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Under the borderline autoignition conditions experienced during cold-starting of diesel engines, the amount and composition of residual gases may play a deterministic role. Among the intermediate species produced by misfiring and partially firing cycles, formaldehyde (HCHO) is produced in significant enough amounts and is sufficiently stable to persist through the exhaust and intake strokes to kinetically affect autoignition of the following engine cycle. In this work, the effect of HCHO addition at various phases of autoignition of n-heptane-air mixtures is kinetically modeled. Results show that HCHO has a retarding effect on the earliest low-temperature heat release (LTHR) phase, largely by competition for hydroxyl (OH) radicals which inhibits fuel decomposition. Conversely, post-LTHR, the presence of HCHO accelerates the occurrence of high-temperature ignition.

Use of ethanol as gasoline replacement can contribute to the reduction of nitrogen oxide (NOx) and carbon oxide (CO) emissions. Depending on ethanol production, significant reduction of greenhouse-gas emissions is possible. Concentration of certain species, such as unburned ethanol and acetaldehyde in the engine-out emissions are known to rise when ratio of ethanol to gasoline increases in the fuel. This research explores on hydrous ethanol fueled port-fuel injection (PFI) spark ignition (SI) engine emissions that contribute to photochemical formation of ozone, or so-called ozone precursors and the precursor of peroxyacetyl nitrates (PANs). The results are compared to engine operation on gasoline. Concentration obtained by FTIR gas analyzer, and mass-specific emissions of formaldehyde (HCHO), acetaldehyde (MeCHO) and methane (CH4) under two engine speed, four load and two spark advance settings are analyzed and presented.

Misfiring or partial combustion during diesel engine operation results in the production of partial oxidation products such as ethylene (C₂H₄), carbon monoxide and aldehydes, in particular formaldehyde (HCHO). These compounds remain in the cylinder as residual gases to participate in the following engine cycle. Carbon monoxide and formaldehyde have been shown to exhibit a dual nature, retarding ignition in one temperature regime, yet decreasing ignition delay periods of hydrocarbon mixtures as temperatures exceed 1000°K. Largely unknown is the synergistic effects of such species. In this work, varying amounts of C₂H₄ and HCHO are added to the intake air of a naturally aspirated optical diesel engine and their combined effect on autoignition and subsequent combustion is examined. To observe the effect of these dopants on the low-temperature heat release (LTHR), ultraviolet chemiluminescent images are recorded using intensified CCD cameras.

The effect of many operating parameters on the instantaneous frictional (IFT) torque was determined experimentally in a single cylinder diesel engine. The method used was the (P - ω)method developed earlier at Wayne State University. The operating parameters were load, lubricating oil grade, oil, temperature and engine speed. Also IFT was determined under simulated motoring conditions, commonly used in engine friction measurements. The results showed that the motoring frictional torque does not represent that under firing conditions even under no load. The error reached 31.4% at full load. The integrated frictional torque over the whole cycle and the average frictional torque were determined. A comparison of the average frictional torque under load was compared with the average motoring torque.

Due to the single fuel concept implemented by the US military, the soot production of diesel engines fueled with JP-8 has important implications for military vehicle visual signature and survivability. This work compares in-cylinder soot formation and oxidation of JP-8 and ULSD in a small-bore, optical diesel engine. Experimental engine-out soot emission measurements are compared to crank-angle resolved two-color measurements of soot temperature and optical thickness, KL. A 3-D chemical kinetic-coupled CFD model with line of sight integration is employed in order to investigate the soot distribution in a 2-D projection associated with the imaging plane, as well as to aid in interpreting the third dimension along the optical depth which is not available within the experimental work. The study also examines the effect of volatility on soot emission characteristics by CFD simulation.

An experimental fuel surrogate validation approach is proposed for a compression ignition application, and applied to validate a Jet-A POSF 4658 fuel surrogate. The approach examines the agreement of both physical and chemical properties of surrogate and target fuels during validation within a real compression-ignition engine environment during four sequential but distinct combustion phases. In-cylinder Mie Scattering measurements are applied to evaporating sprays to compare the behavior of the surrogate, its target fuel, and for reference, n-heptane. Early mixture formation and low temperature reaction behavior were investigated using 2-D broadband chemiluminescence imaging, while high temperature ignition and combustion chemistry were studied using OH chemiluminescence imaging. The optical measurements were combined with cylinder pressure-based combustion analysis, including ignition delay and premixed burn duration, to validate the global behavior of the surrogate.

This study evaluates the performance of an indirect injection (IDI) diesel engine fueled with cotton seed biodiesel while assessing the engine's multi-fuel capability. Millions of tons of cotton seeds are available in the south of the US every year and approximately 10% of oil contained in the seeds can be extracted and transesterified. An investigation of combustion, emissions, and efficiency was performed using mass ratios of 20-50% cotton seed biodiesel (CS20 and CS50) in ultra-low sulfur diesel #2 (ULSD#2). Each investigation was run at 2400 rpm with loads of 4.2 - 6.3 IMEP and compared to the reference fuel ULDS#2. The ignition delay ranged in a narrow interval of 0.8-0.97ms across the blends and the heat release rate showed comparable values and trends for all fuel blends. The maximum volume averaged cylinder temperature increased by approximately 100K with each increase in 1 bar IMEP load but the maximum remained constants across the blends.

