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In this research, a new wire material made using surface-reforming heat treatment was developed in order to enhance the corrosion fatigue resistance of suspension springs. The aim of surface reforming is to improve hydrogen embrittlement characteristics through grain refinement and to improve crack propagation resistance by partial softening of hardness. The grain refinement method used an α'→γ reversed transformation by rapid short-term heating in repeated induction heating and quenching (R-IHQ) to refine the crystal grain size of SAE 9254 steel spring wire to 4 μm or less. In order to simultaneously improve the fatigue crack propagation characteristics, the possibility of reducing the hardness immediately below the spring surface layer was also examined. By applying contour hardening in the second IHQ cycle, a heat affected zone (HAZ) is obtained immediately below the surface.

Recent trends to downsize engines have resulted in lighter weight and greater compactness. At the same time, however, power density has increased due to the addition of turbocharger and other such means to supplement engine power and torque, and this has increased the thermal and mechanical load. In this kind of environment, corrosion of the copper alloy bushing (piston pin bushing) that is press-fitted in the small end of the connecting rod becomes an issue. The material used in automobile bearings, of which the bushing is a typical example, is known to undergo sulfidation corrosion through reaction with an extreme-pressure additive Zinc Dialkyldithiophosphate (ZnDTP) in the lubricating oil. However, that reaction path has not been clarified. The purpose of the present research, therefore, is to clarify the reaction path of ZnDTP and copper in an actual engine environment.

Over the past 60 years, chemical companies have been supplying automotive manufacturers state-of-the-art zinc phosphate conversion coatings which, when applied properly to a metal surface promote excellent paint adhesion and corrosion resistance. Phosphate conversion coatings have undergone many transformations over the years. Now some of their essential components and byproducts are being more tightly regulated under new environmental guidelines. The metal pretreatment industry is now challenged with the task to replace the traditional zinc phosphate coating with the next generation product. This paper will examine the advantages of a new generation conversion coating based on zirconium oxide. The performance and process cost savings will be discussed. This technology has been advancing over the past several years, and in 2007 several successful commercial line trials with this new conversion coating were conducted.

Autodeposition coatings are thin, highly corrosion resistant organic coatings that are deposited in a chemical reaction with a metal surface. Because the autodeposition process deposits a coating only on metallic surfaces, coating of just the metal portion of metal-plastic or metal-rubber assemblies is possible. The overall autodeposition process includes stages of clean, water rinse, coat, reaction rinse, and cure. The use of a reaction rinse after the autodeposition stage is unique among coating processes and allows new properties to be introduced to the coating before curing. This paper will briefly review the general chemistry of autodeposition, and then focus on how corrosion performance and physical characteristics of a recently developed epoxy-acrylic autodeposition coating are designed into the product and how the autodeposition process controls these properties. The role of the organic polymer and the reaction rinse in all the properties will be discussed.

Autodeposition coatings are thin, highly corrosion resistant organic coatings that deposit paint by reaction with the metal surface. The coating deposits only on metallic surfaces, thus allowing coating of just the metal portion of metal-plastic or metal-rubber assemblies. Because it is a chemical reaction with the metal surface, it is possible to evenly paint the inside of tubular and boxed sections, which is where corrosion typically starts. The overall autodeposition process includes cleaning, water rinse, coat, reaction rinse, and cure. The use of a reaction rinse after the autodeposition coating application allows unique properties to be introduced to the coating before curing. This presentation will briefly review the general chemistry of autodeposition. Next it will focus on commercial automotive applications of several newly developed autodeposition coatings. The corrosion performance and physical characteristics of both black and gray epoxy-acrylic coatings will be presented.

Conventionally, the Ni-based superalloys NCF3015 (30Ni-15Cr) and the high nickel content NCF440 (70Ni-19Cr) (with its outstanding wear resistance and corrosion resistance), have been used as engine exhaust valve materials. In recent years, automobile exhaust gases have become hotter because of exhaust gas regulations and enhanced fuel consumption efficiency. Resource conservation and cost reductions also factor into global environmental challenges. To meet these requirements, NCF5015 (50Ni-15Cr), a new resource-conserving, low-cost Ni-based heat-resistant alloy with similar high-temperature strength and wear resistance as NCF440, has been developed. NCF5015's ability to simultaneously provide wear resistance, corrosion resistance and strength when NCF5015 is used with diesel engines was verified and the material was then used in exhaust valves.

The environmental performance of automobiles and automobile engines in particular is the foremost issue in the automotive industry today. In addition, engine durability performance is an essential aspect of engine oil performance. Four-cycle motorcycle engine oils formulated with dialkyl phosphate, a sulfur-free additive developed as an alternative to ZDDP, provide excellent environmental and durability performance in terms of longer drain intervals, cleanliness and low corrosion properties.

