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Biofuels, such as ethanol and butanol, have been the subject of significant political and scientific attention, owing to concerns about climate change, global energy security, and the decline of world oil resources that is aggravated by the continuous increase in the demand for fossil fuels. This study evaluated the potential emissions impacts of different alcohol blends on a fleet of modern gasoline vehicles. Testing was conducted on a fleet of nine vehicles with different combinations of ten fuel blends over the Federal Test Procedure and Unified Cycle. The vehicles ranged in model year from 2007-2014 and included four vehicles with port fuel injection (PFI) fueling and five vehicles with direct injection (DI) fueling. The ten fuel blends included ethanol blends at concentrations of 10%, 15%, 20%, 51%, and 83% by volume and iso-butanol blends at concentrations of 16%, 24%, 32%, and 55% by volume, and an alcohol mixture giving 10% ethanol and 8% iso-butanol in the final blend.

Gasoline direct injection (GDI) engines have improved thermodynamic efficiency (and thus lower fuel consumption) and power output compared with port fuel injection (PFI) and their penetration is expected to rapidly grow in the near future in the U.S. market. In addition, the use of alternative fuels is expanding, with a potential increase in ethanol content beyond the current 10%. Increased emphasis has been placed on butanol due to its more favorable fuel properties, as well as new developments in production processes. This study explores the influence of mid-level ethanol and iso-butanol blends on criteria emissions, gaseous air toxics, and particulate emissions from two wall-guided gasoline direct injection passenger cars fitted with three-way catalysts. Emission measurements were conducted over the Federal Test Procedure (FTP) driving cycle on a chassis dynamometer.

The likely transition from today's conventional to future alternative fuels will be discussed. It will be shown that in the very long term renewable fuels might be the most promising road fuels with respect to low CO2 emissions. In the short and medium term, however, liquid alternative fuels will prevail being produced initially from natural gas and later increasingly from biomass. Methanol, Ethanol, GTL Hydrocarbons and other fuels are still under study since lowest WTW CO2 emissions and overall system costs are not yet clarified. The availability of alternative fuels in large quantities will depend on the costs for production and infra-structure, and not least of all, on the market benefits of the resulting fuel / power train systems in a holistic assessment. Cost trends for conventional and alternative fuels will be discussed.

With the purpose of minimizing the gaseous emissions impacts on the metropolitan areas, many alternative fuel resources has been developed as alternatives to fossil fuels. An environmentally and economical interesting alternative for the Brazilian market is the diesel made from sugar cane (Farnesene - C15H32). The Farnesene, made by sugar cane juice fermentation in presence of a genetically modified yeast is basically a saturated hydrocarbon molecule (C15H32) with more than 98% purity and that presents properties comparable to fossil diesel and when used in regular diesel cycle engines can bring significantly reductions not only in soot levels (Particulate Matter - PM) but also on the Nitrogen Oxides (NOx), unlike the biodiesel, that is well known that it brings increases on NOx emission level due its physic-chemical properties. Reduction on CO2 levels on life cycle is another important benefit of using such fuel since it's made by renewable feedstock.

The growing necessity for less carbon emission vehicles due to environmental issues and more rigid legislation rules encourages many automotive companies to develop low CO2 emission engines. This motivation leads Mercedes-Benz do Brazil to the development of a “dual-fuel” diesel engine for buses that works with diesel and CNG (Compressed Natural Gas) fuel. One of the challenges for the development of this kind of engine is the electric/electronic integration between the diesel engine ECU (Electronic Control Units) and the CNG system ECU that coordinates the engine gas injectors.

With the discovery of oil and gas in the pre-salt Santos and Campos basin, the supply of natural gas (NG) is expected to increase considerably, so the use of compressed natural gas (CNG) in city buses will be an important option for reducing the overall consumption of fossil diesel fuel and a reduction in operating costs in São Paulo and Rio de Janeiro Metropolitan Areas in Brazil. A vehicle with an engine that can run on pure diesel or diesel and CNG has advantage over a vehicle that works exclusively with CNG, because when there is no availability or the lack of CNG, the vehicle / engine operates with diesel only. Another benefit of this technology is the resale value in Brazil, because after the life cycle of use in theses two big cities, Urban Buses are sold country side to small cities where CNG is not available.