Several mechanisms are discussed to understand the particulate matter (PM) characterization in a high speed, direct injection, single cylinder diesel engine using low sulfur diesel fuel. This includes their formation, size distribution and number density. Experiments were conducted over a wide range of injection pressures, EGR rates, injection timings and swirl ratios, therefore covering both conventional and low temperature combustion regimes. A micro dilution tunnel was used to immediately dilute a small part of the exhaust gases by hot air. A Scanning Mobility Particle Sizer (SMPS) was used to measure the particulate size distribution and number density. Particulate mass was measured with a Tapered Element Oscillating Microbalance (TEOM). Analysis was made of the root cause of PM characterization and their relationship with the combustion process under different operating conditions.

Several mechanisms are discussed to understand the formation of both regulated and unregulated emissions in a high speed, direct injection, single cylinder diesel engine using low sulphur diesel fuel. Experiments were conducted over a wide range of injection pressures, EGR rates, injection timings and swirl ratios. The regulated emissions were measured by the standard emission equipment. Unregulated emissions such as aldehydes and ketones were measured by high pressure liquid chromatography and hydrocarbon speciation by gas chromatography. Particulate mass was measured with a Tapered Element Oscillating Microbalance (TEOM). Analysis was made of the sources of different emission species and their relationship with the combustion process under the different operating conditions. Special attention is given to the low temperature combustion (LTC) regime which is known to reduce both NOx and soot. However the HC, CO and unregulated emissions increased at a higher rate.

This paper presents an experimental investigation conducted to determine the parameters that control the behavior of autoignition in a small-bore, single-cylinder, optically-accessible diesel engine. Depending on operating conditions, three types of autoignition are observed: a single ignition, a two-stage process where a low temperature heat release (LTHR) or cool flame precedes the main premixed combustion, and a two-stage process where the LTHR or cool flame is separated from the main heat release by an apparent negative temperature coefficient (NTC) region. Experiments were conducted using commercial grade low-sulfur diesel fuel with a common-rail injection system. An intensified CCD camera was used for ultraviolet imaging and spectroscopy of chemiluminescent autoignition reactions under various operating conditions including fuel injection pressures, engine temperatures and equivalence ratios.

The focus of this study is to determine the effect of using B-20 (a blend of 20% soybean methyl ester biodiesel and 80% ultra low sulfur diesel fuel) on the combustion process, performance and exhaust emissions in a High Speed Direct Injection (HSDI) diesel engine equipped with a common rail injection system. The engine was operated under simulated turbocharged conditions with 3-bar indicated mean effective pressure and 1500 rpm engine speed. The experiments covered a wide range of injection pressures and EGR rates. The rate of heat release trace has been analyzed in details to determine the effect of the properties of biodiesel on auto ignition and combustion processes and their impact on engine out emissions. The results and the conclusions are supported by a statistical analysis of data that provides a quantitative significance of the effects of the two fuels on engine out emissions.

The objective of this work is to develop a strategy to reduce the penalties in the diesel engine performance, fuel economy and HC and CO emissions, associated with the operation in the low temperature combustion regime. Experiments were conducted on a research high speed, single cylinder, 4-valve, small-bore direct injection diesel engine equipped with a common rail injection system under simulated turbocharged conditions, at IMEP = 3 bar and engine speed = 1500 rpm. EGR rates were varied over a wide range to cover engine operation from the conventional to the LTC regime, up to the misfiring point. The injection pressure was varied from 600 bar to 1200 bar. Injection timing was adjusted to cover three different LPPCs (Location of the Peak rate of heat release due to the Premixed Combustion fraction) at 10.5° aTDC, 5 aTDC and 2 aTDC. The swirl ratio was varied from 1.44 to 7.12. Four steps are taken to move from LTC to ALTC.

The effects of different blends of Soybean Methyl Ester (biodiesel) and ultra low sulfur diesel (ULSD) fuel: B-00 (ULSD), B-20, B-40, B-60, B-80 and B-100 (biodiesel); on autoignition, combustion, performance, and engine out emissions of different species including particulate matter (PM) in the exhaust, were investigated in a single-cylinder, high speed direct injection (HSDI) diesel engine equipped with a common rail injection system. The engine was operated at 1500 rpm under simulated turbocharged conditions at 5 bar IMEP load with varied injection pressures at a medium swirl of 3.77 w ithout EGR. Analysis of test results was done to determine the role of biodiesel percentage in the fuel blend on the basic thermodynamic and combustion processes under fuel injection pressures ranging from 600 bar to 1200 bar.

An experimental setup using rapid compression machine to provide excellent optical access to visualize simulated high-speed small-bore direct injection diesel engine combustion processes is described. Typical combustion visualization results of diesel spray combustion under different EGR, swirl, and injection pressure and nozzle conditions are presented. Different swirl intensities are achieved using an air nozzle with variable orientations and a check valve to connect the compression chamber and the combustion chamber. Different EGR ratios are achieved by pre-injection of diesel fuel prior to the main observation sequence. Clear visualization of the high-pressure fuel injection, ignition, combustion and spray/wall/swirl interactions is obtained. The injection system is a high-pressure common-rail system with either a VCO or a mini-sac nozzle. High-speed movies up to 35,000 frame-per-second are taken using a framing drum camera to record the combustion events.

