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Journal Article

Advancements and Opportunities for On-Board 700 Bar Compressed Hydrogen Tanks in the Progression Towards the Commercialization of Fuel Cell Vehicles

2017-03-28
2017-01-1183
Fuel cell vehicles are entering the automotive market with significant potential benefits to reduce harmful greenhouse emissions, facilitate energy security, and increase vehicle efficiency while providing customer expected driving range and fill times when compared to conventional vehicles. One of the challenges for successful commercialization of fuel cell vehicles is transitioning the on-board fuel system from liquid gasoline to compressed hydrogen gas. Storing high pressurized hydrogen requires a specialized structural pressure vessel, significantly different in function, size, and construction from a gasoline container. In comparison to a gasoline tank at near ambient pressures, OEMs have aligned to a nominal working pressure of 700 bar for hydrogen tanks in order to achieve the customer expected driving range of 300 miles.
Journal Article

Developing Safety Standards for FCVs and Hydrogen Vehicles

2009-04-20
2009-01-0011
The SAE Fuel Cell Vehicle (FCV) Safety Working Group has been addressing FCV safety for over 9 years. The initial document, SAE J2578, was published in 2002. SAE J2578 has been valuable as a Recommended Practice for FCV development with regard to the identification of hazards and the definition of countermeasures to mitigate these hazards such that FCVs can be operated in the same manner as conventional gasoline internal combustion engine (ICE)-powered vehicles. SAE J2578 is currently being revised so that it will continue to be relevant as FCV development moves forward. For example, test methods were refined to verify the acceptability of hydrogen discharges when parking in residential garages and commercial structures and after crash tests prescribed by government regulation, and electrical requirements were updated to reflect the complexities of modern electrical circuits which interconnect both AC and DC circuits to improve efficiency and reduce cost.
Journal Article

Developing Safety Standards for FCVs and Hydrogen Vehicles

2008-04-14
2008-01-0725
The SAE FCV Safety Working Group has been addressing fuel cell vehicle (FCV) safety for over 8 years. The initial document, SAE J2578, was published in 2002. SAE J2578 has been valuable to FCV development with regard to the identification of hazards and the definition of countermeasures to mitigate these hazards such that FCVs can be operated in the same manner as conventional gasoline internal combustion engine (ICE)-powered vehicles. J2578 is currently being updated to clarify and update requirements so that it will continue to be relevant and useful in the future. An update to SAE J1766 for post-crash electrical safety was also published to reflect unique aspects of FCVs and to harmonize electrical requirements with international standards. In addition to revising SAE J2578 and J1766, the Working Group is also developing a new Technical Information Report (TIR) for vehicular hydrogen systems (SAE J2579).
Journal Article

Motor Vehicle PM Emissions Measurement at LEV III Levels

2011-04-12
2011-01-0623
This paper examines the issues concerning particulate matter (PM) emissions measurement at the 3 mg/mi level proposed as the future LEV III standard. These issues are general in nature, but are exacerbated at the low levels contemplated for upcoming emissions standards. They are discussed in the context of gasoline direct injection (GDI) engines, where they can have an important impact on the continued development of this technology for improved fuel economy. GDI particulate emissions, just as engine-out diesel PM, contain a high fraction of soot. But the total PM mass is significantly lower than from diesel engines, and there can be significant variations in emissions rate and apparent PM composition between cold-start and running emissions. PM emissions levels depend on sampling method and location. As a result, there can be substantial differences in PM sampled and diluted directly at the exhaust pipe, as opposed to measurements from a dilution tunnel.
Journal Article

Passive Hydrocarbon Trap to Enable SULEV-30 Tailpipe Emissions from a Flex-Fuel Vehicle on E85 Fuel

2018-04-03
2018-01-0944
Future LEV-III tailpipe (TP) emission regulations pose an enormous challenge forcing the fleet average of light-duty vehicles produced in the 2025 model year to perform at the super ultralow emission vehicle (SULEV-30) certification levels (versus less than 20% produced today). To achieve SULEV-30, regulated TP emissions of non-methane organic gas (NMOG) hydrocarbons (HCs) and oxygenates plus oxides of nitrogen (NOx) must be below a combined 30 mg/mi (18.6 mg/km) standard as measured on the federal emissions certification cycle (FTP-75). However, when flex-fuel vehicles use E85 fuel instead of gasoline, NMOG emissions at cold start are nearly doubled, before the catalytic converter is active. Passive HC traps (HCTs) are a potential solution to reduce TP NMOG emissions. The conventional HCT design was modified by changing the zeolite chemistry so as to improve HC retention coupled with more efficient combustion during the desorption phase.
Journal Article

