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This session focuses on kinetically controlled combustion. Experimental and simulation studies pertaining to various means of controlling combustion are welcome. Examples are research studies dealing with temperature and composition distribution inside the cylinder and their impact on heat release process. Studies clarifying the role of fuel physical and chemical properties in autoignition are also welcome. Presenter Hanho Yun, General Motors Company

In the thermal expansion valve (TXV) refrigerant system, transient high-pitched whistle around 6.18 kHz is often perceived following air-conditioning (A/C) compressor engagements when driving at higher vehicle speed or during vehicle acceleration, especially when system equipped with the high-efficiency compressor or variable displacement compressor. The objectives of this paper are to conduct the noise source identification, investigate the key factors affecting the whistle excitation, and understand the mechanism of the whistle generation. The mechanism is hypothesized that the whistle is generated from the flow/acoustic excitation of the turbulent flow past the shallow cavity, reinforced by the acoustic/structural coupling between the tube structural and the transverse acoustic modes, and then transmitted to evaporator. To verify the mechanism, the transverse acoustic mode frequency is calculated and it is coincided to the one from measurement.

Diesel NOx emissions control utilizing combined Lean NOx Trap (LNT) and so-called passive or in-situ Selective Catalytic Reduction (SCR) catalyst technologies (i.e. with reductant species generated by the LNT) has been the subject of several previous papers from our laboratory [ 1 - 2 ]. The present study focuses on hydrocarbon (HC) emissions control via the same LNT+SCR catalyst technology under FTP driving conditions. HC emissions control can be as challenging as NOx control under both current and future federal and California/Green State emission standards. However, as with NOx control, the combined LNT+SCR approach offers advantages for HC emission control over LNT-only aftertreatment. The incremental conversion obtained with the SCR catalyst is shown, both on the basis of vehicle and laboratory tests, to result primarily from HC adsorbed on the SCR catalyst during rich LNT purges that reacts during subsequent lean engine operation.

The Leaner Lifted-Flame Combustion (LLFC) strategy offers a possible alternative to low temperature combustion or other globally lean, premixed operation strategies to reduce soot directly in the flame, while maintaining mixing-controlled combustion. Adjustments to fuel properties, especially fuel oxygenation, have been reported to have potentially beneficial effects for LLFC applications. Six fuels were selected or blended based on cetane number, oxygen content, molecular structure, and the presence of an aromatic hydrocarbon. The experiments compared different fuel blends made of n-hexadecane, n-dodecane, methyl decanoate, tri-propylene glycol monomethyl ether (TPGME), as well as m-xylene. Several optical diagnostics have been used simultaneously to monitor the ignition, combustion and soot formation/oxidation processes from spray flames in a constant-volume combustion vessel.

A single-cylinder, spark-ignited engine was run on a certification test gasoline to saturate the oil in the sump with fuel through exposure to blow-by gas. The sump volume was large relative to production engines making its absorption-desorption time constant long relative to the experimental time. The engine was motored at 1500 RPM, 90° C coolant and oil temperature, and 0.43 bar MAP without fuel flow. Exhaust HC concentrations were measured by on-line FID and GC analysis. The total motoring HC emissions were 150 ppmC1; the HC species distribution was heavily weighted to the low-volatility components in the gasoline. No high volatility components were visible. The engine was then fired on isooctane fuel at the above conditions, producing a total engine-out HC emission of 2300 ppmC1 for Φ = 1.0 and MBT spark timing.

Automotive fuel injectors have been adapted with electrodes that enable negative electric charge to be inserted into the fuel flowing through the injector. Because the fuel is electrically very insulating and flowing rapidly, a significant amount of charge is retained in the fuel as it issues from the injector. Once exposed to the atmosphere, the charge laden fuel both atomizes and spatially disperses due to electrostatic forces. By varying the amount of inserted charge, the spray pattern can be varied significantly. This added variability allows the possibility of changing the fuel presentation when fuel is injected into the intake port of a typical spark ignited engine. A variable presentation may be useful for optimizing fuel evaporation within the port, with a corresponding reduction of exhaust emissions, during the cold start period of the engine when those parameters affecting evaporation are changing both temporally and spatially.

Fuel-air mixing in a direct-injection SI engine was studied to further improve full-load torque output. The fuel-injection location of DI vs. PFI results in different heat sources for fuel evaporation, hence a DI engine has been found to exhibit higher volumetric efficiency and lower knocking tendency, resulting in higher full-load torque output [1]. The ability to change injection timing of the DI engine affects heat transfer and mixture temperature, hence later injection results in lower knocking tendency. Both the higher volumetric efficiency and the lower knocking tendency can improve engine torque output. Improving volumetric efficiency requires that the fuel is injected during the intake stroke. Reducing knocking tendency, in contrast, requires that the fuel is injected late during the compression stroke. Thus, a strategy of split injection was proposed to compromise the two competing requirements and further increase direct-injection SI engine torque output.

