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Gasoline turbocharged direct injection (GTDI) engines, such as EcoBoost™ from Ford, are becoming established as a high value technology solution to improve passenger car and light truck fuel economy. Due to their high specific performance and excellent low-speed torque, improved fuel economy can be realized due to downsizing and downspeeding without sacrificing performance and driveability while meeting the most stringent future emissions standards with an inexpensive three-way catalyst. A logical and synergistic extension of the EcoBoost™ strategy is the use of E85 (approximately 85% ethanol and 15% gasoline) for knock mitigation. Direct injection of E85 is very effective in suppressing knock due to ethanol's high heat of vaporization - which increases the charge cooling benefit of direct injection - and inherently high octane rating. As a result, higher boost levels can be achieved while maintaining optimal combustion phasing giving high thermal efficiency.

Diesel NOx emissions control utilizing combined Lean NOx Trap (LNT) and so-called passive or in-situ Selective Catalytic Reduction (SCR) catalyst technologies (i.e. with reductant species generated by the LNT) has been the subject of several previous papers from our laboratory [ 1 - 2 ]. The present study focuses on hydrocarbon (HC) emissions control via the same LNT+SCR catalyst technology under FTP driving conditions. HC emissions control can be as challenging as NOx control under both current and future federal and California/Green State emission standards. However, as with NOx control, the combined LNT+SCR approach offers advantages for HC emission control over LNT-only aftertreatment. The incremental conversion obtained with the SCR catalyst is shown, both on the basis of vehicle and laboratory tests, to result primarily from HC adsorbed on the SCR catalyst during rich LNT purges that reacts during subsequent lean engine operation.

The Leaner Lifted-Flame Combustion (LLFC) strategy offers a possible alternative to low temperature combustion or other globally lean, premixed operation strategies to reduce soot directly in the flame, while maintaining mixing-controlled combustion. Adjustments to fuel properties, especially fuel oxygenation, have been reported to have potentially beneficial effects for LLFC applications. Six fuels were selected or blended based on cetane number, oxygen content, molecular structure, and the presence of an aromatic hydrocarbon. The experiments compared different fuel blends made of n-hexadecane, n-dodecane, methyl decanoate, tri-propylene glycol monomethyl ether (TPGME), as well as m-xylene. Several optical diagnostics have been used simultaneously to monitor the ignition, combustion and soot formation/oxidation processes from spray flames in a constant-volume combustion vessel.

During the 1980s, the U.S. Environmental Protection Agency (EPA) incorporated the R factor into fuel economy calculations in order to address concerns about the impacts of test fuel property variations on corporate average fuel economy (CAFE) compliance, which is determined using the Federal Test Procedure (FTP) and Highway Fuel Economy Test (HFET) cycles. The R factor is defined as the ratio of the percent change in fuel economy to the percent change in volumetric heating value for tests conducted using two differing fuels. At the time the R-factor was devised, tests using representative vehicles initially indicated that an appropriate value for the R factor was 0.6. Reassessing the R factor has recently come under renewed interest after EPA's March 2013 proposal to adjust the properties of certification gasoline to contain significant amounts of ethanol.

A single-cylinder Direct Injection Spark Ignition (DISI) engine with optical access was used to investigate the effects of ethanol/gasoline blends on in-cylinder formation of particulate matter (PM) and fuel spray characteristics. Indolene was used as a baseline fuel and two blends of 50% and 85% ethanol (by volume, balance indolene) were investigated. Time resolved thermal radiation (incandescence/natural luminosity) of soot particles and fuel spray characteristics were recorded using a high speed camera. The images were analyzed to quantify soot formation in units of relative image intensity as a function of important engine operating conditions, including ethanol concentration in the fuel, fuel injection timing (250, 300 and 320° bTDC), and coolant temperature (25°C and 90°C). Spatially-integrated incandescence was used as a metric to quantify the level of in-cylinder PM formed at the different operating conditions.

Engine dynamometer testing was performed comparing fuels having different octane ratings and ethanol content in a Ford 3.5L direct injection turbocharged (EcoBoost) engine at three compression ratios (CRs). The fuels included midlevel ethanol “splash blend” and “octane-matched blend” fuels, E10-98RON (U.S. premium), and E85-108RON. For the splash blends, denatured ethanol was added to E10-91RON, which resulted in E20-96RON and E30-101 RON. For the octane-matched blends, gasoline blendstocks were formulated to maintain constant RON and MON for E10, E20, and E30. The match blend E20-91RON and E30-91RON showed no knock benefit compared to the baseline E10-91RON fuel. However, the splash blend E20-96RON and E10-98RON enabled 11.9:1 CR with similar knock performance to E10-91RON at 10:1 CR. The splash blend E30-101RON enabled 13:1 CR with better knock performance than E10-91RON at 10:1 CR. As expected, E85-108RON exhibited dramatically better knock performance than E30-101RON.

