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After several decades of human spaceflight, the community of space-faring nations has accumulated a diverse and sometimes harrowing history of toxicological events that have plagued human space endeavors almost from the very beginning. Some lessons have been learned in ground-based test beds and others were discovered the hard way - when human lives were at stake in space. From such lessons one can build a risk-management framework for toxicological events to minimize the probability of a harmful exposure, while recognizing that we cannot predict all possible events. Space toxicologists have learned that relatively harmless compounds can be converted by air revitalization systems into compounds that cause serious harm to the crew.

Polymers are one of the major constituents in electrical components. A study investigating pre-combustion off-gassing and particle release by polymeric materials over a range of temperatures can provide an understanding of thermal degradation prior to failure which may result in a fire hazard. In this work, we report simultaneous measurements of pre-combustion vapor and particle release by heated polymeric materials. The polymer materials considered for the current study are silicone and Kapton. The polymer samples were heated over the range 20 to 400°C. Response to vapor releases were recorded using the JPL Electronic Nose (ENose) and Industrial Scientific's ITX gas monitor configured to detect hydrogen chloride (HCl), carbon monoxide (CO) and hydrogen cyanide (HCN). Particle release was monitored using a TSI P-TRAK particle counter.

We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) <165°C. Compounds insoluble or poorly soluble in hydrocarbon were eliminated from consideration, as were those known to cause corrosion (carboxylic acids or high acid number mixtures) and those with hazard classification as known or suspected carcinogens or reproductive toxins.

An EVA simulation with a medical contingency scenario was conducted in 2006 with the NASA Haughton-Mars and EVA Physiology System and Performance Projects, to develop medical contingency management and evacuation techniques for planetary surface exploration. A rescue/evacuation system to allow two rescuer astronauts to evacuate one incapacitated astronaut was evaluated. The rescue system was utilized effectively to extract an injured astronaut up a slope of15-25° and into a surface mobility rover for transport to a simulated habitat for advanced medical care. Further research is recommended to evaluate the effects of reduced gravity and to develop synergies with other surface systems for carrying out the contingency procedures.

Spacecraft radiators reject heat to their surroundings. Radiators can be deployable or mounted on the body of the spacecraft. NASA's Crew Exploration Vehicle is to use body mounted radiators. Coatings play an important role in heat rejection. The coatings provide the radiator surface with the desired optical properties of low solar absorptance and high infrared emittance. These specialized surfaces are applied to the radiator panel in a number of ways, including conventional spraying, plasma spraying, or as an appliqué. Not specifically designed for a weathering environment, little is known about the durability of conventional paints, coatings, and appliqués upon exposure to weathering and subsequent exposure to solar wind and ultraviolet radiation exposure. In addition to maintaining their desired optical properties, the coatings must also continue to adhere to the underlying radiator panel.

As part of preparing for the Crew Exploration Vehicle (CEV), the National Aeronautics and Space Administration (NASA) worked on developing the requirements to manage the fire risk. The new CEV poses unique challenges to current fire protection systems. The size and configuration of the vehicle resembles the Apollo capsule instead of the current Space Shuttle or the International Space Station. The smaller free air volume and fully cold plated avionic bays of the CEV requires a different approach in fire protection than the ones currently utilized. The fire protection approach discussed in this paper incorporates historical lessons learned and fire detection and suppression system design philosophy spanning from Apollo to the International Space Station.

Development of new air revitalization system (ARS) technology can initially be performed in a subscale laboratory environment, but in order to advance the maturity level, the technology must be tested in an end-to-end integrated environment. The Air Revitalization Technology Evaluation Facility (ARTEF) at the NASA Johnson Space Center (JSC) serves as a ground test bed for evaluating emerging ARS technologies in an environment representative of spacecraft atmospheres. At the center of the ARTEF is a hypobaric chamber which serves as a sealed atmospheric chamber for closed loop testing. A Human Metabolic Simulator (HMS) was custom-built to simulate the consumption of oxygen, and production of carbon dioxide, moisture and heat by up to eight persons. A variety of gas analyzers and dew point sensors are used to monitor the chamber atmosphere and the process flow upstream and downstream of a test article. A robust vacuum system is needed to simulate the vacuum of space.