A new method to estimate instantaneous A/F ratio and use the estimation as a feedback signal to control AFR during cold transients, before the oxygen sensor is functional, has been realized by a on-board PCM for a vehicle with a 4.6L, V8, PFI engine [4, 6]. Different AFRs cause variations in flame propagation, causing fluctuations in the effective torque. When a known AFR disturbance is induced into an engine system, a corresponding crankshaft angular velocity fluctuation can be detected. A variable derived from this physical phenomenon can be used to characterize the problem. The optimal fuel perturbation signal is designed by a relaxation concept, and the system model is determined by employing a dual-direction screening multivariate stepwise regression analysis. The estimated AFR is used by the PCM in a closed loop control to correct the fuel during cold transients.

Until now no results have been available regarding the composition of evaporative emissions in a SHED test. In particular, for alcohol containing fuels, it is important to assess the relative percentage of alcohols and hydrocarbons in view of their different environmental impacts. This paper presents the results of a study conducted to determine the composition of the emissions from a number of multilayer coextruded plastic fuel tanks soaked in IE10 and CM15 test fuels. These emissions were analyzed for composition using a gas chromatography analytical method which employs a vapor trap and desorb sampling technique. In the case of CM15, methanol was found to account for as much as 50% of the overall evaporative emissions. This speciation method also allows estimation of how leakage and permeation contribute separately to the overall emissions.

The occurrence of flash boiling in the fuel spray of a Port Fuel Injected (PFI) spark ignition engine has been observed and photographed during normal automotive vehicle operating conditions. The flash boiling of the PFI spray has a dramatic affect on the fuel spray characteristics such as droplet size and spray cone angle which can affect engine transient response, intake valve temperature and possibly hydrocarbon emissions. A new method of correlating the spray behavior using the equilibrium vapor/liquid (V/L) volume ratio of the fuel at the measured fuel temperature and manifold pressure is introduced.

A review of flame kernel growth in SI engines and the regimes of premixed turbulent combustion showed that a misfire model based on regimes of premixed turbulent combustion was warranted[1]. The present study will further validate the misfire model and show that it has captured the dominating physics and avoided extremely complex, yet inefficient, models. Results showed that regimes of turbulent combustion could, indeed, be used for a concept-simple model to predict misfire limits in SI engines. Just as importantly, the entire regimes of premixed turbulent combustion in SI engines were also mapped out with the model.

A lean-rich hydrothermal aging was used to study the deactivation of Cu-zeolite SCR catalyst that has enhanced stability. Impact of DOC upstream on the SCR catalyst during the lean-rich aging was also investigated. The LR hydrothermal aging was conducted with the presence of hydrocarbon, CO and H₂ at different O₂ levels. It was found that the SCR catalyst was active for the oxidation of CO, H₂ and hydrocarbon, resulting in significant exotherm across the catalyst. In addition to hydrothermal aging, reductive aging, especially the presence of H₂ in the aging gas stream without O₂ presence during the L-R aging, might also contribute to the Cu/zeolite SCR catalyst deactivation. The impacts of DOC upstream on Cu/zeolite SCR catalysts depended on the aging temperatures. At lower aging temperature, the uncompleted oxidation of hydrocarbon and CO on the DOC might cause steam reforming and water-gas shift reactions on the DOC to form reductive gas stream.

A series of tests have been performed on a production vehicle to determine the characteristics of the external turbulent flow field in wind tunnel and road conditions. Empirical formulas are developed to use the measured data as source levels for a Statistical Energy Analysis (SEA) model of the vehicle structural and acoustical responses. Exterior turbulent flow and acoustical subsystems are used to receive power from the source excitations. This allows for both the magnitudes and wavelengths of the exterior excitations to be taken into account - a necessary condition for consistently accurate results. Comparisons of measured and calculated interior sound levels show good correlation.

The catalytic activity of selected materials (BaY and NaY zeolites, and γ-alumina) for selective NOx reduction in combination with a non-thermal plasma was investigated. Our studies suggest that aldehydes, formed during the plasma treatment of simulated diesel exhaust, are the important species for the reduction of NOx to N2. Indeed, all materials that are active in plasma-assisted catalysis were found to be very effective for the thermal reduction of NOx in the presence of aldehydes. For example, the thermal catalytic activity of a BaY zeolite with aldehydes gives 80-90% NOx removal at 250°C with 200ppm NOx at the inlet and a VHSV=12,000 h-1. The hydrocarbon reductants, n-octane and 1-propyl alcohol, have also shown high thermal catalytic activity for NOx removal over BaY, NaY and γ-alumina.

