development and systems tasks. This paper describes the use of emissions index, the ratio of emissions mass flow to fuel mass flow, to define the tailpipe emissions capabilities required from engine/fuel/calibration and after-treatment/control systems.

The Coordinating Research Council conducted a program to measure the reversibility of fuel sulfur effects on emissions from California Low Emission Vehicles (LEVs). Six LEV models were tested using two non-oxygenated conventional Federal fuels with 30 and 630 ppm sulfur. The following emission test sequence was used: 30 ppm fuel to establish a baseline, 630 ppm fuel, and return to 30 ppm fuel. A series of emission tests were run after return to 30 ppm to ensure that emissions had stabilized. The effect of the driving cycle on reversibility was evaluated by using both the LA4 and US06 driving cycles for mileage accumulation between emission tests after return to 30-ppm sulfur fuel. The reversibility of sulfur effects was dependent on the vehicle, driving cycle, and the pollutant. For the test fleet as a whole most but not all of the sulfur effects were reversible.

As motor vehicle emissions have been reduced to meet requirements of the clean air acts, they have become low enough to be difficult to measure accurately. This is especially the case for hydrocarbons, because after warm-up, there are fewer hydrocarbons emitted from a modern vehicle's tailpipe than in the surrounding air. It is therefore important to correctly compensate for the ambient hydrocarbon levels of the air used to dilute the collected exhaust. In estimating the accuracy of the federally required testing procedures, previously published error analyses have examined the effects of random errors. This study examines the systematic errors inherent in the CVS (Constant Volume Sampling) technique specified in federal regulations, estimates their sizes, and proposes a method using proportional ambient sampling whereby they can be avoided.

The following paper highlights the results of a vehicle emission improvement program with emphasis on two main points: In the initial phase, various combinations of Pd and Pt-based three-way catalyst technologies were evaluated on a TLEV and a LEV calibrated vehicle in order to generate ULEV exhaust gas levels. One goal in this portion of the study was to achieve technical equivalence between a viable Pd-based technology and a newly developed Pt-based technology. A combination of the Pd- and Pt-based technologies was able to meet the ULEV and part of the ULEV II regulations in the test vehicle after a catalyst aging cycle that resembles 50,000 miles of vehicle driving. In the later phase, a mathematical algorithm based on the original TLEV and LEV vehicle data was developed in order to conduct computer modeling of the exhaust gas aftertreatment system. This algorithm described the kinetic behavior of the individual catalysts over a broad range of reaction conditions.