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In this study an attempt to understand and demonstrate the effects of various washcoat technologies under active and passive regeneration conditions was performed. Six different formulations, on 1.0" D. x 3.0" L. SiC wall flow filters at the laboratory level were used at various test conditions, including variable NO₂/NO ratios and O₂ concentrations. Samples were regenerated using active and passive conditions to evaluate regeneration rates and the potential impact of regeneration at the vehicle level. Results were applied to vehicle operating conditions to determine passive functionality and potential benefits. Active regenerations at 2% O₂ and 5% O₂ showed no significant difference in time to complete regeneration and soot burn rates. Active regenerations performed at 1% O₂ and 5% O₂ concentration showed that the regeneration temperature was shifted by approximately 50°C.

Exhaust gas temperature is often measured with a device such as thermocouple or RTD (Resistance Temperature Detector). An alternative method to determine the gas temperature would be to use an existing gas sensor heating mechanism to perform as a temperature sensor. A planar type FLOH (Fast Light Off HEGO-Heated Exhausted Gas Oxygen) sensor under transient vehicle speed/load conditions is suited to this function and was modeled to predict the exhaust gas temperature. The numerical input to the model includes exhaust flow rate, heater voltage, and heater current. Laboratory experiments have been performed to produce an equation relating the resistance of the heater and the temperature of the sensor (heater), which provides a method to indirectly determine HEGO sensor temperature.

A lean-rich hydrothermal aging was used to study the deactivation of Cu-zeolite SCR catalyst that has enhanced stability. Impact of DOC upstream on the SCR catalyst during the lean-rich aging was also investigated. The LR hydrothermal aging was conducted with the presence of hydrocarbon, CO and H₂ at different O₂ levels. It was found that the SCR catalyst was active for the oxidation of CO, H₂ and hydrocarbon, resulting in significant exotherm across the catalyst. In addition to hydrothermal aging, reductive aging, especially the presence of H₂ in the aging gas stream without O₂ presence during the L-R aging, might also contribute to the Cu/zeolite SCR catalyst deactivation. The impacts of DOC upstream on Cu/zeolite SCR catalysts depended on the aging temperatures. At lower aging temperature, the uncompleted oxidation of hydrocarbon and CO on the DOC might cause steam reforming and water-gas shift reactions on the DOC to form reductive gas stream.

Mass transfer limitations from the bulk gas phase to the surface of the catalyst as well as mass transfer limitations within the washcoat itself have important effects on conversion in washcoated monolith catalysts. These factors depend upon the shape of the channel as well as the loading of washcoat material. This paper outlines a method to describe the washcoat distribution profile for different channel shapes and washcoat loadings. This allows for prediction of effectiveness factors and bulk mass transfer coefficients as a function of cell geometry and washcoat loading for the oxidation of propane. It was found that differences in the diffusion limitations within the washcoat control conversion in the catalyst more than differences in bulk mass transfer rates when comparing different cell shapes. The results show that optimum washcoat loadings exist for the geometry of each cell, and that these optimum loadings are a function of catalyst temperature.

Meeting upcoming stringent emission standards will require that exhaust gas catalyst systems become active very quickly, function at very high efficiencies and maintain those capabilities at high mileages. This means that contamination of the catalysts by engine oil derived poisons must be minimized. Phosphorus compounds, derived from the zinc dialkyldithio-phosphate (ZDTP) additives that provide antiwear and antioxidant activity, are a principal contaminant that can increase catalyst light off times and reduce catalyst efficiency. Therefore, reducing the concentration of, or eliminating, phosphorus in engine oils is desirable. Doing so, however, requires that oils be reformulated to ensure that wear protection will not be compromised and that oxidation stability will be maintained. To address these concerns, laboratory tests for evaluating oil oxidation and wear performance have been developed and used to evaluate developmental low phosphorus oils.

The Vehicle Exhaust Emissions Simulator was developed to evaluate the performance of vehicle emissions sampling and analytical systems. The simulator produces a representative tailpipe volume flow rate containing up to five emission constituents, injected via mass flow controllers (MFCs). Eliminating the variability of test results associated with the vehicle, driver, and dynamometer makes the simulator an ideal quality control tool for use in commissioning new test cells, checking data correlation between test cells, and evaluating overall system performance. Earlier vehicle emissions simulators being used in the industry were primarily for checking Constant Volume Samplers (CVSs) and Bag Benches but they did not have the ability to properly simulate tailpipe volume.

