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Journal Article

Sulfur Poisoning of a NOx Storage Catalyst - A Comprehensive Modelling Approach

2016-04-05
2016-01-0964
This paper describes the development of a 0-D-sulfur poisoning model for a NOx storage catalyst (NSC). The model was developed and calibrated using findings and data obtained from a passenger car diesel engine used on testbed. Based on an empirical approach, the developed model is able to predict not only the lower sulfur adsorption with increasing temperature and therefore the higher SOx (SO2 and SO3) slip after NSC, but also the sulfur saturation with increasing sulfur loading, resulting in a decrease of the sulfur adsorption rate with ongoing sulfation. Furthermore, the 0-D sulfur poisoning model was integrated into an existing 1-D NOx storage catalyst kinetic model. The combination of the two models results in an “EAS Model” (exhaust aftertreatment system) able to predict the deterioration of NOx-storage in a NSC with increasing sulfation level, exhibiting higher NOx-emissions after the NSC once it is poisoned.
Journal Article

Evaluation of Valve Train Variability in Diesel Engines

2015-09-06
2015-24-2532
The continuously decreasing emission limits lead to a growing importance of exhaust aftertreatment in Diesel engines. Hence, methods for achieving a rapid catalyst light-off after engine cold start and for maintaining the catalyst temperature during low load operation will become more and more necessary. The present work evaluates several valve timing strategies concerning their ability for doing so. For this purpose, simulations as well as experimental investigations were conducted. A special focus of simulation was on pointing out the relevance of exhaust temperature, mass flow and enthalpy for these thermomanagement tasks. An increase of exhaust temperature is beneficial for both catalyst heat-up and maintaining catalyst temperature. In case of the exhaust mass flow, high values are advantageous only in case of a catalyst heat-up process, while maintaining catalyst temperature is supported by a low mass flow.
Technical Paper

Strategies for Emission Reduction on Small Capacity Two-Wheelers with Regard to Future Legislative Limits

2014-11-11
2014-32-0031
Looking at upcoming emission legislations for two-wheelers, it is quite obvious that the fulfilment of these targets will become one of the biggest challenges within the engine development process. The gradual harmonization of emission limits for two-wheelers with existing automotive standards will subsequently lead to new approaches regarding mixture preparation and exhaust gas aftertreatment. Referring to these future scenarios, a state-of-the-art in development of catalytic converters for two- or three-wheeler applications should be presented. After choosing a suitable test carrier, which has already been equipped with EFI components including an oxygen sensor for λ=1 operation mode, a basic injection system calibration was used to optimize the combustion process. Based on this setup, a variable exhaust system was manufactured to be able to integrate different catalyst configurations.
Technical Paper

Impact of 3-way catalytic converters on particulate emission of MPFI motorcycle engines

2022-01-09
2022-32-0004
Due to climatic movements and politics, there is no doubt that a stricter emission legislation will soon face the two-wheeler sector and their manufacturers with new challenges. Additional to the already limited pollutants, a limitation of particulate number will probably also be introduced, which means that there is an urgent need for action in exhaust gas after treatment and particulate reduction systems. For natural aspirated, port injected engines, as used in two-wheeler-technologies, conventional systems already established in passenger cars are not necessarily applicable. Moreover, the emission spectrum is fundamentally different from passenger car engines due to the better homogenization of they typically used MPFI engine types. Adapting conventional particulate filter technologies to the finer particles of MPFI engines would result in a disproportionately larger exhaust backpressure.
Technical Paper

Improvement of the EGR Dilution Tolerance in Gasoline Engines by the Use of a HSASI Pre-Chamber Spark Plug

2023-10-24
2023-01-1805
Charge dilution in gasoline engines reduces NOx emissions and wall heat losses by the lower combustion temperature. Furthermore, under part load conditions de-throttling allows the reduction of pumping losses and thus higher engine efficiency. In contrast to lean burn, charge dilution by exhaust gas recirculation (EGR) under stoichiometric combustion conditions enables the use of an effective three-way catalyst. A pre-chamber spark plug with hot surface-assisted spark ignition (HSASI) was developed at the UAS Karlsruhe to overcome the drawbacks of charge dilution, especially under part load or cold start conditions, such as inhibited ignition and slow flame speed, and to even enable a further increase of the dilution rate. The influence of the HSASI pre-chamber spark plug on the heat release under EGR dilution and stoichiometric conditions was investigated on a single-cylinder gasoline engine.
Technical Paper

A Demonstration of Emissions' Behaviour of Various Handheld Engines Including Investigations on Particulate Matter

2013-10-15
2013-32-9130
To get an overview of the emission situation in the field of small non-road mobile machinery powered by various types of SI engines, the Association for Emissions Control by Catalyst (AECC), together with the Institute for Internal Combustion Engines and Thermodynamics (IVT) of Graz University of Technology, conducted a customized test program. The main goal for this campaign was to derive information regarding the emissions of regulated gaseous components (following European Directive 97/68/EC) as well as particulate matter. With regard to the big variety of different engines that are available on the European and North-American market, the most representative ones had to be chosen. This resulted in a pool of test devices to cover different engine working principles (2-Stroke and 4-Stroke), technological standards (low-cost and professional tools) and different emissions control strategies (advanced combustion and exhaust gas aftertreatment).
Technical Paper

Impacts of eFuels on Solid and Gaseous Emissions of Powersport Two-Wheelers

2023-10-24
2023-01-1838
As alternative to electrification or carbon free fuels such as hydrogen, CO2-neutral fuels have been researched aiming to decrease the impact of fossil energy sources on the environment. Despite the potential benefit of capturing CO2 emission after combustion for own fuel production, the so-called eFuels also benefit by using a green source of energy during their fabrication. Among all the possibilities for eFuels, alcohols, ethers (such as MTBE and ETBE) and alternative hydrocarbons have shown positive impacts regarding emission reduction and performance when compared to standard gasoline. Previously in [1] and [2], synthetic fuels and methanol blends were tested at steady state conditions in order to verify advantages and drawbacks relative to gasoline, for power-sport motorcycles.
Technical Paper

Exhaust Aftertreatment Technologies for PN Reduction of Motorcycles

2023-10-24
2023-01-1846
The objective of this experimental investigation was to analyze the effect of various exhaust gas aftertreatment technologies on particulate number emissions (PN) of an MPFI EU5 motorcycle. Specifically, three different aftertreatment strategies were compared, including a three-way-catalyst (TWC) with LS structure as the baseline, a hybrid catalyst with a wire mesh filter, and an optimized gasoline particulate filter (GPF) with three-way catalytic coating. Experimental investigations using the standard test cycle WMTC performed on a two-wheeler chassis dynamometer, while the inhouse particulate sampling system was utilized to gather information about size-dependent filtering efficiency, storage, and combustion of nanoparticles. The particulate sampling and measuring system consist of three condensation particle counters (CPCs) calibrated to three different size classes (SPN4, SPN10, SPN23).
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