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Particle size distribution and particle number emissions rather than legislated particulate mass emissions from diesel engines are subject of rising concern especially in the US and several Western European countries [1]*. Recently also particle number emissions from gasoline engines attracted much attention since these engines are supposed to emit very high numbers of ultrafine particles or even nano-sized particles [2]. The work described in this paper focused on the impact of modern diesel exhaust gas aftertreatment systems like diesel oxidation catalysts (DOC) and diesel particulate filter (DPF) on particle number emission. Especially the effect that these aftertreatment systems are supposed to significantly increase ultrafine particle numbers (because they may act like “reactors” actively producing ultrafine solid particles) gave reason for investigating the effects and mechanisms more in detail.

The reduction of particulate emissions from diesel engines is one of the most challenging problems associated with exhaust pollution control, second only to the control of NOx from any “lean burn” application. Particulate emissions can be controlled by adjustments to the combustion parameters of a diesel engine but these measures normally result in increased emissions of oxides of nitrogen. Diesel particulate filters (DPFs) hold out the prospect of substantially reducing regulated particulate emissions and the task of actually removing the particles from the exhaust gas has been solved by the development of effective filtration materials. The question of the reliable regeneration of these filters in situ, however, remains a difficult hurdle. Many of the solutions proposed to date suffer from high engineering complexity and/or high energy demand. In addition some have special disadvantages under certain operating conditions.

A vehicle investigation programme was initiated to evaluate the influence of diesel fuel sulfur content on the performance of a DeNOx catalyst for NOx control. The programme was conducted with a passive DeNOx catalyst, selected for its good NOx reduction performance and two specially prepared fuels with different sulfur contents. Regulated emissions were measured and analysed during the course of the programme. The NOx conversion efficiency of the DeNOx catalyst increased from 14 to 26% over the new European test cycle when the sulfur content of the diesel fuel was reduced from 49 to 6 wt.-ppm. In addition the number and size of particles produced using 6 wt.-ppm sulfur fuel were measured by two different techniques: mobility diameter by SMPS and aerodynamic diameter by impactor. The influence of the assumed density of the particulate on the apparent diameters measured by the two techniques is discussed.