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A single-cylinder, spark-ignited engine was run on a certification test gasoline to saturate the oil in the sump with fuel through exposure to blow-by gas. The sump volume was large relative to production engines making its absorption-desorption time constant long relative to the experimental time. The engine was motored at 1500 RPM, 90° C coolant and oil temperature, and 0.43 bar MAP without fuel flow. Exhaust HC concentrations were measured by on-line FID and GC analysis. The total motoring HC emissions were 150 ppmC1; the HC species distribution was heavily weighted to the low-volatility components in the gasoline. No high volatility components were visible. The engine was then fired on isooctane fuel at the above conditions, producing a total engine-out HC emission of 2300 ppmC1 for Φ = 1.0 and MBT spark timing.

Modern four-valve engines are running at ever higher compression ratios in order to improve fuel efficiency. Hotter cylinder bores also can produce increased fuel economy by decreasing friction due to less viscous oil layers. In this study changes in compression ratio and coolant temperature were investigated to quantify their effect on exhaust emissions. Tests were run on a single cylinder research engine with a port-deactivated 4-valve combustion chamber. Two compression ratios (9.15:1 and 10.0:1) were studied at three air/fuel ratios (12.5, 14.6 and 16.5) at a part load condition (1500 rpm, 3.8 bar IMEP). The effect of coolant temperature (66 °C and 108°C) was studied at the higher compression ratio. The exhaust was sampled and analyzed for both total and speciated hydrocarbons. The speciation analysis provided concentration data for hydrocarbons present in the exhaust containing twelve or fewer carbon atoms.

The effects of fuel injection and spark timing on engine-out, regulated (total HC, NOx, and CO) and speciated HC emissions have been investigated for a 0.31L, single-cylinder, direct-injection, spark-ignition (DISI) engine equipped with an air-forced fuel injector. When the timing of the start of the air injection (SOA) is varied during high stratification operation, the mole fractions of all regulated emissions vary sharply over relatively small (20-30 crank angle degrees) changes in SOA. In addition, the distribution of exhaust hydrocarbon species changes significantly. As stratification increases, the contribution of unburned paraffinic fuel components to the HC emissions decreases by a factor of two while the olefinic partial oxidation products increase. When the spark timing is varied during high stratification operation, the HC emissions increase sharply as the spark timing is retarded relative to MBT.