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Fuel cell vehicles are entering the automotive market with significant potential benefits to reduce harmful greenhouse emissions, facilitate energy security, and increase vehicle efficiency while providing customer expected driving range and fill times when compared to conventional vehicles. One of the challenges for successful commercialization of fuel cell vehicles is transitioning the on-board fuel system from liquid gasoline to compressed hydrogen gas. Storing high pressurized hydrogen requires a specialized structural pressure vessel, significantly different in function, size, and construction from a gasoline container. In comparison to a gasoline tank at near ambient pressures, OEMs have aligned to a nominal working pressure of 700 bar for hydrogen tanks in order to achieve the customer expected driving range of 300 miles.

This paper describes a proton-exchange-membrane Fuel Cells (FC) system dynamic model oriented to automotive applications. The dynamic model allows analysis of FC system transient response and can be used for: a) performance assessment; b) humidification analysis; c) analysis of special modes of operation, e.g., extended idle or freeze start; d) model based FC control design and validation. The model implements a modular structure with first principle based components representation. Emphasis is placed on development of a 1-D membrane water transport model used to simulate gas to gas humidification and stack membrane water diffusion. The Simulink implementation of the model is discussed and results showing FC system transient behavior are presented.

Accounting for more than 90% of the molecules and more than 75% of the mass [1], hydrogen is the most abundant element in the universe. Due to the small molecule size and high buoyancy, it is not available in it’s free form on Earth. In recent years, hydrogen has gained the attention of the automotive industry [2–12] as an environmentally friendly alternative fuel. As a fuel, hydrogen is unique - it is odorless, colorless, tasteless, and burns invisibly in sunlight. Detection solutions such as the odorants used in natural gas are not yet feasible for automotive hydrogen because the available additives can poison the fuel cell catalyst. Additionally, the lower flammability limit of hydrogen is lower, and the flammability range wider, than fuels such as gasoline [13]. Hydrogen detection and its concentration measurement is usually done using hydrogen concentration sensors [13].

This paper examines the issues concerning particulate matter (PM) emissions measurement at the 3 mg/mi level proposed as the future LEV III standard. These issues are general in nature, but are exacerbated at the low levels contemplated for upcoming emissions standards. They are discussed in the context of gasoline direct injection (GDI) engines, where they can have an important impact on the continued development of this technology for improved fuel economy. GDI particulate emissions, just as engine-out diesel PM, contain a high fraction of soot. But the total PM mass is significantly lower than from diesel engines, and there can be significant variations in emissions rate and apparent PM composition between cold-start and running emissions. PM emissions levels depend on sampling method and location. As a result, there can be substantial differences in PM sampled and diluted directly at the exhaust pipe, as opposed to measurements from a dilution tunnel.

Future LEV-III tailpipe (TP) emission regulations pose an enormous challenge forcing the fleet average of light-duty vehicles produced in the 2025 model year to perform at the super ultralow emission vehicle (SULEV-30) certification levels (versus less than 20% produced today). To achieve SULEV-30, regulated TP emissions of non-methane organic gas (NMOG) hydrocarbons (HCs) and oxygenates plus oxides of nitrogen (NOx) must be below a combined 30 mg/mi (18.6 mg/km) standard as measured on the federal emissions certification cycle (FTP-75). However, when flex-fuel vehicles use E85 fuel instead of gasoline, NMOG emissions at cold start are nearly doubled, before the catalytic converter is active. Passive HC traps (HCTs) are a potential solution to reduce TP NMOG emissions. The conventional HCT design was modified by changing the zeolite chemistry so as to improve HC retention coupled with more efficient combustion during the desorption phase.

Fossil energy diversity and security along with environmental emission policies demand new energy carriers and associated technologies in the future. One of the major challenges of the automotive industry and research institutes worldwide currently is to develop and realize alternative fuel concepts for passenger cars. In line with Ford's global hydrogen vehicle program, different onboard hydrogen storage technologies are under investigation. In general, hydrogen storage methods can be categorized as either physical storage of hydrogen (i.e. compressed, liquid, or cryo-compressed) or material based hydrogen storage. Currently, automotive OEMs have only introduced hydrogen fleet vehicles that utilize physical-based hydrogen storage systems but they have recognized that hydrogen storage systems need to advance further to achieve the range associated with today's gasoline vehicle.

The high conversion efficiency required by the modern three-way catalyst (TWC) is dependent on oxygen storage material functionality and capacity. To successfully model a TWC, it is critical that the oxygen storage function in the catalyst be adequately represented. The original oxygen storage model (a simple “bucket” model) included in one of Ford's TWC models, SIMTWC, was developed for vehicle programs meeting LEV emission standards. Application of SIMTWC to test data from vehicles targeting more stringent emission standards, such as ULEV and PZEV, revealed limitations in the accuracy of the original bucket model. To address these limitations, an improved kinetic model of oxygen storage is being developed. This new model is more kinetically-detailed than the old model.