This paper presents engine dynamometer testing and modeling analysis of ethanol compared to gasoline at part load conditions where the engine was not knock-limited with either fuel. The purpose of this work was to confirm the efficiency improvement for ethanol reported in published papers, and to quantify the components of the improvement. Testing comparing E85 to E0 gasoline was conducted in an alternating back-to-back manner with multiple data points for each fuel to establish high confidence in the measured results. Approximately 4% relative improvement in brake thermal efficiency (BTE) was measured at three speed-load points. Effects on BTE due to pumping work and emissions were quantified based on the measured engine data, and accounted for only a small portion of the difference.

A single-cylinder, spark-ignited engine was run on a certification test gasoline to saturate the oil in the sump with fuel through exposure to blow-by gas. The sump volume was large relative to production engines making its absorption-desorption time constant long relative to the experimental time. The engine was motored at 1500 RPM, 90° C coolant and oil temperature, and 0.43 bar MAP without fuel flow. Exhaust HC concentrations were measured by on-line FID and GC analysis. The total motoring HC emissions were 150 ppmC1; the HC species distribution was heavily weighted to the low-volatility components in the gasoline. No high volatility components were visible. The engine was then fired on isooctane fuel at the above conditions, producing a total engine-out HC emission of 2300 ppmC1 for Φ = 1.0 and MBT spark timing.

Ford Motor Company is researching and developing multiple propulsion strategies which include advanced gasoline engines, clean diesel, flexible fuel (ethanol blends up to E-85), hybrids and hydrogen propulsion, both in internal combustion (IC) engines and fuel cells. Hydrogen utilized as a transportation fuel is viewed as a long term solution as it is sustainable and clean when derived from renewable resources. The development and use of hydrogen IC engine (H2ICE) technology can readily be utilized to drive the transition strategy from the petroleum economy to the hydrogen economy. Because the “more conventional” H2ICE systems can be brought to market more quickly and in higher volume, business initiatives for hydrogen fueling infrastructure and other hydrogen complimentary required technologies can be realized sooner. To that end Ford has fully re-engineered a 6.8L Triton V-10 engine to run on hydrogen and power an E-450 shuttle van.

Until now no results have been available regarding the composition of evaporative emissions in a SHED test. In particular, for alcohol containing fuels, it is important to assess the relative percentage of alcohols and hydrocarbons in view of their different environmental impacts. This paper presents the results of a study conducted to determine the composition of the emissions from a number of multilayer coextruded plastic fuel tanks soaked in IE10 and CM15 test fuels. These emissions were analyzed for composition using a gas chromatography analytical method which employs a vapor trap and desorb sampling technique. In the case of CM15, methanol was found to account for as much as 50% of the overall evaporative emissions. This speciation method also allows estimation of how leakage and permeation contribute separately to the overall emissions.

The occurrence of flash boiling in the fuel spray of a Port Fuel Injected (PFI) spark ignition engine has been observed and photographed during normal automotive vehicle operating conditions. The flash boiling of the PFI spray has a dramatic affect on the fuel spray characteristics such as droplet size and spray cone angle which can affect engine transient response, intake valve temperature and possibly hydrocarbon emissions. A new method of correlating the spray behavior using the equilibrium vapor/liquid (V/L) volume ratio of the fuel at the measured fuel temperature and manifold pressure is introduced.

A lean-rich hydrothermal aging was used to study the deactivation of Cu-zeolite SCR catalyst that has enhanced stability. Impact of DOC upstream on the SCR catalyst during the lean-rich aging was also investigated. The LR hydrothermal aging was conducted with the presence of hydrocarbon, CO and H₂ at different O₂ levels. It was found that the SCR catalyst was active for the oxidation of CO, H₂ and hydrocarbon, resulting in significant exotherm across the catalyst. In addition to hydrothermal aging, reductive aging, especially the presence of H₂ in the aging gas stream without O₂ presence during the L-R aging, might also contribute to the Cu/zeolite SCR catalyst deactivation. The impacts of DOC upstream on Cu/zeolite SCR catalysts depended on the aging temperatures. At lower aging temperature, the uncompleted oxidation of hydrocarbon and CO on the DOC might cause steam reforming and water-gas shift reactions on the DOC to form reductive gas stream.

The catalytic activity of selected materials (BaY and NaY zeolites, and γ-alumina) for selective NOx reduction in combination with a non-thermal plasma was investigated. Our studies suggest that aldehydes, formed during the plasma treatment of simulated diesel exhaust, are the important species for the reduction of NOx to N2. Indeed, all materials that are active in plasma-assisted catalysis were found to be very effective for the thermal reduction of NOx in the presence of aldehydes. For example, the thermal catalytic activity of a BaY zeolite with aldehydes gives 80-90% NOx removal at 250°C with 200ppm NOx at the inlet and a VHSV=12,000 h-1. The hydrocarbon reductants, n-octane and 1-propyl alcohol, have also shown high thermal catalytic activity for NOx removal over BaY, NaY and γ-alumina.