Three jet fuel surrogates were compared against their target fuels in a compression ignited optical engine under a range of start-of-injection temperatures and densities. The jet fuel surrogates are representative of petroleum-based Jet-A POSF-4658, natural gas-derived S-8 POSF-4734 and coal-derived Sasol IPK POSF-5642, and were prepared from a palette of n-dodecane, n-decane, decalin, toluene, iso-octane and iso-cetane. Optical chemiluminescence and liquid penetration length measurements as well as cylinder pressure-based combustion analyses were applied to examine fuel behavior during the injection and combustion process. HCHO* emissions obtained from broadband UV imaging were used as a marker for low temperature reactivity, while 309 nm narrow band filtered imaging was applied to identify the occurrence of OH*, autoignition and high temperature reactivity.

With increasing interest to reduce the dependency on gasoline and diesel, alternative energy source like compressed natural gas (CNG) is a viable option for internal combustion engines. Spark-ignited (SI) CNG engine is the simplest way to utilize CNG in engines, but direct injection (DI) Diesel-CNG dual-fuel engine is known to offer improvement in combustion efficiency and reduction in exhaust gases. Dual-fuel engine has characteristics similar to both SI engine and diesel engine which makes the combustion process more complex. This paper reports the computational fluid dynamics simulation of both DI dual-fuel compression ignition (CI) and SI CNG engines. In diesel-CNG dual-fuel engine simulations and comparison to experiments, attention was on ignition delay, transition from auto-ignition to flame propagation and heat released from the combustion of diesel and gaseous fuel, as well as relevant pollutants emissions.

This paper investigates the effect of boost pressure and intake temperature on the auto-ignition of fuels with a wide range of properties. The fuels used in this investigation are ULSD (CN 45), FT-SPK (CN 61) and two blends of JP-8 (with CN 25 and 49). Detailed analysis of in-cylinder pressure and rate of heat release traces are made to correlate the effect of intake pressure and injection strategy on the events immediately following start of injection leading to combustion. A CFD model is applied to track the effect of intake pressure and injection strategy on the formation of different chemical species and study their role and contribution in the auto-ignition reactions. Results from a previous investigation on the effect of intake temperature on auto-ignition of these fuels are compared with the results of this investigation.

Biodiesel is a desirable alternative fuel for the diesel engine due to its low engine-out soot emission tendency. When blended with petroleum-based diesel fuels, soot emissions generally decrease in proportion to the volume fraction of biodiesel in the mixture. This paper presents an experimental investigation of biodiesel impact on in-cylinder soot temperature and concentrations in a single-cylinder, small-bore, optical access, compression ignition engine. While in-cylinder soot measurements have been widely performed with two-color thermometry implemented on digital cameras, their finite dynamic range limits the observation of soot due to its dramatically different radiation intensities. To expand the dynamic range of two-color measurements, this investigation utilizes three cameras. A high-speed CMOS color camera with a wide-band Bayer filter is used to obtain simultaneous measurements of soot temperature and KL factor for high intensity soot clouds within one cycle.

Recent legislation entitled “The Single Fuel Forward Policy” mandates that all vehicles deployed by the US military be operable with aviation fuel (JP-8). Therefore, the authors are conducting an investigation into the influence of JP-8 on a diesel engine's performance. The injection, combustion, and performance of JP-8, 20-50% by weight in ULSD (diesel no.2) mixtures (J20-J50) produced at room temperature, were investigated in a small indirect injection, high compression ratio (24.5), 77mm separate combustion chamber diesel engine. The effectiveness of JP8 for application in an auxiliary power unit (APU) at continuous operation (100% load) of 4.78bar bmep/2400rpm was investigated. The blends had an ignition delay of approximately 1.02ms that increased slightly in relation to the amount of JP-8 introduced. J50 and diesel no.2 exhibited similar characteristics of heat release, the premixed phase being combined with the diffusion combustion.

"The Single Fuel Forward Policy" legislation enacted in the United States mandates that deployed U.S. military ground vehicles must be operable with aviation fuel (JP-8). This substitution of JP-8 for diesel raises concerns about the compatibility of this fuel with existing reciprocating piston engine systems. This study investigates the combustion, emissions, and performance characteristics of blends of JP-8 and Ultra Low Sulfur Diesel (ULSD) fuels with similar cetane numbers (CN), 48 (JP-8) and 47(ULSD), respectively, in a direct injection (DI) compression ignition engine over the load range of 3-8 bar imep at 1400 rpm. The results showed that JP-8 blends and ULSD had ignition delays ranging from approximately 1.0-1.4 ms and an average combustion duration time in the range of 47-65 CAD. Cylinder maximum heat flux values were found to be between 2.0 and 4.4 MW/m₂, with radiation flux increasing much faster than convection flux while increasing the imep.