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Modern automobile diesel engines make use of aluminium cylinder heads that experience both high pressure and thermal loads. Maximum temperatures are above 250°C in the valve bridge area, generating microstructural transformations in the material and thus local evolution of the mechanical properties. To be able to predict the life time of this component with a reasonable amount of confidence, it is therefore necessary to describe these changes in the material. This has been done on a variety of casting materials, with various amount of silicon and copper. Two of them have been taken as references, namely the A356 and 319 type of alloys, making extensive use of Transmission Electron Microscope (TEM) associated with Automatic Image Analysis for quantitative analysis of the precipitation stages during different heat treatments, from the as-received state to saturated aging state.