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Diesel exhaust aftertreatment systems are required for meeting both EPA 2010 and final Tier 4 emission regulations while meeting the stringent packaging constraints of the vehicle. The aftertreatment system for this study consists of a fuel dosing system, mixing elements, fuel reformer, lean NOx trap (LNT), diesel particulate filter (DPF), and a selective catalytic reduction (SCR) catalyst. The fuel reformer is used to generate hydrogen (H₂) and carbon monoxide (CO) from injected diesel fuel. These reductants are used to regenerate and desulfate the LNT catalyst. NOx emissions are reduced using the combination of the LNT and SCR catalysts. During LNT regeneration, ammonia (NH₃) is intentionally released from the LNT and stored on the downstream SCR catalyst to further reduce NOx that passed through the LNT catalyst. This paper addresses system packaging and exhaust flow optimization for heavy-duty line-haul and severe service applications.

The performance of a commercial Cu-zeolite SCR catalyst after differing degrees of hydrothermal aging (aged for 72 hours at 500, 700 and 800°C with 10% moisture balanced with air) was studied by spatially resolving different key reactions using gas-phase FTIR measurements. Gases were sampled along a channel at different positions and analyzed using FTIR, which overcomes the interference of water and nitrogen on ammonia concentration detection encountered in standard mass spectrometer-based spatial resolution measurements. The NO:NO₂ concentration ratio was changed so that the standard (NO:NO₂ = 1:0), fast (NO:NO₂ = 1:1) and NO₂ (NO:NO₂ = 0:1) SCR reactions could be investigated as a function of the catalyst's hydrothermal aging extent. In addition, the effects of hydrothermal aging on the activity of NH₃ and NO oxidation were also investigated. Hydrothermal aging had little effect on NO oxidation activity.

The conversion design strategy, and emissions and performance results for a dedicated propane, vapour injected, 1995 Dodge Dakota truck are reported. Data is obtained from the University of Waterloo entry in the 1997 Propane Vehicle Challenge. A key feature of the design strategy is its focus on testing and emissions while preserving low engine speed power for drivability. Major changes to the Dakota truck included the following: installation of a custom shaped fuel tank, inclusion of a fuel temperature control module, addition of a vaporizer and a fuel delivery metering unit, installation of a custom vapour distribution manifold, addition of an equivalence ratio electronic controller, inclusion of a wide range oxygen sensor, addition of an exhaust gas recirculation cooler and installation of thermal insulation on the exhaust system. A competition provided natural gas catalyst was used.

Stringent space constraints for on and off highway vehicles require compact exhaust aftertreatment system packaging to meet both EPA 2010 and final Tier 4 emission regulations. Development and validation of a compact diesel fuel vaporization and mixing system is the focus of this work. The fuel vaporization and mixing system is comprised of a fuel dosing system, catalytic monolith and mechanical mixer. A fuel reformer, lean NOx trap (LNT), diesel particulate filter (DPF) and a selective catalytic reduction (SCR) catalysts are positioned downstream of the fuel vaporizer system. A 44% reduction in total fuel vaporization / mixing path length was achieved using an optimized injection chamber, catalytic monolith and mixing element. Reformer outlet temperature results confirm that reformer inlet fuel vapor uniformity targets meet design specifications. Similarly, the fuel reformer efficiency using the fuel vaporizer met the design targets within the compact packaging envelope.

Exhaust valve guttering is a corrosive process that takes place on the valve seat face. Detroit Diesel Allison Division of General Motors and Eaton Corporation have developed an accelerated test to gutter exhaust valves. The test was used to rank seven factors considered to be significant oil consumption, lubrication oil ash content and injector timing were found to be the major contributors to guttering.

A real-time control-oriented mean value engine plant model that includes engine thermals and cold starts is developed for a Toyota Prius 2015 plug-in hybrid engine in Modelica and MapleSim and validated experimentally. The model consists of an engine block model, intake and exhaust manifold models, and a throttle model. An advantage of the engine block model is the ability to compute the frictional Mean Effective Pressure during engine cold starts from calculated air, oil, and coolant temperatures at various locations in the engine block. Traditionally, engine thermals are modelled utilizing thermal resistances and capacitors. The proposed model utilizes linear graph theory with terminal equations to study the topology of the different components that affect engine thermals, including engine head, liner, coolant, and oil sump.

Regulations that limit emissions of pollutants from gasoline-powered cars and trucks continue to tighten. More than 75% of emissions through an FTP-75 regulatory test are released in the first few seconds after cold-start. A factor that controls the time to catalytic light-off is the heat capacity of the catalytic converter substrate. Historically, substrates with thinner walls and lower heat capacity have been developed to improve cold-start performance. Another approach is to increase porosity of the substrate. A new material and process technology has been developed to significantly raise the porosity of thin wall substrates (2-3 mil) from 27-35% to 55% while maintaining strength. The heat capacity of the material is 30-38% lower than existing substrates. The reduction in substrate heat capacity enables faster thermal response and lower tailpipe emissions. The reliance on costly precious metals in the washcoat is demonstrated to be lessened.

An advanced Variable Valve Actuation (VVA) system is optimized for response time in order to provide robust switching at high engine speeds. The VVA system considered is Cylinder Deactivation (CDA) for the purpose of improving fuel economy. Specifically, a Switching Roller Finger Follower (SRFF) on a Dual Overhead Camshaft (DOHC) engine is optimized for cylinder deactivation. The objective of this work is to (1) improve the latch response time when the system response is the slowest, and (2) balance the “ON” and “OFF” response time. A proper tradeoff was established to provide the minimum switching time such that deactivation and reactivation occurs seamlessly and in the right sequence. The response time optimization is accomplished while maintaining the existing packaging space of the overhead. A camshaft with a single lobe per SRFF device on a type II valvetrain was used as the baseline configuration for this study.

The effects of propylene (C₃H₆) and dodecane (n-C₁₂H₂₆) exposure on the NH₃-based selective catalytic reduction (SCR) performance of two Cu-exchanged zeolite catalysts were investigated. The first sample was a model Cu/beta zeolite sample and the second a state-of-the-art Cu/zeolite sample, with the zeolite material characterized by relatively small pores. Overall, the state-of-the-art sample performed better than the model sample, in terms of hydrocarbon inhibition (which was reduced) and N₂O formation (less formed). The state-of-the-art sample was completely unaffected by dodecane at temperatures lower than 300°C, and only slightly inhibited (less than 5% conversion loss), for standard SCR, by C₃H₆. There was no evidence of coke formation on this catalyst with C₃H₆ exposure. The model sample was more significantly affected by hydrocarbon exposure. With C₃H₆, inhibition is associated with its partial oxidation intermediates adsorbed on the catalyst surface.

Automobile fires are a serious concern to manufacturers and consumers. However, understanding how the fires begin, in the confines of the engine compartment, is a difficult task. One known cause of fires is hot surface ignition (HSI) arising when engine fluids contact hot surfaces in the engine compartment or the exhaust train. In this study, the ignition of automotive gasoline on four hot surfaces: stainless and carbon steels from the heat shields, stainless steel from the exhaust manifold and cast iron cut from an intake manifold, was examined in a well-controlled, model study. Infra-red thermography and thermocouples were used to monitor surface temperatures prior to, during and after the fluid impacted the surface. This allowed evaluation and comparison of temperature evolution during fluid impact and the ignition event, resulting in an improved mechanistic understanding of the fluid/hot surface interaction.