We present here a phenomenological analysis of a cascade of two-step discharge-catalyst reactors. That is, each step of the cascade consists of a discharge reactor in series with a catalyst bed. These reactors are intended for use in the reduction of tailpipe emission of NOx from diesel engines. The discharge oxidizes NO to NO2, and partially oxidizes HC. The NO2 then reacts on the catalyst bed with hydrocarbons and partially oxidized HCs and is reduced to N2. The cascade may be essential because the best catalysts for this purpose that we have also convert significant fractions of the NO2 back to NO. As we show, reprocessing the gas may not only be necessary, but may also result in energy savings and increased device reliability.

This paper presents results from an experimental programme researching the in-cylinder conditions necessary to obtain homogenous CAI (or HCCI) combustion in a 4-stroke engine. The fuels under investigation include three blends of Unleaded Gasoline, a 95 RON Primary Reference Fuel, Methanol, and Ethanol. This work concentrates on establishing the CAI operating range with regard to Air/Fuel ratio and Exhaust Gas Re-circulation and their effect on the ignition timing, combustion rate and variability, Indicated thermal efficiency, and engine-out emissions such as NOx. Detailed maps are presented, defining how each of the measured variables changes over the entire CAI region. Results indicate that the alcohols have significantly higher tolerance to dilution than the hydrocarbon fuels tested. Also, variations in Gasoline blend have little effect on any of the combustion parameters measured.

The requirements to produce high specific power, a high torque across a broad engine speed range and very low emissions levels have been seen as mutually exclusive in a conventional normally aspirated SI engine. Ford Motor Co in association with Cosworth Technology Ltd. have developed a port injection SI engine which achieves in excess of 63kW/ltr, a peak torque in excess of 97Nm/ltr, 92Nm/ltr between 2500rpm and 6500rpm and meets European IV and North American LEV emissions levels for the Focus ST170 in Europe and the SVT Focus in the US. To achieve the required torque across the speed range the volumetric efficiency needed to be maximized at all engine speeds. This was done by fitting continuously variable inlet valve timing, variable length intake manifold and a tuned exhaust manifold. To meet the emissions requirements, the catalyst light off time must be kept to a minimum.

As part of the P2000 hydrogen fueled internal combustion engine (H2ICE) vehicle program, an engine dynamometer research project was conducted in order to systematically investigate the unique hydrogen related combustion characteristics cited in the literature. These characteristics include pre-ignition, NOx emissions formation and control, volumetric efficiency of gaseous fuel injection and related power density, thermal efficiency, and combustion control. To undertake this study, several dedicated, hydrogen-fueled spark ignition engines (compression ratios: 10, 12.5, 14.5 and 15.3:1) were designed and built. Engine dynamometer development testing was conducted at the Ford Research Laboratory and the University of California at Riverside. This engine dynamometer work also provided the mapping data and control strategy needed to develop the engine in the P2000 vehicle.

Particulate and manganese mass emissions have been measured as a function of mileage for four Escort and four Explorer vehicles using 1) MMT (Methylcyclopentadienyl Manganese Tricarbonyl) added to the gasoline at 1/32 g Mn/gal and 2) gasoline without MMT. The MMT was used in half of the fleet starting at 5,000 miles. The vehicles were driven on public roads at an average speed of 54 mph to accumulate mileage. This report describes the particulate and manganese emissions, plus emissions of four air toxics at 5,000, 20,000, 55,000, 85,000 and 105,000 miles. Four non-regulated emissions were measured and their average values for vehicles without MMT were 0.6 mg/mi for formaldehyde, 0.7 mg/mi for 1,3-butadiene, 9 mg/mi for benzene and 12 mg/mi for toluene. Corresponding values for MMT-fueled vehicles were between 1.5 and 2.4 times higher.

Measurements of oxygen storage capacity (OSC) and HC conversion efficiency for 17 catalysts were carried out in the laboratory. All catalysts with steady state HC efficiency below 90% were found to have roughly equivalent and very low capacities to store oxygen. However, catalyst oxygen storage capacity was seen to rise sharply with HC conversion efficiency in excess of 90 percent. These results parallel the trends which are observed between rear HEGO/EGO indexes for OBD-II catalyst monitoring and HC conversion efficiency. In addition, temperature programed reduction (TPR) was found to lend insight into the relationship between catalyst OSC and HC conversion efficiency by providing a qualitative understanding of the mechanisms by which OSC deteriorates. TPR profiles showed that most of the usable oxygen storage is derived from surface ceria which is interacted with precious metals.