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Organic acid degradation products and other anions in engine oil were speciated by capillary electrophoresis (CE) and liquid chromatography-mass spectrometry (LCMS) with electrospray ionization. The sample preparation procedure involved selectively extracting the acids and other water soluble salts into 0.05M aqueous potassium hydroxide. Samples of engine-aged mineral oil and synthetic engine oil contained formic acid, acetic acid, and complex mixtures of fatty acid degradation products. CE analysis of formic acid, acetic acid and selected fatty acids is proposed as a new chemical analysis method for evaluating the condition of engine oil and for studying the effects of high temperature-high load (HTHL) oxidation. Because the overall pattern of CE peaks in the electropherogram changes with oil age or condition, CE-fingerprint (i.e., pattern recognition) techniques may also be useful for evaluating an aged oil's condition or remaining service life.

A pilot-main injection strategy is investigated for a part-load operating point in a single cylinder optical Diesel engine. As the energizing dwell between the pilot and main injections decreases below 200 μs, combustion noise reaches a minimum and a reduction of 3 dB is possible. This decrease in combustion noise is achieved without increased pollutant emissions. Injection schedules employed in the engine are analyzed with an injection analyzer to provide injection rates for each dwell tested. Two distinct injection events are observed even at the shortest dwell tested; rate shaping of the main injection occurs as the dwell is adjusted. High-speed elastic scattering imaging of liquid fuel is performed in the engine to examine initial liquid penetration rates.

Cost and robustness are key factors in the design of diesel engines for low power density applications. Although compression ignition engines can produce very high power density output with turbocharging, naturally aspirated (NA) engines have advantages in terms of reduced cost and avoidance of system complexity. This work explores the use of direct injection (DI) and exhaust gas recirculation (EGR) in NA engines using experimental data from a single-cylinder research diesel engine. The engine was operated with a fixed atmospheric intake manifold pressure over a map of speed, air-to-fuel ratio, EGR, fuel injection pressure and injection timing. Conventional gaseous engine-out emissions were measured along with high speed cylinder pressure data to show the load limits and resulting emissions of the NA-DI engine studied. Well known reductions in NOX with increasing levels of EGR were confirmed with a corresponding loss in peak power output.

An investigation of high speed direct injection (DI) compression ignition (CI) engine combustion fueled with gasoline injected using a triple-pulse strategy in the low temperature combustion (LTC) regime is presented. This work aims to extend the operation ranges for a light-duty diesel engine, operating on gasoline, that have been identified in previous work via extended controllability of the injection process. The single-cylinder engine (SCE) was operated at full load (16 bar IMEP, 2500 rev/min) and computational simulations of the in-cylinder processes were performed using a multi-dimensional CFD code, KIVA-ERC-Chemkin, that features improved sub-models and the Chemkin library. The oxidation chemistry of the fuel was calculated using a reduced mechanism for primary reference fuel combustion chosen to match ignition characteristics of the gasoline fuel used for the SCE experiments.

Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution hardware used for transportation of fuel from refineries and to buffer the potential organic acids present in an ethanol blended fuel to enhance storage stability. The impact of these inhibitors on spark-ignition engine fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the corrosion inhibitors to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a second market place survey of corrosion inhibitors and how they vary in concentration in the final blended fuel, specifically E85 (Ethanol Fuel Blends); and, to show how the variation in the concentrations of the components of the CIs impacts the operation and performance of vehicles, specifically, the effects on intake valve deposit formation.

Polyacetals have high strength, modulus, and chemical resistance with good dimensional stability. Because of these properties, they are used in a number of automotive applications. The injection molding process used for the molding of these components is complex and requires the adjustment of multiple process parameters to produce parts. Typically, physical tests are used to confirm that tensile strength is achieved in processing. A study was undertaken with an impact modified carbon powder filled, acetal copolymer to determine the effect of variation in process parameters on other material properties in addition to tensile strength. These material properties were measured dry as-molded and after exposure to heat and to a test fluid. It was determined that in the case of this specific polymer, the barrel temperature, and to a lesser extent the cooling time during processing, affected the strain at break.

Experimental work was carried out on a small displacement Euro 5 automotive diesel engine alternatively fuelled with ultra low sulphur diesel (ULSD) and with two blends (30% vol.) of ULSD and of two different fatty acid methyl esters (FAME) obtained from both rapeseed methyl ester (RME) and jatropha methyl ester (JME) in order to evaluate the effects of different fuel compositions on particle number (PN) emissions. Particulate matter (PM) emissions for each fuel were characterized in terms of number and mass size distributions by means of two stage dilutions system coupled with a scanning mobility particle sizer (SMPS). Measurements were performed at three different sampling points along the exhaust system: at engine-out, downstream of the diesel oxidation catalyst (DOC) and downstream of the diesel particulate filter (DPF). Thus, it was possible to evaluate both the effects of combustion and after-treatment efficiencies on each of the tested fuels.

