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Pre-chamber ignition is one of the advanced technologies to improve the combustion performance for lean combustion natural gas engine, which could achieve low NOx, simultaneously. The designing scheme of the orifices, which connects the pre-chamber and the main chamber, is the main challenge limiting the further improvement. In this work, the three-dimensional computational fluid dynamics calculation based on a four-stroke engine with 320 mm cylinder bore was conducted to investigate the effects of orifice structure on the combustion and NOx performance. The results show that the schemes with 7 and 9 orifices lead to the delayed high-temperature jets formation due to the asymmetrical airflow in the pre-chamber, which retards the ignition timing but enhances the combustion in the main chamber. The 6 orifices scheme leads to the insufficient distribution of the high-temperature jets, and the 10 orifices result in the serious interference between the adjacent high-temperature jets.