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In the paper, a rule-based (RB) control strategy is proposed to optimize on-board energy management on a Hybrid Solar Vehicle (HSV) with series structure. Previous studies have shown the promising benefits of such vehicles in urban driving in terms of fuel economy and carbon dioxide reduction, and that economic feasibility could be achieved in a near future. The control architecture consists of two main loops: one external, which determines final battery state of charge (SOC) as function of expected solar contribution during next parking phase, and the second internal, whose aim is to define optimal ICE- EG power trajectory and SOC oscillation around the final value, as addressed by the first loop. In order to maximize the fuel savings achievable by a series architecture, an intermittent ICE scheduling is adopted for HSV. Therefore, the second loop yields the average power at which the ICE is operated as function of the average values of traction power demand and solar power.