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This paper describes the development of a 0-D-sulfur poisoning model for a NOx storage catalyst (NSC). The model was developed and calibrated using findings and data obtained from a passenger car diesel engine used on testbed. Based on an empirical approach, the developed model is able to predict not only the lower sulfur adsorption with increasing temperature and therefore the higher SOx (SO2 and SO3) slip after NSC, but also the sulfur saturation with increasing sulfur loading, resulting in a decrease of the sulfur adsorption rate with ongoing sulfation. Furthermore, the 0-D sulfur poisoning model was integrated into an existing 1-D NOx storage catalyst kinetic model. The combination of the two models results in an “EAS Model” (exhaust aftertreatment system) able to predict the deterioration of NOx-storage in a NSC with increasing sulfation level, exhibiting higher NOx-emissions after the NSC once it is poisoned.

AM-SC1™ is a high temperature Mg alloy that was originally developed as a sand casting alloy for automotive powertrain applications. The alloy has been selected as the engine block material for both the AVL Genios LE and the USCAR lightweight magnesium engine projects. The present work assesses the potential of this alloy for permanent-mould die cast applications. Thermo-physical and mechanical properties of AM-SC1 were determined for material derived from a permanent-mould die casting process. The mechanical properties determined included: tensile, creep, bolt load retention/relaxation and both low and high cycle fatigue. To better assess the creep performance, a comparative analysis of the normalized creep properties was carried out using the Mukherjee-Dorn parameter, which confirmed the high viscoplastic performance of AM-SC1 compared with common creep resistant high pressure die cast (HPDC) Mg-alloys.

In large-scale industrial simulations the numerical prediction of fracture in sheet metal forming operations as well as in crash events is still a challenging task of high social and economic relevance. Among several approaches presented in literature, the authors and their colleagues developed a model which accounts each for three different mechanisms leading finally to fracture in thin sheet metals: the local instability (necking), ductile normal fracture and ductile shear fracture. The focus of this paper is to develop and validate a new approach to improve the predictive capabilities for fracture triggered by localized necking for a wide variety of steel grades. It is well known that after the onset of a local instability additional strain is still necessary to induce fracture. In a numerical simulation using shell elements this post instability strain becomes of increasing importance when the ratio of the characteristic shell element edge length to its thickness decreases.

The European Emissions Stage 5b standard for diesel passenger cars regulates particulate matter to 0.0045 g/km and non-volatile part/km greater than 23 nm size to 6.0x10₁₁ as determined by the PMP procedure that uses a heated evaporation tube to remove semi-volatile material. Measurement artifacts associated with the evaporation tube technique prevents reliable extension of the method to a lower size range. Catalytic stripper (CS) technology removes possible sources of these artifacts by effectively removing all hydrocarbons and sulfuric acid in the gas phase in order to avoid any chemical reactions or re-nucleation that may cause measurement complications. The performance of a miniature CS was evaluated and experimental results showed solid particle penetration was 50% at 10.5 nm. The sulfate storage capacity integrated into the CS enabled it to chemically remove sulfuric acid vapor rather than rely on dilution to prevent nucleation.

State of the art technologies of 2 and 4 stroke engines have to fulfill severe future exhaust emission regulations, with special focus on the aspects of rising performance and low cost manufacturing, leading to an important challenge for the future. In special fields of applications (e.g. mopeds, hand held or off-road equipment) mainly engines with simple mixture preparation systems, partially without exhaust gas after treatment are used. The comparison of 2 and 4 stroke concepts equipped with different exhaust gas after treatment systems provides a decision support for applications in a broad field of small capacity engine classes.

Efficiency and dynamic behavior of a vehicle are strongly affected by its weight. Taking into consideration comfort, safety and emissions in modern automobiles, lightweight design is more of a challenge than ever in automotive engineering. Materials development plays an important role against this background, since significant weight decrease is made possible through the substitution of high density materials and more precise adjustment of material parameters to the functional requirements of components. Reinforced light metals, therefore, offer a promising approach due to their high strength to weight ratio. The paper gives an overview on matrix and reinforcement structures suited for the high volume output of the automotive industry. Further analytical and numerical approaches to describe the strengthening effects and the good mechanical characteristics of these composite materials are presented.