Global concerns involving smog, ozone formation, carcinogens and greenhouse gases have produced increasingly stringent governmental emission regulations worldwide. In the United States, the Environmental Protection Agency (EPA) introduced Tier II emissions regulations and the California Air Resources Board (CARB) established Low Emission Vehicles (LEV II) and Partial Zero Emission Vehicles (PZEV) legislation. These initiatives have created the most stringent emissions regulations to date. Vehicle manufacturers have had to improve their evaporative emission control systems to comply with these standards. The evaporative emission control system is engineered to protect our environment from fuel vapor emissions. The carbon canister is the most important component of the evaporative emissions system due to its ability to capture fuel vapors continuously during the life of the vehicle. Ford Motor Company redesigned its carbon canisters after utilizing Experimental Design techniques.

IC engines have been the dominant automotive powertrain in the 20th century because of their advantages in power density, thermal efficiency, simplicity, durability and mobility. Condensing 100 years of information on automotive engine system technology evolution shows five different development stages: “bone and muscle”, “instinct”, “nerve and brain”, “intelligence”, and “system optimization”. Currently, the last step is facing the pressure of the “clean revolution” plus the “e-commerce revolution”. To meet future emission requirements and reduce CO2 emissions, the conventional engine system will be pushed to new physical limits, leading to higher cost and reduced durability. Therefore, the automobile industry should consider re-engineering or system optimization of the engines, including configuring the system architecture to be as transparent as possible to suit the fast changing environment of e-commerce.

Hydrogen Fuel cell vehicles, and techniques for fuel economy measurement and fuel economy calculations are considerably different from those traditionally used fro combustion engine vehicles.. Like gasoline or diesel hybrid vehicles, fuel cell vehicles typically use batteries or other power systems such as super-capacitors for load leveling. Thus, the energy transfer or consumption from these supplemental power sources to the drive train should be compensated for when determining fuel consumption or fuel economy. This paper addresses fuel economy calculations and testing for hybrid hydrogen fuel cell vehicles. The impact of supplemental power systems to a fuel cell vehicle's fuel economy and the various methods to derive actual vehicle fuel economy with supplemental power system usage are discussed.

The future of diesel-engine-powered passenger cars and light-duty vehicles in the United States depends on their ability to meet Federal Tier 2 and California LEV2 tailpipe emission standards. The experimental purpose of this work was to examine the potential role of fuels; specifically, to determine the sensitivity of engine-out NOx and particulate matter (PM) to gross changes in fuel formulation. The fuels studied were a market-average California baseline fuel and three advanced low sulfur fuels (<2 ppm). The advanced fuels were a low-sulfur-highly-hydrocracked diesel (LSHC), a neat (100%) Fischer-Tropsch (FT100) and 15% DMM (dimethoxy methane) blended into LSHC (DMM15). The fuels were tested on modern, turbocharged, common-rail, direct-injection diesel engines at DaimlerChrysler, Ford and General Motors. The engines were tested at five speed/load conditions with injection timing set to minimize fuel consumption.

The Flame Ionization Detector (FID) used to measure hydrocarbon content in emission samples uses a hydrogen flame that produces little ionization. Hydrocarbons introduced into this flame produce large numbers of ions with ionization proportional to the number of carbon atoms present. This proportionality can be skewed by variations in oxygen content. Oxygen variation in emission samples, cylinders of air or span/calibration gas, and zero air systems are investigated and their effects on emission results are discussed. The oxygen content of the gas under analysis will affect the hydrocarbon concentration reported by the FID. In the example examined in this paper, the oxygen effect was shown to decrease the FTP (Federal Test Procedure) weighted NMHC (Non-Methane Hydrocarbon) results by as much as 7 % for a BMD (Bag Mini-Diluter) sample and 13% for a CVS (Constant Volume Sampling) sample.

The Automotive Industry/Government Emissions Research CRADA (AIGER) has been working to develop a new methodology for the direct determination of nonmethane hydrocarbons (DNMHC) in vehicle testing. This new measurement technique avoids the need for subtraction of a separately determined methane value from the total hydrocarbon measurement as is presently required by the Code of Federal Regulations. This paper will cover the historical aspects of the development program, which was initiated in 1993 and concluded in 2002. A fast, gas chromatographic (GC) column technology was selected and developed for the measurement of the nonmethane hydrocarbons directly, without any interference or correction being caused by the co-presence of sample methane. This new methodology chromatographically separates the methane from the nonmethane hydrocarbons, and then measures both the methane and the backflushed, total nonmethane hydrocarbons using standard flame ionization detection (FID).

