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With the development of advanced ABE fermentation technology, the volumetric percentage of acetone, butanol and ethanol in the bio-solvents can be precisely controlled. To seek for an optimized volumetric ratio for ABE-diesel blends, the previous work in our team has experimentally investigated and analyzed the combustion features of ABE-diesel blends with different volumetric ratio (A: B: E: 6:3:1; 3:6:1; 0:10:0, vol. %) in a constant volume chamber. It was found that an increased amount of acetone would lead to a significant advancement of combustion phasing whereas butanol would compensate the advancing effect. Both spray dynamic and chemistry reaction dynamic are of great importance in explaining the unique combustion characteristic of ABE-diesel blend. In this study, a semi-detailed chemical mechanism is constructed and used to model ABE-diesel spray combustion in a constant volume chamber.

Acetone-Butanol-Ethanol (ABE) is an intermediate product in the ABE fermentation process for producing bio-butanol. As an additive for diesel, it has been shown to improve spray evaporation, improve fuel atomization, enhance air-fuel mixing, and enhance combustion as a whole. The typical compositions of ABE are in a volumetric ratio of 3:6:1 or 6:3:1. From previous studies done in a constant volume chamber, it was observed that the presence of additional acetone in the blend caused advancement in the combustion phasing, but too much acetone content led to an increase in soot emission during combustion. The objective of this research was to investigate the combustion of these mixtures in a diesel engine. The experiments were conducted in an AVL 5402 single-cylinder diesel engine at different speeds and different loads to study component effects on the various engine conditions. The fuels tested in these experiments were D100, ABE(3:6:1)10, ABE(3:6:1)20, ABE(6:3:1)10, and ABE(6:3:1)20.

The performance and emission of an AVL 5402 single-cylinder engine fueled with acetone-butanol-ethanol (ABE) / diesel blends were experimentally investigated at various load conditions and injection timings. The fuels tested in the experiments were ABE10 (10% ABE, 90% diesel), ABE20 and diesel as baseline. Thermodynamics analyses of pressure traces acquired in experiments were performed to show the impact of ABE concentration to the overall combustion characteristics of the fuel mixtures. Cumulative heat release analysis showed that ABE mixtures generally retarded the overall combustion phasing, ignition delays of ABE-containing fuels were significantly extended, however, combustion rate during CA10∼CA50 were accelerated at different extent. Pressure rise rate of ABE-containing fuels further implicated that the premixed combustion were more dominant than that of diesel. Polytropic indices of both expansion and compression strokes were calculated from p-V diagram.