A running loss test procedure has been developed which integrates a point-source collection method to measure fuel evaporative running loss from vehicles during their operation on the chassis dynamometer. The point-source method is part of a complete running loss test procedure which employs the combination of site-specific collection devices on the vehicle, and a sampling pump with sampling lines. Fugitive fuel vapor is drawn into these collectors which have been matched to characteristics of the vehicle and the test cell. The composite vapor sample is routed to a collection bag through an adaptation of the ordinary constant volume dilution system typically used for vehicle exhaust gas sampling. Analysis of the contents of such bags provides an accurate measure of the mass and species of running loss collected during each of three LA-4* driving cycles. Other running loss sampling methods were considered by the Auto-Oil Air Quality Improvement Research Program (AQIRP or Program).

Air charge calibration of turbocharged SI gasoline engines with both variable inlet valve lift and variable inlet and exhaust valve opening angle has to be very accurate and needs a high number of measurements. In particular, the modeling of the transition area from unthrottled, inlet valve controlled resp. throttled mode to turbocharged mode, suffers from small number of measurements (e.g. when applying Design of Experiments (DoE)). This is due to the strong impact of residual gas respectively scavenging dominating locally in this area. In this article, a virtual residual gas sensor in order to enable black-box-modeling of the air charge is presented. The sensor is a multilayer perceptron artificial neural network. Amongst others, the physically calculated air mass is used as training data for the artificial neural network.

Results of laboratory studies of the static characteristics of several different commercially available heated exhaust gas oxygen sensors are described. In these studies, the emf of the sensors was measured as a function of temperature and of the composition of calibrated gas mixtures. Several different binary gas mixtures (H2/N2, CO/N2, C3H6/N2, C3H8/N2, and CH4/N2) were used together with a variable amount of O2. In addition to laboratory studies, the same sensors were also studied in the exhaust gas of an engine. Whereas at high temperatures thermodynamic equilibrium appears to prevail, clear departures from thermodynamic equilibrium are observed at some lower temperatures (the value of which depends on the specific sensor and the specific gas mixture used). This behavior is manifested by shifts of the emf step away from stoichiometry, broadening of the step, abnormally high emf values in excess oxygen mixtures, and abnormally low emf values in reducing gas mixtures.

A proportional sampler for vehicle feedgas and tailpipe emissions has been developed that extracts a small, constant fraction of the total exhaust flow during rapid transient changes in engine speed. Heated sampling lines are used to extract samples either before or after the catalytic converter. Instantaneous exhaust mass flow is measured by subtracting the CVS dilution air volume from the total CVS volume. This parameter is used to maintain a constant dilution ratio and proportional sample. The exhaust sample is diluted with high-purity air or nitrogen and is delivered into Tedlar sample bags. These transient test cycle weighted feedgas samples can be collected for subsequent analysis of hydrocarbons and oxygenated hydrocarbon species. This “mini-diluter” offers significant advantages over the conventional CVS system. The concentration of the samples are higher than those collected from the current CVS system because the dilution ratio can be optimized depending on the fuel.

Exhaust gas air-fuel ratio (A/F) sensors are common devices in powertrain feedback control systems aimed at minimizing emissions. Both resistive (using TiO2) and electrochemical (using ZrO2) mechanisms are used in the high temperature ceramic devices now being employed. In this work a new mechanism for making the measurement is presented based on the change in the workfunction of a Pt film in interaction with the exhaust gas. In particular it is found that the workfunction of Pt increases reversibly by approximately 0.7 V at that point (the stoichiometric ratio) where the exhaust changes from rich to lean conditions. This increase arises from the adsorption of O2 on the Pt surface. On returning to rich conditions, catalytic reaction of the adsorbed oxygen with reducing species returns the workfunction to its original value. Two methods, one capacitive and one thermionic, for electrically sensing this workfunction change and thus providing for a practical device are discussed.

For an automotive exhaust system, analytical evaluation of coatings, dual wall, multiwall, and blanket insulation methods indicated that the blanket insulation provided the best method for heat containment. An experimental vehicle was tested with and without a blanket insulation on the exhaust system over a demanding heat protection cycle. The exhaust gas, pipe wall, surrounding air, and adjacent component temperatures at 25 locations along the pipe are reported indicating reduced outer wall temperatures and good containment of the heat. A comparison of the heat lost through the exhaust system walls is presented.

A technique is presented that has been successfully demonstrated to non-intrusively and quickly sample gases typically found in PCV systems. Color Detection Tubes (CDTs) were used with a simple sampling arrangement to monitor CO2, NOx, O2, and H2O(g) at the closure line, crankcase, and PCV line. Measurements were accurate and could be made instantaneously. Short Path Thermal Desorbtion Tubes (SPTDTs) were used at the same engine locations for the characterization of fuel- and oil-derived hydrocarbon (HC) fractions and required only 50 cc samples. High engine loads caused pushover of blowby vapors as indicated by increased concentrations of CO2, NOx, H2O(g), and fuel HCs in the engines' fresh air inlets during WOT operation. Peak concentrations of blowby vapors were measured in the crankcase under no load and part throttle conditions. Oxygen concentrations always opposed the trends of CO2, NOx, and H2O(g).