With a tighter regulatory environment, reduction of hydrocarbon (HC) and NOx emissions during cold-start has emerged as a major challenge for diesel engines. In the complex diesel aftertreatment system, more than 90% of engine-out NOx is removed in the underfloor SCR. However, the combination of low temperature exhaust and heat sink over DOC delays the SCR light-off during the cold start. In fact, the first 350 seconds during the cold light-duty FTP75 cycle contribute more than 50% of the total NOx tailpipe emission due to the low SCR temperature. For a fast SCR light-off, electrically heated catalyst (EHC) technology has been suggested to be an effective solution as a rapid warm-up strategy. In this work, the EHC, placed in front of DOC, utilizes both electrical power and hydrocarbon fuel. The smart energy management during the cold-start was crucial to optimize the EHC integrated aftertreatment system.

Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution hardware used for transportation of fuel from refineries. The impact of these inhibitors on spark ignited fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the additive concentrations to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a market place survey of corrosion inhibitors and how they vary in concentration in the final blended fuel; and, to show how the variation in the concentrations of the CIs impact the operation and performance of vehicles, specifically, the effects on intake valve deposit formation. Commercially available corrosion inhibitor packages for both gasoline and ethanol blended fuels, specifically E85 fuels, were studied for their chemical compositions, and their impact on valves for a port fuel injection (PFI) engine.

In the automotive industry, CAE methods are now widely used to predict several functional characteristics and to develop designs that are first-time-capable to meet programs targets. The N&V area is one of the increasing key factors for a product differentiation; costumers expect not only more powerful and more fuel efficient but also less noisy engines. The oil pan is one of the bigger contributors to engine radiated noise and to diesel knocking, so that great attention is paid within GM to optimize oil pans of Diesel engines by following a CAE-based approach to achieve a “first-time-capable” design for this component. This allows focusing the subsequent N&V testing activities to pinpoint modifications mainly on those components with shorter lead time. This paper describes the key-steps that are executed to optimize the oil pan design by using CAE methods with the main intent of reducing its noise radiation.

Corn ethanol has been used for fuel blending as both an oxygenate and octane booster and in most U.S. states conform to the ASTM D5798 fuel ethanol quality standard. Today the fuel ethanol market is expanding the types of feedstocks used to make ethanol and changing the processing techniques. These non-corn alternative feedstocks used to produce fuel ethanol bring new chemical components into the product that are not monitored under the D5798 standard, and it is unclear if they will result in material compatibility challenges for vehicle fuel systems that could affect performance and emissions. The vehicle contains a variety of plastic, metallic, and polymeric materials in the fuel tank, fuel pump, engine, and exhaust system that are sensitive to water, ions, acids, and high molecular weight compounds.

Diesel engines have the potential to significantly increase vehicle fuel economy and decrease CO₂ emissions; however, efficient removal of NOx and particulate matter from the engine exhaust is required to meet stringent emission standards. A conventional diesel aftertreatment system consists of a Diesel Oxidation Catalyst (DOC), a urea-based Selective Catalyst Reduction (SCR) catalyst and a diesel particulate filter (DPF), and is widely used to meet the most recent NOx (nitrogen oxides comprising NO and NO₂) and particulate matter (PM) emission standards for medium- and heavy-duty sport utility and truck vehicles. The increasingly stringent emission targets have recently pushed this system layout towards an increase in size of the components and consequently higher system cost. An emerging technology developed recently involves placing the SCR catalyst onto the conventional wall-flow filter.

The present paper describes an experimental investigation over the impact of diesel injector nozzle flow number on spray formation and combustion evolution for a modern EURO5 light-duty diesel engine. The analysis has been carried out by coupling the investigations in non evaporative spray bomb to tests in optical single cylinder engine in firing conditions. The research activity, which is the result of a collaborative project between Istituto Motori Napoli - CNR and GM Powertrain Europe, is devoted to understanding the basic operating behaviour of low flow number nozzles which are showing promising improvements in diesel engine behaviour at partial load. In fact, because of the compelling need to push further emission, efficiency, combustion noise and power density capabilities of the last-generation diesel engines, the combination of high injection pressure fuel pumps and low flow number nozzles is general trend among major OEMs.