On-Board Physical Based 70 MPa Hydrogen Storage Systems

2011-04-12
2011-01-1343
Fossil energy diversity and security along with environmental emission policies demand new energy carriers and associated technologies in the future. One of the major challenges of the automotive industry and research institutes worldwide currently is to develop and realize alternative fuel concepts for passenger cars. In line with Ford's global hydrogen vehicle program, different onboard hydrogen storage technologies are under investigation. In general, hydrogen storage methods can be categorized as either physical storage of hydrogen (i.e. compressed, liquid, or cryo-compressed) or material based hydrogen storage. Currently, automotive OEMs have only introduced hydrogen fleet vehicles that utilize physical-based hydrogen storage systems but they have recognized that hydrogen storage systems need to advance further to achieve the range associated with today's gasoline vehicle.
Technical Paper

Developing Safety Standards for FCVs and Hydrogen Vehicles

2007-04-16
2007-01-0436
The SAE FCV Safety Working Group has been addressing fuel cell vehicle (FCV) safety for over 7 years. The initial document, SAE J2578, was published in 2002. SAE J2578 has been valuable to the FCV development with regard to the identification of hazards and the definition of countermeasures to mitigate these hazards such that FCVs can be operated in the same manner as conventional gasoline IC-powered vehicles. The document is currently being updated to clarify and update requirements so that the document will continue to be relevant and useful in the future. In addition to developing draft revisions to SAE J2578, the working group has updated SAE J1766 and is developing a new recommended practice on vehicular hydrogen systems (SAE J2579). The documents are written from the standpoint of systems-level, performance-based requirements. A risk-based approach was used to identify potential electrical and fuel system hazards and provide criteria for acceptance.
Technical Paper

Development of a New Oxygen Storage Model for SIMTWC

2007-04-16
2007-01-1081
The high conversion efficiency required by the modern three-way catalyst (TWC) is dependent on oxygen storage material functionality and capacity. To successfully model a TWC, it is critical that the oxygen storage function in the catalyst be adequately represented. The original oxygen storage model (a simple “bucket” model) included in one of Ford's TWC models, SIMTWC, was developed for vehicle programs meeting LEV emission standards. Application of SIMTWC to test data from vehicles targeting more stringent emission standards, such as ULEV and PZEV, revealed limitations in the accuracy of the original bucket model. To address these limitations, an improved kinetic model of oxygen storage is being developed. This new model is more kinetically-detailed than the old model.
Technical Paper

The Design for Six Sigma Approach for the Development of a Carbon Canister for Tier II, LEV II and PZEV Emission Levels

2007-04-16
2007-01-1090
Global concerns involving smog, ozone formation, carcinogens and greenhouse gases have produced increasingly stringent governmental emission regulations worldwide. In the United States, the Environmental Protection Agency (EPA) introduced Tier II emissions regulations and the California Air Resources Board (CARB) established Low Emission Vehicles (LEV II) and Partial Zero Emission Vehicles (PZEV) legislation. These initiatives have created the most stringent emissions regulations to date. Vehicle manufacturers have had to improve their evaporative emission control systems to comply with these standards. The evaporative emission control system is engineered to protect our environment from fuel vapor emissions. The carbon canister is the most important component of the evaporative emissions system due to its ability to capture fuel vapors continuously during the life of the vehicle. Ford Motor Company redesigned its carbon canisters after utilizing Experimental Design techniques.
Technical Paper

A Comparison of Different Methods for Battery and Supercapacitor Modeling

2003-06-23
2003-01-2290
In future vehicles (e.g. fuel cell vehicles, hybrid electric vehicles), the electrical system will have an important impact on the mechanical systems in the car (e.g. powertrain, steering). Furthermore, this coupling will become increasingly important over time. In order to develop effective designs and appropriate control systems for these systems, it is important that the plant models capture the detailed physical behavior in the system. This paper will describe models of two electrical components, a battery and a supercapacitor, which have been modeled in two ways: (i) modeling the plant and controller using block diagrams in Simulink and (ii) modeling the plant and controller in Dymola followed by compiling this model to an S-function for simulation in Simulink. Both the battery and supercapacitor model are based on impedance spectroscopy measurements and can be used for highly dynamic simulations.
Technical Paper