A hydrocarbon trapping system for cold start emissions was constructed and tested using two types of carbonaceous adsorbents provided by Corning, Inc. One was made by combining activated carbon with an organic binder and extruding it into a honeycomb, and the other by depositing a carbon coating on a ceramic monolith. The tests were carried out on an engine in a dynamometer laboratory to characterize the performance of the carbon elements under transient cold start conditions. Performance was evaluated by continuously measuring exhaust gas hydrocarbon concentrations upstream and downstream of the trap, using conventional emissions consoles. Samples were also collected for off-line analysis of individual hydrocarbon species using gas chromatography to examine differences in adsorption of individual species. The speciated hydrocarbon data were used to distinguish between the mass trapping efficiency and a reactivity-based trapping efficiency of the adsorbant traps.

As vehicle tailpipe emission levels decrease with improvements in emission control technology and reformulation of gasolines, exhaust hydrocarbon levels begin to approach the levels in ambient air. Hydrocarbon speciation at these low levels requires high sensitivity capillary gas chromatography methods. In this study, a mixture of “synthetic” exhaust was prepared at two concentration levels (approximately 5 ppm C and 10 ppm C), and was analyzed by the widely-used Auto/Oil Air Quality Improvement Research Program (AQIRP) Phase II (gas chromatography) speciation method with a sensitivity of 0.005 ppm C for individual species. The mixture at each concentration level, along with a sample of ambient air, was analyzed a total of 20 times on 10 separate days over a 2½ week period. Concentrations of total hydrocarbons (HCs) and individual species (using the AQIRP library) were measured; averages and standard deviations were calculated.

Application of Atmospheric Pressure Chemical Vapor Deposition (APCVD) to the production of thin film coated glass is addressed in this study. Several layers of thin solid film are deposited on the surface of the glass as it moves underneath the APCVD applicator system at high temperature. High velocity in the vicinity of the deposition zone is desirable. Two separated regions of recirculating fluid are generated as the fluid jet exits the injector. The memory effect in the form of thickness streaks, corresponding to the location of the inlet holes located upstream in the upper manifold feed channel, are evident on the thin film. Also, the velocity field in the injector channel is influenced by the location of the holes. This nonuniform gas flow across the glass causes a color variation of the coating. Effective mixing of the gas streams is required to treat the hole memory problem. However, premature reaction is to be avoided.

A steady state model of the ZrO2 exhaust gas oxygen sensor response to a simple (O2,CO,H2,N2) gas mixture has shown that while the detailed shape of the curve for sensor emf output versus inverse redox ratio for the gas mixture depends on many parameters, the step from a relatively high emf to a lower emf that occurs at a critical gas composition can be located from conservation constraints on the individual atomic species. In this paper, these conservation constraints are generalized; a Rule of Mixtures is developed that relates the inverse redox ratio of the gas at the ZrO2 sensor switch point (Rs′) to a weighted average of the corresponding switch points for individual oxygen /gas-component mixtures (Rsjo′): where j denotes a specific reductant species, zj is the stoichiometric factor of the j species for complete oxidation, pj∞ is the partial pressure of gas species j in the mixture, and Δ is a well defined property of the O2 and NO oxidizing gases and the sensor electrodes.

The production of the BMW ALPINA B12 5.7 with Switch-Tronic transmission provides the markets of Europe and Japan with an exclusive, luxury-orientated, high performance limited series limousine. This is the first vehicle worldwide to be fitted with the progressive exhaust gas aftertreatment technology known as the Electrically Heated Catalyst (EHC), in which the effectiveness of the power utilized is increased significantly by an alternating heating process for both catalytic converters. Only since this achievement has the implementation of the EHC been viable without extensive modification to the battery and alternator. With this exhaust gas aftertreatment concept, the emissions of this high performance vehicle will fall to less than half the maximum permissible for compliance with 1996 emission standards.

A life cycle energy model for representing electric (EV) and internal combustion energy (TCV) vehicles is presented. The full life cycle energy for each vehicle is computed including the material production, vehicle assembly, operation, maintenance, delivery, scrapping and recycling contributions. It is found that the modelled electric vehicle (sodium sulphur battery system) consumes 24% less life cycle energy than a functionally equivalent (in carrying capacity and life time distance) gasoline powered internal combustion energy vehicle. In fact, the ICV would have to operate at 50 MPG to be as operationally energy efficient as the EV. However, it should be noted that the EV is not the performance equivalent of the ICV; the former has a lower acceleration, a shorter range, a much longer “refueling time”, and a considerably greater cost. Overall, atmospheric emissions for the EV are lower than those for the ICV, though the former does generate more acid rain gases.

In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.