The future exhaust emission legislation limits and the procedures for running the test cycles will have an important influence on future range extender concepts. Due to the special steady state operation strategy of the range extender engines, it is possible to create a simple methodology for comparing engine test bench emissions with the emission limits of exhaust gas legislations. Therefore the energy demand of a predefined vehicle was simulated with PHEM, a longitudinal dynamic simulation tool. According to that, the influence of different exhaust gas after treatment systems and preheating options on the tolerated raw emission concentration will be analyzed. With this information, a few chosen range extender engine concepts will be compared concerning their suitability for future exhaust emission legislations. The selection of the range extender concepts was carried out with the methotology of a value benefit analysis.

AJ alloy is used with a new Aluminum-Magnesium Composite Design, which is an innovative approach to lightweight crankcase technology. The component is manufactured using high pressure die cast process. A wide range of chemical compositions was used to develop a good understanding of the behavior of this alloy system (castability, thermophysical, mechanical, microstructure). The basic mechanical properties were determined from separately die cast samples and also from samples machined out from high pressure die cast components. Tensile, creep, bolt load retention/relaxation and high cycle fatigue properties were established and analyzed using multivariate analysis and statistical approach. This methodology was used to select the optimal chemical composition to match the requirements. The sensitivity of the alloy to heat exposure was investigated for both mechanical properties and microstructure.

The validity of numerical simulations is still limited by the unknown failure of materials when nonlinear load paths in successive stamping and crash processes occur. Localized necking is the main mechanism for fractures in ductile sheet metal. The classical forming limit curve (FLC) is limited to linear strain paths. To include the effects of nonlinear strain paths a theoretical model for instability (algorithm CRACH) has been used. The algorithm has been developed on the basis of the Marciniak model [8]. The calibration and validation of this approach is done by a set of multistage experiments under static and dynamic strain rates for a mild steel.

Future catalyst systems need to be highly efficient in a limited packaging space. This normally leads to a design where the flow distribution, in front of the catalyst, is not perfectly uniform. Measurements on the flow test bench show that the implementation of perforated foils for the corrugated and flat foils has the capability to distribute the flow within the channels in the radial direction so that the maximum of the given catalyst surface is of use, even under very poor uniformity indices. Therefore a remarkable reduction in back pressure is measured. Emission results demonstrate cold start improvement due to reduced heat capacity. The use of LS - structured ( Longitudinal structured ) corrugated foils creates a high turbulence level within the single channels. The substrate lights-up earlier and the maximum conversion efficiency is reached more quickly.

In the near future the effort on the development of exhaust gas treatment systems must be increased to meet the stringent emission requirements. If the relevant physical and chemical models are available, the numerical simulation is an important tool for the design of these systems. This work presents a CFD model that allows to cover the full range of applications in this area. After a detailed presentation of the theoretical background and the modeling strategies results for the simulation of a close-coupled catalyst are shown. The presented model is also applied to the oxidation of nitrogen oxides, to a diesel particle filter and a fuel-cell reformer catalyst.

An increasing environmental consciousness as well as the awareness for sustained preservation of natural resources causes new regulations for emissions and great efforts for fuel economy and increasing oil service intervals. For a better understanding of the process generating pollutants, the emissions of every phase of the combustion cycle have to be monitored online. Moreover, it is important to measure the raw exhaust gas during different driving cycles and investigate the influence of different parameters as for example changing engine operating conditions. The new mass spectrometer (MS) based measurement system allows the direct detection of unburned gaseous oil HC without tracers. The gas inlet system enables crank angle resolved monitoring of different raw exhaust gas compounds in the exhaust manifold or directly in the cylinder.

Commonly, the spray process in Direct Injection (DI) diesel engines is modeled with the Euler Lagrangian discrete droplet approach which has limited validity in the dense spray region, close to the injector nozzle hole exit. In the presented research, a new reactive spray modelling method has been developed and used within the 3D RANS CFD framework. The spray process was modelled with the Euler Eulerian multiphase approach, extended to the size-of-classes approach which ensures reliable interphase momentum transfer description. In this approach, both the gas and the discrete phase are considered as continuum, and divided into classes according to the ascending droplet diameter. The combustion process was modelled by taking into account chemical kinetics and by solving general gas phase reaction equations.