In view of limited crude oil resources, alternative fuels for internal combustion engines are currently being intensively researched. Synthetic fuels from natural gas offer a promising interim option before the development of CO2-neutral fuels. Up to a certain degree, these fuels can be tailored to the demands of modern engines, thus allowing a concurrent optimization of both the engine and the fuel. This paper summarizes investigations of a Gas-To-Liquid (GTL) diesel fuel in a modern, post-EURO 4 compliant diesel engine. The focus of the investigations was on power output, emissions performance and fuel economy, as well as acoustic performance, in comparison to a commercial EU diesel fuel. The engine investigations were accompanied by injection laboratory studies in order to assist in the performance analyses.

Although various legislation and regulations have been adopted to promote the use of alternative-fuel vehicles for curbing urban air pollution problems, there is a lack of systematic comparisons of emission control cost-effectiveness among various alternative-fuel vehicle types. In this paper, life-cycle emission reductions and life-cycle costs were estimated for passenger cars fueled with methanol, ethanol, liquified petroleum gas, compressed natural gas, and electricity. Vehicle emission estimates included both exhaust and evaporative emissions for air pollutants of hydrocarbon, carbon monoxide. nitrogen oxides, and air-toxic pollutants of benzene, formaldehyde, 1,3-butadiene, and acetaldehyde. Vehicle life-cycle cost estimates accounted for vehicle purchase prices, vehicle life, fuel costs, and vehicle maintenance costs.

The heavy-duty natural gas engine has been subject of growing interest as a feasible alternative for the reduction of pollution levels in urban centers, where currently diesel vehicles predominate. This paper summarizes the development of the Mercedes Benz compressed natural gas engine M366LAG, which reached competitive characteristics of Diesel engines, like fuel consumption, weight / power ratio and thermal loading, by matching the turbocharging technology with charge cooler and the concept of lean burn combustion. An oxidation catalyst was developed and emissions less than 50% of the EURO II limits were achieved. With 5,958 1 of displacement and 6 cylinders in line, the M366LAG provides a power of 170 kW @ 2600 min-1 and 720 Nm @ 1560 min-1 as maximum torque.

This paper addresses the use of neat, indigenous biodiesel in advanced Mercedes-Benz passenger cars. Modern, unmodified EU3 Common-Rail diesel engines with second generation common rail technology were used to determine the effects of neat biodiesel on performance and emission characteristics. The biodiesel was made from the seeds of the Jatropha Curcas plant and sourced from the Central Salt and Marine Chemicals Research Institute in Bhavnagar, India. The production of biodiesel and the vehicle tests are part of a PPP project, funded jointly by the DaimlerChrysler AG and the German DEG. The project aims at providing additional jobs and income in rural Indian areas along with reclaiming unused wasteland. The test vehicles were operated for a cumulative 8000 kilometers with an intention to expose the vehicle and fuel to diverse climatic conditions.

With focus on reducing the Green House Gases emissions, the use of biodiesel as an alternative fuel, in special for buses that runs on the Brazilian metropolitan areas has been even higher. Additionally, with the introduction of the new legislation for diesel engines in 2012, CONAMA PROCONVE P7, that in order to attempt to its requirements uses different kinds of exhaust gases after treatment systems, the necessity of knowing the behavior of those “P7 engines” operating with different biodiesel contents on blends with regular fossil fuel or even pure biodiesel has been an important issue to ensure the benefits of using such alternative fuel. On this evaluation, blends of 5%, 10%, 20%, 30%, 50%, 75% and 100% of biodiesel content in ANP65/2011 A_S50 Diesel Fuel (50ppm Sulfur content) was experimented in a Mercedes-Benz OM926LA E5 engine with SCR (Selective Catalyst Reaction) exhaust gases after treatment system.