Work is underway to deliver an instrument for analysis of the atmosphere aboard the International Space Station. The Vehicle Cabin Atmosphere Monitor (VCAM) is based on a low-mass, low-power miniature preconcentrator gas chromatograph/mass spectrometer (PCGC/MS) capable of providing sub-ppm measurements of volatile constituents in a space vehicle or outpost. VCAM is designed to operate autonomously, maintenance-free, once per day, with its own carrier and calibration gas supplies sufficient for a one-year lifetime. VCAM performance is sufficient to detect and identify 90% of the target compounds specified at their 180-day Spacecraft Maximum Allowable Concentration (SMAC) levels. The flight units will be delivered in mid-2008 and be operated in the ISS EXPRESS rack.

To meet the challenge of future deep space programs an accurate and efficient engineering code for analyzing the shielding requirements against high-energy galactic heavy radiations is needed. Such engineering design codes require establishing validation processes using laboratory ion beams and space flight measurements in realistic geometries. In consequence, a new version of the HZETRN code capable of simulating HZE ions with either laboratory or space boundary conditions is currently under development. The new code, GRNTRN, is based on a Green's function approach to the solution of Boltzmann's transport equation and like its predecessor is deterministic in nature. Code validation in the laboratory environment is addressed by showing that GRNTRN accurately predicts energy loss spectra as measured by solid-state detectors in ion beam experiments.

Protecting astronauts from space radiation exposure is an important challenge for mission design and operations for future exploration-class and long-duration missions. Crew members are exposed to sporadic solar particle events (SPEs) as well as to the continuous galactic cosmic radiation (GCR). If sufficient protection is not provided the radiation risk to crew members from SPEs could be significant. To improve exposure risk estimates and radiation protection from SPEs, detailed evaluations of radiation shielding properties are required. A model using a modern CAD tool ProE™, which is the leading engineering design platform at NASA, has been developed for this purpose. For the calculation of radiation exposure at a specific site, the cosine distribution was implemented to replicate the omnidirectional characteristic of the 4π particle flux on a surface.

Scientists and engineers at NASA are currently developing flight instruments which will demonstrate oxygen production on the Moon and Mars. REGA will extract oxygen from the lunar regolith, measure implanted solar wind and indigenous gases, and monitor the lunar atmosphere. MIP will demonstrate oxygen production on Mars, along with key supporting technologies including filtration, atmospheric acquisition and compression, thermal management, solar cell performance, and dust removal.

Gas transfer systems in a closed life support test were controlled by intelligent layered monitoring and control software. Interactive simulation-based testing was used for system-level validation of the discrete sequencer layer of the software. An advanced discrete event simulation tool was used to model diverse components and systems for processing gases in a plant growth chamber, crew chamber and incinerator, and transferring gases between chambers. Models included physico-chemical and biological gas processors, pumps, concentrators, chambers and tanks, and devices for configuring and controlling gas transfer. Several types of control were modeled. This paper describes the models, the testing approach, and some results of the testing.

Progress on the delivery of the Vehicle Cabin Atmosphere Monitor (VCAM) is reported. VCAM is an autonomous trace-species detector to be used aboard the International Space Station (ISS) for atmospheric analysis. The instrument is based on a low-mass, low-power miniature preconcentrator, gas chromatograph, and Paul ion trap mass spectrometer (PCGC/MS) capable of measuring volatile constituents in a space vehicle or planetary outpost at sub-ppm levels. VCAM detects and quantifies 40 target compounds at their 180-day Spacecraft Maximum Allowable Concentration (SMAC) levels. It is designed to operate autonomously, maintenance-free, with a self-contained carrier and calibration gas supplies sufficient for a one-year lifetime. Two flight units will be delivered for operation in the ISS EXPRESS rack.

In a crewed spacecraft environment, atmospheric carbon dioxide (CO2) and moisture control are crucial. Hamilton Sundstrand has developed a stable and efficient amine-based CO2 and water vapor sorbent, SA9T, that is well suited for use in a spacecraft environment. The sorbent is efficiently packaged in pressure-swing regenerable beds that are thermally linked to improve removal efficiency and minimize vehicle thermal loads. Flows are controlled with a single spool valve. This technology has been baselined for the new Orion spacecraft, but additional data was needed on the operational characteristics of the package in a simulated spacecraft environment. One unit was tested with simulated metabolic loads in a closed chamber at Johnson Space Center during the latter part of 2006. Those test results were reported in a 2007 ICES paper.

