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A hydrocarbon trapping system for cold start emissions was constructed and tested using two types of carbonaceous adsorbents provided by Corning, Inc. One was made by combining activated carbon with an organic binder and extruding it into a honeycomb, and the other by depositing a carbon coating on a ceramic monolith. The tests were carried out on an engine in a dynamometer laboratory to characterize the performance of the carbon elements under transient cold start conditions. Performance was evaluated by continuously measuring exhaust gas hydrocarbon concentrations upstream and downstream of the trap, using conventional emissions consoles. Samples were also collected for off-line analysis of individual hydrocarbon species using gas chromatography to examine differences in adsorption of individual species. The speciated hydrocarbon data were used to distinguish between the mass trapping efficiency and a reactivity-based trapping efficiency of the adsorbant traps.

An experimental data base of catalyst conversion efficiency was generated, using a tubular flow reactor which contained either a Pt/Rh (5:1; 40g/ft3) or a Pd/Rh (5:1; 40g/ft3) catalyst sample, for the purpose of updating the kinetic rate constants in the Ford TWC model. Steady-state conversion efficiency of CO, NO, C3H8, C3H6, H2 and O2 through these catalysts were determined for a variety of inlet species concentrations and inlet gas temperatures. These data were obtained for values of redox ratio between 0.5 (excess O2) and 4.0, and inlet gas temperatures between 371°C and 593°C. All experimental details and modeling procedures utilized in obtaining an optimized set of kinetic parameters are included. Results of these experiments show significant improvement in CO and NO conversion efficiency and an increase in NH3 production for both catalyst formulations over previous generation catalyst formulations when redox ratio is greater than unity.