Future vehicle North American emissions standards (e.g., North American Tier 3 Bin 30 or LEVIII SULEV 30) require the exhaust catalyst to be greater than 80% efficient by 20 seconds after the engine has been started in the Federal Test Procedure. Turbocharged engines are especially challenged to deliver fast catalyst light-off since the presence of the turbocharger in the exhaust flow path significantly increases exhaust system heat losses. A solution to delivering cost effective SULEV 30 emissions in turbocharged engines is to achieve fast catalyst light-off by reducing exhaust system heat losses in cold start, without increasing catalyst thermal degradation during high load operation. A CAE methodology to assess the thermal performance of exhaust system hardware options, from the exhaust port to the catalyst brick face is described, which enables compliance with future emissions regulations.

This study investigates a system and a method to enhance fuel cell vehicle robustness during vehicle start/stop cycle by mitigating cathode half-cell potential spikes. Multiple dynamic hydrogen reference electrodes were installed in the fuel cell under test to observe changes of anode and cathode half-cell potentials during simulated system startup and shutdown conditions. Multiple reference electrodes were used to measure localized anode and cathode half-cell potentials in an active area. A 1.4-1.8 V half-cell potential spike at the cathode in the startup condition was observed due to a hydrogen/air boundary formed within the anode flow field. Various system solutions have been studied to contain the cathode half-cell potential spikes, such as purging with inert gas, or inserting a shunt resistor as a shorting component between the anode and the cathode. In this study, a method of connecting an electrical load prior to flowing hydrogen fuel to the cell was tested.

One of the most critical elements in engineering a hydrogen fuel cell vehicle is the design of the on-board hydrogen storage system. Because the current compressed-gas hydrogen storage technology has several key challenges, including cost, volume and capacity, materials-based storage technologies are being evaluated as an alternative approach. These materials-based hydrogen storage technologies include metal hydrides, chemical hydrides, and adsorbent materials, all of which have drawbacks of their own. To optimize the engineering of storage systems based on these materials, it is critical to understand the impacts these systems will have on the overall vehicle system performance and what trade-offs between the hydrogen storage systems and the vehicle systems might exist that allow these alternative storage approaches to be viable.

In Fall of 2001, a new emissions test cell was installed at Ford Motor Company that was specifically designed for precise low-level measurements (as described in Reference 6). The primary design focus for this cell was to ensure that optimal measurement capability was available to test vehicles that meet the stringent Partial Zero Emission Vehicle (PZEV) tailpipe requirements (NMOG = 10 mg/mile, NOx = 20 mg/mile). Over the past four years, there have been numerous improvements to the operational and Quality Assurance (QA) practices used in the PZEV Test Cell. Several investigations have also been performed to demonstrate the quality of its emissions measurements. Finally, a number of “lessons learned” have been documented from our experiences with PZEV measurements and with testing hybrid-electric vehicles. This paper summarizes these findings as a reference for others interested in low-level emissions measurements.

In this paper the application of Statistical Energy Analysis (SEA) to the sound package design for a fuel cell powered sedan is presented. Fuel cell vehicles represent a different challenge to a vehicle with a conventional powertrain. With the replacement of the internal combustion engine (ICE), a principal source of airborne and structure-borne powertrain noise, the expectation is that the cabin noise levels would be significantly reduced as the main noise sources would be road and wind noise. A fuel cell powertrain, however, has a number of mechanical sources on the body structure that will radiate airborne noise and may transmit significant structure-borne noise to the vehicle interior. With this alternative power train, much of the conventional wisdom on vehicle sound package developed from experience with ICE's must be reconsidered.

The High Voltage Power Distribution Unit (PDU) is constructed of magnesium in support of Fuel Cell Electric Vehicle (FCEV) weight reduction efforts. The PDU distributes and controls a nominal 75 kilowatts of power generated by the Fuel Cell, the primary source of High Voltage power, to all the vehicle loads and accessories. The constraints imposed on the design of the PDU resulted in a component highly susceptible to general and galvanic corrosion. Corrosion abatement was the focus of the PDU redesign. This paper describes the redesign efforts undertaken by Ford personnel to improve the part robustness and corrosion resistance.

Development of propulsion control systems frequently involves large-scale transient simulations, e.g. Monte Carlo simulations or drive-cycle optimizations, which require fast dynamic plant models. Models of the air-path—for internal combustion engines or fuel cells—can exhibit stiff behavior, though, causing slow numerical simulations due to either using an implicit solver or sampling much faster than the bandwidth of interest to maintain stability. This paper proposes a method to reduce air-path model stiffness by adding an impedance in series with potentially stiff components, e.g. throttles, valves, compressors, and turbines, thereby allowing the use of a fast-explicit solver. An impedance, by electrical analogy, is a frequency-dependent resistance to flow, which is shaped to suppress the high-frequency dynamics causing air-path stiffness, while maintaining model accuracy in the bandwidth of interest.