We present here a phenomenological analysis of a cascade of two-step discharge-catalyst reactors. That is, each step of the cascade consists of a discharge reactor in series with a catalyst bed. These reactors are intended for use in the reduction of tailpipe emission of NOx from diesel engines. The discharge oxidizes NO to NO2, and partially oxidizes HC. The NO2 then reacts on the catalyst bed with hydrocarbons and partially oxidized HCs and is reduced to N2. The cascade may be essential because the best catalysts for this purpose that we have also convert significant fractions of the NO2 back to NO. As we show, reprocessing the gas may not only be necessary, but may also result in energy savings and increased device reliability.

This paper presents results from an experimental programme researching the in-cylinder conditions necessary to obtain homogenous CAI (or HCCI) combustion in a 4-stroke engine. The fuels under investigation include three blends of Unleaded Gasoline, a 95 RON Primary Reference Fuel, Methanol, and Ethanol. This work concentrates on establishing the CAI operating range with regard to Air/Fuel ratio and Exhaust Gas Re-circulation and their effect on the ignition timing, combustion rate and variability, Indicated thermal efficiency, and engine-out emissions such as NOx. Detailed maps are presented, defining how each of the measured variables changes over the entire CAI region. Results indicate that the alcohols have significantly higher tolerance to dilution than the hydrocarbon fuels tested. Also, variations in Gasoline blend have little effect on any of the combustion parameters measured.

Particulate and manganese mass emissions have been measured as a function of mileage for four Escort and four Explorer vehicles using 1) MMT (Methylcyclopentadienyl Manganese Tricarbonyl) added to the gasoline at 1/32 g Mn/gal and 2) gasoline without MMT. The MMT was used in half of the fleet starting at 5,000 miles. The vehicles were driven on public roads at an average speed of 54 mph to accumulate mileage. This report describes the particulate and manganese emissions, plus emissions of four air toxics at 5,000, 20,000, 55,000, 85,000 and 105,000 miles. Four non-regulated emissions were measured and their average values for vehicles without MMT were 0.6 mg/mi for formaldehyde, 0.7 mg/mi for 1,3-butadiene, 9 mg/mi for benzene and 12 mg/mi for toluene. Corresponding values for MMT-fueled vehicles were between 1.5 and 2.4 times higher.

Measurements of oxygen storage capacity (OSC) and HC conversion efficiency for 17 catalysts were carried out in the laboratory. All catalysts with steady state HC efficiency below 90% were found to have roughly equivalent and very low capacities to store oxygen. However, catalyst oxygen storage capacity was seen to rise sharply with HC conversion efficiency in excess of 90 percent. These results parallel the trends which are observed between rear HEGO/EGO indexes for OBD-II catalyst monitoring and HC conversion efficiency. In addition, temperature programed reduction (TPR) was found to lend insight into the relationship between catalyst OSC and HC conversion efficiency by providing a qualitative understanding of the mechanisms by which OSC deteriorates. TPR profiles showed that most of the usable oxygen storage is derived from surface ceria which is interacted with precious metals.

The fuel effects on HCCI operation in a spark assisted direct injection gasoline engine are assessed. The low load limit has been extended with a pilot fuel injection during the negative valve overlap (NVO) period. The fuel matrix consists of hydrocarbon fuels and various ethanol blends and a butanol blend, plus fuels with added ignition improvers. The hydrocarbon fuels and the butanol blend do not significantly alter the high or the low limits of operation. The HCCI operation appears to be controlled more by the thermal environment than by the fuel properties. For E85, the engine behavior depends on the extent that the heat release from the pilot injected fuel in the NVO period compensates for the evaporative cooling of the fuel.

A proportional sampler for vehicle feedgas and tailpipe emissions has been developed that extracts a small, constant fraction of the total exhaust flow during rapid transient changes in engine speed. Heated sampling lines are used to extract samples either before or after the catalytic converter. Instantaneous exhaust mass flow is measured by subtracting the CVS dilution air volume from the total CVS volume. This parameter is used to maintain a constant dilution ratio and proportional sample. The exhaust sample is diluted with high-purity air or nitrogen and is delivered into Tedlar sample bags. These transient test cycle weighted feedgas samples can be collected for subsequent analysis of hydrocarbons and oxygenated hydrocarbon species. This “mini-diluter” offers significant advantages over the conventional CVS system. The concentration of the samples are higher than those collected from the current CVS system because the dilution ratio can be optimized depending on the fuel.

Bench reactor experiments were carried out to investigate the effects of operating temperature, precious metal loading, space velocity, and air-fuel (A/F) ratio on the performance of palladium (Pd) catalysts under simulated natural gas vehicle (NGV) exhaust conditions. The performance of these catalysts under simulated gasoline vehicle (GV) conditions was also investigated. In the case of simulated NGV exhaust, where methane was used as the prototypical hydrocarbon (HC) species, peak three-way conversion was obtained under richer conditions than required with simulated GV exhaust (propane and propene HC species). Moreover, the hydrocarbon efficiency of the catalyst under simulated NGV exhaust conditions was more sensitive to both A/F ratio and perturbations in A/F ratio than the HC efficiency under GV exhaust conditions.