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Journal Article

Sulfur Poisoning of a NOx Storage Catalyst - A Comprehensive Modelling Approach

2016-04-05
2016-01-0964
This paper describes the development of a 0-D-sulfur poisoning model for a NOx storage catalyst (NSC). The model was developed and calibrated using findings and data obtained from a passenger car diesel engine used on testbed. Based on an empirical approach, the developed model is able to predict not only the lower sulfur adsorption with increasing temperature and therefore the higher SOx (SO2 and SO3) slip after NSC, but also the sulfur saturation with increasing sulfur loading, resulting in a decrease of the sulfur adsorption rate with ongoing sulfation. Furthermore, the 0-D sulfur poisoning model was integrated into an existing 1-D NOx storage catalyst kinetic model. The combination of the two models results in an “EAS Model” (exhaust aftertreatment system) able to predict the deterioration of NOx-storage in a NSC with increasing sulfation level, exhibiting higher NOx-emissions after the NSC once it is poisoned.
Journal Article

The Effect of Backing Profile on Cutting Blade Wear during High-Volume Production of Carbon Fiber-Reinforced Composites

2018-04-03
2018-01-0158
Carbon fiber sheet molding compound (SMC) is an attractive material for automotive lightweighting applications, but several issues present themselves when adapting a process developed for glass fiber composites to instead use carbon fibers. SMC is a discontinuous fiber material, so individual carbon fiber tows must be chopped into uniform rovings before being compounded with the resin matrix. Rotary chopping is one such method for producing rovings, but high wear rates are seen when cutting carbon fibers. Experiments were performed to investigate the wear progression of cutting blades during rotary carbon fiber chopping. A small rotary chopper with a polyurethane (PU) backing and thin, hardened steel blades was used to perform extended wear tests (120,000 chops, or until failure to reliably chop tows) to simulate the lifespan of blades during composite material production.
Technical Paper

Wear Performances of Gray Cast Iron Brake Rotor with Plasma Electrolytic Aluminating Coating against Different Pads

2020-10-05
2020-01-1623
Gray cast iron brake rotor experiences substantial wear during braking and contributes largely to the wear debris emissions. Surface coating on the gray cast iron rotor represents a trending approach dealing with the problems. In this research, a new plasma electrolytic aluminating (PEA) process was used for preparing an alumina-based ceramic coating with metallurgical bonding to the gray cast iron. Three different types of brake pads (ceramic, semi-metallic and non asbestos organic (NAO)) were used for tribotests. Performances of PEA coatings vs. different brake pad materials were comparatively investigated with respect to their coefficients of friction (COFs) and wear. The PEA-coated brake rotor has a dimple-like surface which promotes the formation of a thin transferred film to protect the rotor from wear. The transferred film materials come from the wear debris of the pads. The secondary plateaus are regenerated on the brake pads through compacting wear debris of the pads.
Technical Paper

Wear and Galvanic Corrosion Protection of Mg alloy via Plasma Electrolytic Oxidation Process for Mg Engine Application

2009-04-20
2009-01-0790
Sliding wear of magnesium (Mg) engine cylinder bore surfaces and corrosion of Mg engine coolant channels are the two unsolved critical issues that automakers have to deal with in development of magnesium-intensive engines. In this paper, Plasma Electrolytic Oxidation (PEO) process was used to produce oxide coatings on AJ62 Mg alloy to provide wear and corrosion protection. In order to optimize the PEO process, orthogonal experiments were conducted to investigate the effect of PEO process parameters on the wear properties of PEO coatings. The PEO coatings showed a much better wear resistance, as well as a smaller friction coefficient, than the AJ62 substrate. The galvanic corrosion property of AJ62 Mg coupled with stainless steel and aluminum (Al) was investigated via immersion corrosion test in an engine coolant. Applying PEO coating on Mg can effectively prevent the galvanic corrosion attack to Mg.
Technical Paper

Load and Lubricating Oil Effects on Friction of a PEO Coating at Different Sliding Velocities

2017-03-28
2017-01-0464
Friction between the piston and cylinder accounts for large amount of the friction losses in an internal combustion (IC) engine. Therefore, any effort to minimize such a friction will also result in higher efficiency, lower fuel consumption and reduced emissions. Plasma electrolytic oxidation (PEO) coating is considered as a hard ceramic coating which can provide a dimpled surface for oil retention to bear the wear and reduce the friction from sliding piston rings. In this work, a high speed pin-on-disc tribometer was used to generate the boundary, mixed and hydrodynamic lubrication regimes. Five different lubricating oils and two different loads were applied to do the tribotests and the COFs of a PEO coating were studied. The results show that the PEO coating indeed had a lower COF in a lower viscosity lubricating oil, and a smaller load was beneficial to form the mixed and hydrodynamic lubricating regimes earlier.
Technical Paper