Wall flow particulate filters have been used as a standard exhaust aftertreatment device for many years. The interaction of particulate matter (PM) regeneration and catalytically supported reactions strongly depends on the given operating conditions. Temperature, species concentration and mass flow cause a change from advective to diffusive-controlled flow conditions and influence the rate controlling dominance of individual reactions. A transient 1D+1D model is presented considering advective and diffusive transport phenomena. The reaction scheme focuses on passive PM conversion and catalytic oxidation of NO. The model is validated with analytical references. The impact of back-diffusion is explored simulating pure advective and combined advective diffusive species transport. Rate approaches from literature are applied to investigate PM conversion at various operating conditions.

Especially in horizontal applications of thermoplastic body-panels occurs a conflict between the required thermal stability (generally achieved with short glass fibers) and the high level surface finish as the reinforcements worsen the surface texture. The sandwich-molding procedure for bigger body-panels, developed further at BMW, offers an innovative solution to this problem. Two materials, one with good surface finish properties (material A) and another with glass fiber reinforcement (material B), are coinjected in a single process step. The result is a part with class-A surface (only material A visible at the surface), advanced mechanical and thermal properties. Additionally to an outstanding surface finish the body-panel exhibits small thermal expansion relevant for reduction of gaps to bordering parts.

In addition to the creep properties, the fatigue properties are essential for the design of a power-train component in Mg which is operated at elevated temperatures. In case of the new BMW I6 composite Mg/Al crankcase using the AJ alloy system, material testing focused on both subjects. The basic mechanical properties were determined from separately die cast samples and also from samples machined out from high-pressure die cast components. Tensile, high cycle fatigue properties, low cycle fatigue and crack propagation properties were established and analyzed within the technical context for power-train applications reflected in the temperature and load levels. The aspects of mean stress influence, notch sensitivity and crack propagation are evaluated to estimate the performances of the AJ62A alloy system.

The application of crash durable structural adhesives in modern cars design, to improve the driving durability, the overall vehicle stiffness, the crash resistance and to make real light weight constructions feasible is significantly gaining in importance. 1-component systems are already introduced in the market and used in automotive industries. Usually the use of these bonds in automotive industries is limited by a relatively low wash off resistance in the pre-treatment tanks of the paint shop. If no additional actions are taken, there is a severe risk of wash off of the adhesives up to the partial loss in functionality. Respectively contamination of the pre-treatment tanks and aftereffects damage the surface of the coated cars. To avoid wash off a thermal process (oven) to pre-gel the adhesive in the flanges of the Body-In-White (BIW)- bodies before entering the pre-treatment utility is necessary. This is a save but cost intensive solution.

The importance of the automotive interior as a characteristic feature in the competition for the goodwill of the customer has increased significantly in recent years. Whilst there are established, more or less efficient CAE processes for the solution of problems in the areas of occupant safety and service strength, until now the implementation of CAE in themes such as dimensional stability, warpage and corrugation1 of plastic parts has been little investigated. The developmental support in this field is predominantly carried out by means of hardware tests. Real plastic components alter their form as a result of internal forces often during the first weeks following production. The process, known as “creep”, can continue over an extended period of time and is exacerbated by high ambient temperatures and additional external loads stemming from installation and post assembly position.

Automotive clear coats have a broad field of requirements to fulfill, e.g. weathering stability, stone chipping, chemical resistance, scratch resistance, and have to show a brilliant surface appearance. Beside this, the paint and repair process for high volume car manufacturing must be fulfilled with respect to costs and the environment. From the development point of view of a car manufacture interactions between these properties and the critical way of understanding and describing the value for the customer is shown. The conclusion of this scenario and a detailed benchmark study of different new clear coats guide to the development of the ‘Next generation’ of powder clear coats.

A specific objective of the European Mg-Engine project is to qualify at least two die cast Mg alloys with improved high temperature properties, in addition to satisfactory corrosion resistance, castability and costs. This paper discusses the selection criteria for high temperature alloys leading to four candidate alloys, AJ52A, AJ62A, AE44 and AE35. Tensile-, creep- and fatigue testing of standard die cast test specimens at different temperatures and conditions have led to a very large amount of material property data. Numerous examples are given to underline the potential for these alloys in high temperature automotive applications. The subsequent use of the basic property data in material models for design of automotive components is illustrated.