For automotive applications, it is necessary to maximize the fuel conversion efficiency of a PEM direct-methanol fuel cell (DMFC) over the broadest possible dynamic range of power. The research reported here critically examines the efficiency of the DMFC stack when operated over a broad power range. This research establishes a basis for a control strategy that simultaneously: optimizes DMFC fuel conversion efficiency versus power level, leads into a system level optimization of efficiency vs. power, and provides an operational strategy for controlling a direct-methanol fuel cell for maximum fuel efficiency from minimum to maximum power demand. First, there is an explanation of the experimental conditions used to obtain the DMFC experimental data that is reported and analyzed. Next the DMFC methanol crossover phenomenon is discussed and characterized. Then the conceptual framework for the optimization of fuel conversion efficiency is presented.

The relationship between ethanol and iso-butanol fuel concentrations and vehicle particulate matter emissions was investigated. This study utilized a gasoline direct injection (GDI) flexible fuel vehicle (FFV) with wall-guided fueling system tested with four fuels, including E10, E51, E83, and an iso-butanol blend at a proportion of 55% by volume. Emission measurements were conducted over the Federal Test Procedure (FTP) driving cycle on a chassis dynamometer with an emphasis on the physical and chemical characterization of particulate matter (PM) emissions. The results indicated that the addition of higher ethanol blends and the iso-butanol blend resulted in large reductions in PM mass, soot, and total and solid particle number emissions. PM emissions for the baseline E10 fuel were characterized by a higher fraction of elemental carbon (EC), whereas the PM emissions for the higher ethanol blends were more organic carbon (OC) in nature.

This paper follows a cycle-simulation method for creating an engine performance map for an ethanol fueled boosted HCCI engine using a 1-dimensional engine model. Based on experimentally determined limits, the study defined operating conditions for the engine and performed a limited parameter sweep to determine the best efficiency case for each condition. The map is created using a 6-Zone HCCI combustion model coupled with a detailed chemical kinetic reaction mechanism for ethanol, and validated against engine data collected from a 1.9L 4-Cylinder VW TDI engine modified to operate in HCCI mode. The engine was mapped between engine speeds of 900 and 3000 rpm, 1 and 3 bar intake pressure, and 0.2 and 0.4 equivalence ratio, resulting in loads between idle and 14.0 bar BMEP. Analysis of a number of trends for this specific engine map are presented, such as efficiency trends, effects of combustion phasing, intake temperature, engine load, engine speed, and operating strategy.

Engine manufacturers have explored many routes to reducing the emissions of harmful pollutants and conserving energy resources, including development of after treatment systems to reduce the concentration of pollutants in the engine exhaust, using alternative fuels, and using alternative fuels with after treatment systems. Liquefied petroleum gas (LPG) is one alternative fuel in use and this paper will discuss emission measurements for several LPG vehicles. Regulated emissions were measured for five school buses, one box truck, and two small buses over a cold start Urban Dynamometer Driving Schedule (CS_UDDS), the Urban Dynamometer Driving Schedule (UDDS), and the Central Business District (CBD) cycle. In general, there were no significant differences in the gas phase emissions between the UDDS and the CBD test cycles. For the CS-UDDS cycle the total hydrocarbons and non-methane hydrocarbon emissions are higher than they are from the UDDS cycle.

Steady-state, transient and dithering characteristics of emission conversion efficiencies of three-way catalysts on natural gas IC engine were investigated experimentally on a single-cylinder CFR engine test bench. Steady-state runs were conducted as references for specific engine emission levels and corresponding catalyst capacities. The steady-state data showed that conversion of HC will be the major problem since conversion of HC was effective only for a very narrow range of exhaust mixture. Unsteady exploration runs with both lean-to-rich and rich-to-lean transitions were conducted. These results were interpreted with a time scale analysis, according to which a qualitative oxygen storage model was proposed featuring the difference between oxygen absorption and desorption rates on the palladium catalysts.