Architecture and Development of a Hydrogen Sensing and Mitigation System in H2RV - Ford's Concept HEV Propelled With a Hydrogen Engine

2004-03-08
2004-01-0359
Ford's Hydrogen Hybrid Research Vehicle (H2RV) is an industry first parallel hybrid vehicle utilizing a hydrogen internal combustion engine. The goal of this drivable concept vehicle is to marry Ford's extensive hybrid powertrain experience with its hydrogen internal combustion engine technology to produce a low emission, fuel-efficient vehicle. This vehicle is seen as a possible bridge from the petroleum fueled vehicles of today to the fuel cell vehicles envisioned for tomorrow. A multi-layered hydrogen management strategy was developed for the H2RV. All aspects of the vehicle including the design of the fuel and electrical systems, placement of high-voltage subsystems, and testing, service, and storage procedures were examined to ensure the safe operation of the vehicle. The results of these reviews led to the design of the hydrogen sensing and mitigation system for the H2RV vehicle.
Technical Paper

Hydrogen Consumption Measurement for Fuel Cell Vehicles

2004-03-08
2004-01-1008
Fuel cell vehicle fuel consumption measurement is considerably different from internal combustion engine vehicle fuel consumption measurement. Conventional Carbon Balance Method and Flow Measurement methods for gas consumption within combustion engines are not suitable for fuel cell vehicles. The small quantities of fuel consumed and the characteristics of hydrogen itself impose a challenge for the hydrogen measurement. This paper addresses fuel consumption measurement for fuel cell vehicles using various methods such as mass flow measurement, pressure/temperature/volume method, weigh method as well as other methods. The advantages and disadvantages of these methods are discussed.
Technical Paper

Hydrogen Fuel Cell Vehicle Fuel Economy Measurements and Calculation

2004-03-08
2004-01-1339
Hydrogen Fuel cell vehicles, and techniques for fuel economy measurement and fuel economy calculations are considerably different from those traditionally used fro combustion engine vehicles.. Like gasoline or diesel hybrid vehicles, fuel cell vehicles typically use batteries or other power systems such as super-capacitors for load leveling. Thus, the energy transfer or consumption from these supplemental power sources to the drive train should be compensated for when determining fuel consumption or fuel economy. This paper addresses fuel economy calculations and testing for hybrid hydrogen fuel cell vehicles. The impact of supplemental power systems to a fuel cell vehicle's fuel economy and the various methods to derive actual vehicle fuel economy with supplemental power system usage are discussed.
Technical Paper

Overall Results: Phase I Ad Hoc Diesel Fuel Test Program

2001-03-05
2001-01-0151
The future of diesel-engine-powered passenger cars and light-duty vehicles in the United States depends on their ability to meet Federal Tier 2 and California LEV2 tailpipe emission standards. The experimental purpose of this work was to examine the potential role of fuels; specifically, to determine the sensitivity of engine-out NOx and particulate matter (PM) to gross changes in fuel formulation. The fuels studied were a market-average California baseline fuel and three advanced low sulfur fuels (<2 ppm). The advanced fuels were a low-sulfur-highly-hydrocracked diesel (LSHC), a neat (100%) Fischer-Tropsch (FT100) and 15% DMM (dimethoxy methane) blended into LSHC (DMM15). The fuels were tested on modern, turbocharged, common-rail, direct-injection diesel engines at DaimlerChrysler, Ford and General Motors. The engines were tested at five speed/load conditions with injection timing set to minimize fuel consumption.
Technical Paper

Flame Ionization Detector Oxygen Quench Effects on Hydrocarbon Emission Results

2004-06-08
2004-01-1960
The Flame Ionization Detector (FID) used to measure hydrocarbon content in emission samples uses a hydrogen flame that produces little ionization. Hydrocarbons introduced into this flame produce large numbers of ions with ionization proportional to the number of carbon atoms present. This proportionality can be skewed by variations in oxygen content. Oxygen variation in emission samples, cylinders of air or span/calibration gas, and zero air systems are investigated and their effects on emission results are discussed. The oxygen content of the gas under analysis will affect the hydrocarbon concentration reported by the FID. In the example examined in this paper, the oxygen effect was shown to decrease the FTP (Federal Test Procedure) weighted NMHC (Non-Methane Hydrocarbon) results by as much as 7 % for a BMD (Bag Mini-Diluter) sample and 13% for a CVS (Constant Volume Sampling) sample.
Technical Paper

