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Homogeneous charge compression ignition (HCCI) is a part load, low-temperature combustion process which operates at lean mixtures and produces ultra-low NOX emissions. As opposed to SI engines that use a spark to control combustion timing, HCCI combustion is enabled by compression induced autoignition which is characterized by rapid global and spatial combustion yielding fuel efficiency benefits. This process is highly dependent on the in-cylinder state, including pressure, temperature and trapped mass. The absence of a direct combustion control proves to be a major challenge and results in unstable engine operation especially at the limits of the narrow operation range. In recent studies, direct water injection is used in HCCI combustion to stabilize combustion and increase the operation range. This paper outlines the thermodynamic influence and evaluation of the potential of water injection for HCCI combustion.