The International Lubricant Standardization and Approval Committee (ILSAC) ATF subcommittee members have compared the two oxidation bench test methods, Aluminum Beaker Oxidation Test (ABOT) and Indiana Stirring Oxidation Stability Test (ISOT), using a number of factory-fill and service-fill ATFs obtained in Japan and in the US. In many cases, the ATFs were more severely oxidized after the ABOT procedure than after the same duration of the ISOT procedure. The relative severity of these two tests was influenced by the composition of the ATFs. The bench test oxidation data were compared with the transmission and the vehicle oxidation test data.

A new type of lean NOx catalyst has been developed with improved thermal resistance. This lean NOx catalyst contains precious metals and NO2 adsorbents. The precious metals are used mainly for the oxidation reaction of NO, and the NO2 adsorbents are for the adsorption removal of generated NO2. The thermal resistance of the catalyst was raised by paying attention to the following points. 1) Improvement of thermal resistance for the NO oxidation activity by addition of a different precious metal element. 2) Prevention of thermal degradation of the NO2 adsorbent by addition of a new metal oxide. For item 1, Pd was added to the catalyst which had already included Pt. By having Pd coexist with Pt, the precious metal dispersion was kept high even after heat treatment, so the NO oxidizing ability was improved. For item 2, thermal degradation of NO2 adsorbent was prevented by addition of the new metal oxide (B) to the adsorbent.

The PVC(poly-vinyl chloride) underbody coating was specifically designed for the automotive underfloor area in order to prevent chipping damage as well as the onset of rust propagation from a scratched point. This superior anti-chipping performance can also be achieved without increasing film thickness of the PVC by balancing film strength and adhesion strength. Also, by incorporating plastic balloons in the PVC formulation, a dried film specific gravity of less than 1.0 is achieved, and consequently a 2 kg weight reduction becomes possible when compared to conventional materials used for underbody coating.

For the purpose of developing onboard gasoline reforming technology for higher octane number fuel on demand, octane number enhancement of gasoline surrogate by aerobic oxidation using N-hydroxyphthalimide catalyst was investigated. At first, octane numbers of the oxygen-containing products from alkane and aromatic compound were estimated using a fuel ignition analyzer. As a result, not only alcohol but also ketones and aldehydes have higher octane numbers than the original alkanes and aromatic compound. Next, gasoline surrogate was oxidized aerobically with N-hydroxyphthalimide derivative catalyst and cobalt catalyst at conditions below 100 °C. As a result, fuel molecules were oxidized to produce alcohols, ketones, aldehydes, and carboxylic acids. N-hydroxyphthalimide derivative catalyst with higher solubility in gasoline surrogate has higher oxidation ability. Furthermore, the estimated octane number of the oxidized gasoline surrogate improves 17 RON.

Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO₃ (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn⁴+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/γ-Al₂O₃ (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO₂).

High viscosity index(HVI) petroleum base stock, with excellent temperature-viscosity characteristics, oxidation resistance, and low-evaporation properties, offers advantages as the base stock for high fuel economy engine oils, particularly because of its low-friction properties in the boundary and/or “E.H.L (Elastohydrodynamic Lubrication)” area due to its rheological characteristics. This research evaluated HVI base stock's low-friction properties. Upgrading the oil from 5W-30 to 5W-20 was also investigated. The friction properties of the HVI base stock were measured by a unit friction platform. The results show a 28% reduction in friction coefficient compared with the conventional, solvent refined oil, which is attributable to the high-pressure viscosity of the base oil.

Gas shielded metal arc welding is generally applied to automobile chassis parts. However, the weld parts with the E-coat show poor corrosion resistance. Therefore, the corrosion mechanism of the weld parts was investigated. The results found two reasons why the weld parts corroded faster than the non weld parts:(1)inadequate phosphating (2)defects in the E-coat. After detailed investigation, it was clarified that the major cause of poor corrosion resistance was the defects in the E-coat caused by slags formed on the surface of the weld bead. Therefore the amount of slag has to be decreased to improve the corrosion resistance. The effect of shielding gas composition on the amount of slag was then investigated. In the case of Ar and oxidizing gas mixture, the corrosion resistance improved as the oxidizing gas content decreased. This was due to the reduction of slags.

The use of low-density materials in body panels is increasing as a measure to reduce the weight of the vehicle body. Honda has developed an aluminum/steel sheet hybrid door that is more effective in reducing weight than an all-aluminum door. Because aluminum was used in the door skin, bimetallic corrosion at the connection between the aluminum and the steel sheets represented an issue. It was possible that the difference in the electrical potential of the two metals might promote corrosion at the connection between the aluminum door skin and the steel sheet door panel, in particular at the lower edge of the door, where rainwater and other moisture tend to accumulate, with the result that the appeal of the exterior of the door might decline.

Amidst of the recent concerns on depletion of natural resources, a new heat resistant titanium alloy has been developed using the minimum amount of rare metals. Using Ti-811 as a basis and modifying the alloy composition to Ti-7Al-2Mo-0.2Si-0.15C-0.2Nb, the mechanical property, the creep resistance and the oxidation resistance at high temperatures are improved. At the same time, with the β transformation point shifted to a higher temperature, the hot formability is also improved. The newly developed alloy has made it possible to expand the application of titanium material to exhaust valves in reciprocating engines.