Multimethod Concept for Continuous Wear-Analysis of the Piston Group

2018-04-03
2018-01-0839
Friction losses as well as lube oil consumption at the piston group are key factors for future engine downsizing concepts regarding to emissions and consumption. This means an early identification of friction losses and wear is essential within development. The main problem is that the wear assessment is based on long durability tests which are typically performed in a later phase. This may lead to the fact that an early optimized configuration with respect to friction can cause a potential wear problem later in the durability test program. Still ongoing trends in combustion engine engineering lead to both the minimized oil supply in the tribocontact piston bore interface and improved wear resistance. One is forced to the conclusion that understanding and quantifying wear will be a key driver for the future engine development process. The aim is a holistic concept that combines different methods to investigate wear and furthermore its combination with friction loss studies.
Technical Paper

Effect of Surface Roughness and Sliding Velocity on Tribological Properties of an Oxide-Coated Aluminum Alloy

2014-04-01
2014-01-0957
Aluminum engines have been successfully used to replace heavy gray cast engines to lighten the car's weight and reduce the fuel consumption. To overcome the aluminum alloys' poor wear resistance, cast iron liners and thermal spraying coatings were used as cylinder bore materials for wear protection. A plasma electrolytic oxidation (PEO) technique had also been proposed to produce an oxide coating on aluminum cylinder bore. The oxide coating can have a low coefficient of friction (COF) and minimum wear shown in the lab tests. To conserve more fuel, the stopping and restarting system was introduced when the vehicle was forced to stop immediately for a short time. When the engine was forced to stop and restart, the reciprocating speed of the piston was very slow, and the friction between the piston and the cylinder was high. In this research, a pin-on-disc tribometer was used to investigate tribological behavior of the oxide coating on an aluminum alloy.
Technical Paper

High Mileage Emission Deterioration Factors from Euro 6 Positive and Compression Ignition Vehicles

2022-08-30
2022-01-1028
The current European fleet of vehicles is ageing and lifetime mileages are rising proportionally. Consequently, a substantial fraction of the vehicle fleet is currently operating at mileages well beyond current durability legislation (≤ 160,000 km). Emissions inventories and models show substantial increases in emissions with increasing mileage, but knowledge of the effect of emissions control system deterioration at very high mileages is sparse. Emissions testing has been conducted on matched pairs (or more) of diesel and gasoline (and CNG) vehicles, of low and high mileage, supplementing the results with in-house data, in order to explore high mileage emission deterioration factors (DF). The study isolated, as far as possible, the effect of emissions deterioration with mileage, by using nominally identical vehicle models and controlling other variables.
Technical Paper

Characterizing a Real-Driving Brake Emissions Sampling System on a Laboratory Test Bed

2023-11-05
2023-01-1875
Brake wear emissions gained significant relevance with the upcoming Euro7 type approval within the European Union for brake emission measurement on the test bed. While the controlled brake test bed approach provides consistent results, real-driving emission (RDE) measurements are needed to better understand actual emission behavior due to varying vehicle and environmental conditions. The EU has already announced its interest in RDE testing. Here we present the results of an RDE brake wear sampling system with minimal thermal impact, where particles are only sampled from one side of the brake disc, characterized on a laboratory sampling system. The investigations aim to validate symmetric particle release and to confirm that doubling the measured RDE results effectively represents the reference emissions on the test bed.
Technical Paper

Measuring Brake Wear Particles with a Real-Driving Emissions Sampling System on a Brake Dynamometer

2022-09-19
2022-01-1180
Brake wear particles are recognized as one of the dominant sources of road transport particulate matter emissions and are linked to adverse health effects and environmental impact. The UNECE mandated the Particle Measurement Program to address this issue, by developing a harmonized sampling and measurement methodology for the investigation of brake wear particles on a brake dynamometer (dyno). However, although the brake dyno approach with tightly controlled test conditions offers good reproducibility, a multitude of changing vehicle and surrounding conditions make real-driving emissions measurement a highly relevant task. Here we show two different prototypes for on-road particle measurement with minimal impact of the measurement setup on the emission behavior, tested on a brake dyno.
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