Auto-Generated Production Code Development for Ford/Think Fuel Cell Vehicle Programme

2003-03-03
2003-01-0863
Pi Technology and the Ford Motor Company are using MATLAB Simulink/Stateflow model based design and automatic code generation in C, for the main software development for three electronic control units targeted at the Ford Focus fuel cell vehicle. The automatic generation of code for embedded automotive applications offers a number of potential advantages over traditional methods. These include faster development, the avoidance of coding errors and avoiding inconsistencies with the design specification. However, the use of automatically generated code in production-intent safety-related systems requires at least the same standard of validation and verification. If code generation were perfect, one could validate only the design. However, it is impractical to require that the code generator must be validated for all possible input designs. Furthermore it must be assumed that the compiler and the hardware can also introduce faults.
Technical Paper

Development of the Direct Nonmethane Hydrocarbon Measurement Technique for Vehicle Testing

2003-03-03
2003-01-0390
The Automotive Industry/Government Emissions Research CRADA (AIGER) has been working to develop a new methodology for the direct determination of nonmethane hydrocarbons (DNMHC) in vehicle testing. This new measurement technique avoids the need for subtraction of a separately determined methane value from the total hydrocarbon measurement as is presently required by the Code of Federal Regulations. This paper will cover the historical aspects of the development program, which was initiated in 1993 and concluded in 2002. A fast, gas chromatographic (GC) column technology was selected and developed for the measurement of the nonmethane hydrocarbons directly, without any interference or correction being caused by the co-presence of sample methane. This new methodology chromatographically separates the methane from the nonmethane hydrocarbons, and then measures both the methane and the backflushed, total nonmethane hydrocarbons using standard flame ionization detection (FID).
Technical Paper

Exhaust System Thermal Management: A Process to Optimize Exhaust Enthalpy for Cold Start Emissions Reduction

2017-03-28
2017-01-0141
Future vehicle North American emissions standards (e.g., North American Tier 3 Bin 30 or LEVIII SULEV 30) require the exhaust catalyst to be greater than 80% efficient by 20 seconds after the engine has been started in the Federal Test Procedure. Turbocharged engines are especially challenged to deliver fast catalyst light-off since the presence of the turbocharger in the exhaust flow path significantly increases exhaust system heat losses. A solution to delivering cost effective SULEV 30 emissions in turbocharged engines is to achieve fast catalyst light-off by reducing exhaust system heat losses in cold start, without increasing catalyst thermal degradation during high load operation. A CAE methodology to assess the thermal performance of exhaust system hardware options, from the exhaust port to the catalyst brick face is described, which enables compliance with future emissions regulations.
Technical Paper

Method to Enhance Fuel Cell Powertrain System Robustness by Reducing Cathode Potential during Start-Up Condition

2017-03-28
2017-01-1186
This study investigates a system and a method to enhance fuel cell vehicle robustness during vehicle start/stop cycle by mitigating cathode half-cell potential spikes. Multiple dynamic hydrogen reference electrodes were installed in the fuel cell under test to observe changes of anode and cathode half-cell potentials during simulated system startup and shutdown conditions. Multiple reference electrodes were used to measure localized anode and cathode half-cell potentials in an active area. A 1.4-1.8 V half-cell potential spike at the cathode in the startup condition was observed due to a hydrogen/air boundary formed within the anode flow field. Various system solutions have been studied to contain the cathode half-cell potential spikes, such as purging with inert gas, or inserting a shunt resistor as a shorting component between the anode and the cathode. In this study, a method of connecting an electrical load prior to flowing hydrogen fuel to the cell was tested.
Technical Paper

Development of a Vehicle-Level Simulation Model for Evaluating the Trade-Off between Various Advanced On-Board Hydrogen Storage Technologies for Fuel Cell Vehicles

2012-04-16
2012-01-1227
One of the most critical elements in engineering a hydrogen fuel cell vehicle is the design of the on-board hydrogen storage system. Because the current compressed-gas hydrogen storage technology has several key challenges, including cost, volume and capacity, materials-based storage technologies are being evaluated as an alternative approach. These materials-based hydrogen storage technologies include metal hydrides, chemical hydrides, and adsorbent materials, all of which have drawbacks of their own. To optimize the engineering of storage systems based on these materials, it is critical to understand the impacts these systems will have on the overall vehicle system performance and what trade-offs between the hydrogen storage systems and the vehicle systems might exist that allow these alternative storage approaches to be viable.
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