In the last few years, the application of downsizing and turbocharging to internal combustion engines has considerably increased due to the proven potential of this technology to increase engine efficiency. Variable geometry turbines have been largely adopted to optimize the exhaust energy recovery over a large operating range. Two-stage turbocharger systems have also been studied as a solution to improve engine low-end torque and efficiency, with the first units currently available on the market. However, the compressor technology is today still based on fixed geometry machines, which are sized to efficiently operate at the maximum air flow and therefore lead to poor efficiency values at low air flow conditions. Furthermore, the surge limits prevents the full capabilities of VGT systems to increase the boosting at low engine speed.

The present paper describes the results of a research project aimed at studying the impact of nozzle flow number on a Euro5 automotive diesel engine, featuring Closed-Loop Combustion Control. In order to optimize the trade-offs between fuel economy, combustion noise, emissions and power density for the next generation diesel engines, general trend among OEMs is lowering nozzle flow number and, as a consequence, nozzle hole size. In this context, three nozzle configurations have been characterized on a 2.0L Euro5 Common Rail Diesel engine, coupling experimental activities performed on multi-cylinder and optical single cylinder engines to analysis on spray bomb and injector test rigs. More in detail, this paper deeply describes the investigation carried out on the multi-cylinder engine, specifically devoted to the combustion evolution and engine performance analysis, varying the injector flow number.

It is advantageous to increase the specific power output of diesel engines and to operate them at higher load for a greater portion of a driving cycle to achieve better thermal efficiency and thus reduce vehicle fuel consumption. Such operation is limited by excessive smoke formation at retarded injection timing and high rates of cylinder pressure rise at more advanced timing. Given this window of operation, it is desired to understand the influence of fuel properties such that optimum combustion performance and emissions can be retained over the range of fuels commonly available in the marketplace. Data are examined from a direct-injection single-cylinder research engine for eight common diesel fuels including soy-based biodiesel blends at two high load operating points with no exhaust gas recirculation (EGR) and at a moderate load with four levels of EGR.

Biofuel usage is increasingly expanding thanks to its significant contribution to a well-to-wheel (WTW) reduction of greenhouse gas (GHG) emissions. In addition, stringent emission standards make mandatory the use of Diesel Particulate Filter (DPF) for the particulate emissions control. The different physical properties and chemical composition of biofuels impact the overall engine behaviour. In particular, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value (LHV). More specifically, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value, respectively. The particle emissions, in fact, are lower mainly because of the higher oxygen content. Subsequently less frequent regenerations are required.

Diesel particle filters (DPF) have become the standard and essential aftertreatment components for all on-road diesel engines used in the US and Europe. The OBD requirements for DPF are becoming rigorously strict starting from 2015 model year. The pressure sensor or other strategies currently used for DPF diagnostics will most likely become insufficient to meet the new OBD requirements and a post DPF soot sensor might be necessary. This means that it will be even more imperative to develop a DPF design that would not have any soot leaks in its emission lifetime, otherwise the DPF will become a high warranty item.

Vehicle manufacturers have developed new vehicle and diesel engine technologies compatible with B6-B20 biodiesel blends meeting ASTM D7467, “Standard Specification for Diesel Fuel Oil, Biodiesel Blend (B6 to B20).” However, recent U.S. market place fuel surveys have shown that many retail biodiesel samples are out of specification. A vehicle designed to use biodiesel blends is likely to encounter occasional use of poor quality biodiesel fuel; and therefore understanding the effects of bad marketplace biodiesel fuels on engine and fuel system performance is critical to develop durable automotive technologies. The results presented herein are from vehicle evaluation studies with both on-specification and off-specification bio-based fuels. These studies focused on the performance of fuel injection equipment, engine, engine oil, emissions and emissions system durability.

The effects of using blended renewable diesel fuel (30% vol.), obtained from Rapeseed Methyl Ester (RME) and Hydrotreated Vegetable Oil (HVO), in a Euro 5 small displacement passenger car diesel engine have been evaluated in this paper. The hydraulic behavior of the common rail injection system was verified in terms of injected volume and injection rate with both RME and HVO blends fuelling in comparison with commercial diesel. Further, the spray obtained with RME B30 was analyzed and compared with diesel in terms of global shape and penetration, to investigate the potential differences in the air-fuel mixing process. Then, the impact of a biofuel blend usage on engine performance at full load was first analyzed, adopting the same reference calibration for all the tested fuels.