This paper present a summary of the design studies for the suit port proof of concept. The Suit Port reduces the need for airlocks by docking the suits directly to a rover or habitat bulkhead. The benefits include reductions in cycle time and consumables traditionally used when transferring from a pressurized compartment to EVA and mitigation of planetary surface dust from entering into the cabin. The design focused on the development of an operational proof of concept evaluated against technical feasibility, level of confidence in design, robustness to environment and failure, and the manufacturability. A future paper will discuss the overall proof of concept and provide results from evaluation testing including gas leakage rates upon completion of the testing program.

Simultaneous measurements were made for particle releases and off-gassing products produced by heating electrical wires. The wire samples in these experiments were heated to selected temperatures in a heating chamber and responses to vapor releases were recorded by the JPL Electronic Nose (ENose) and an Industrial Scientific ITX gas-monitor; particles released were detected by a TSI P-Trak particle counter. The temperature range considered for the experiment is room temperature (24−26°C) to 500 °C. The results were analyzed by overlapping responses from the ENose, ITX gas sensors and P-Trak, to understand the events (particle release/off-gassing) and sequence of events as a function of temperature and to determine qualitatively whether ENose may be used to detect pre-combustion event markers.

The 2001 Mars Odyssey spacecraft Martian Radiation Environment Experiment (MARIE) is a solid-state silicon telescope high-energy particle detector designed to measure galactic cosmic radiation (GCR) and solar particle events (SPEs) in the 20 – 500 MeV/nucleon energy range. In this paper we discuss the instrument design and focus on the observations and measurements of SPEs at Mars. These are the first-ever SPE measurements at Mars. The measurements are compared with the geostationary GOES satellite SPE measurements. We also discuss some of the current interplanetary particle propagation and diffusion theories and models. The MARIE SPE measurements are compared with these existing models.

As shielding materials are developed for protection against the hazards of galactic cosmic rays, it is desirable to develop a protocol for rapid assessment of shielding properties. Solid state energy loss detectors are often used to estimate the charge and energy of particles in ion beam experiments. The direct measurement is energy deposited in the detector. As a means of separating the charge components in typical shield transmission studies with observation, a stack of many such detectors is used. With high-energy beams and thin targets, surviving primaries and fragments emerging from the target have nearly-equal velocities and deposited energy scales with the square of the charge, simplifying the data analysis. The development of a transport model for the shield and detector arrangement and evaluation of prediction of the energy loss spectrum for direct comparison with the experimentally derived data allows a rapid assessment of the shield transmission characteristics.

Biological water processors are currently being developed for application in microgravity environments. Work has been performed to develop a single-phase, gravity independent anoxic denitrification reactor for organic carbon removal [1]. As a follow on to this work it was necessary to develop a gravity independent nitrification reactor in order to provide sufficient nitrite and nitrate to the organic carbon oxidation reactor for the complete removal of organic carbon. One approach for providing the significant amounts of dissolved oxygen required for nitrification is to require the biological reactor design to process two-phase gas and liquid in micro-gravity. This paper addresses the design and test results overview for development of a tubular, two-phase, gravity independent nitrification biological water processor.

The purification of waste water is a critical element of any long-duration space mission. The Vapor Phase Catalytic Ammonia Removal (VPCAR) system offers the promise of a technology requiring low quantities of expendable material that is suitable for exploration missions. NASA has funded an effort to produce an engineering development unit specifically targeted for integration into the NASA Johnson Space Center's Integrated Human Exploration Mission Simulation Facility (INTEGRITY) formally known in part as the Bioregenerative Planetary Life Support Test Complex (Bio-Plex) and the Advanced Water Recovery System Development Facility. The system includes a Wiped-Film Rotating-Disk (WFRD) evaporator redesigned with micro-gravity operation enhancements, which evaporates wastewater and produces water vapor with only volatile components as contaminants. Volatile contaminants, including organics and ammonia, are oxidized in a catalytic reactor while they are in the vapor phase.