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Journal Article

Modeling of Thermophoretic Soot Deposition and Hydrocarbon Condensation in EGR Coolers

2009-06-15
2009-01-1939
EGR coolers are effective to reduce NOx emissions from diesel engines due to lower intake charge temperature. EGR cooler fouling reduces heat transfer capacity of the cooler significantly and increases pressure drop across the cooler. Engine coolant provided at 40–90 C is used to cool EGR coolers. The presence of a cold surface in the cooler causes particulate soot deposition and hydrocarbon condensation. The experimental data also indicates that the fouling is mainly caused by soot and hydrocarbons. In this study, a 1-D model is extended to simulate particulate soot and hydrocarbon deposition on a concentric tube EGR cooler with a constant wall temperature. The soot deposition caused by thermophoresis phenomena is taken into account the model. Condensation of a wide range of hydrocarbon molecules are also modeled but the results show condensation of only heavy molecules at coolant temperature.
Journal Article

On the Premixed Phase Combustion Behavior of JP-8 in a Military Relevant Single Cylinder Diesel Engine

2011-04-12
2011-01-0123
Current U.S. Army ground vehicles predominately use commercial off-the-shelf or modified commercial diesel engines as the prime mover. Unique military engines are typically utilized when commercial products do not meet the mobility requirements of the particular ground vehicle in question. In either case, such engines traditionally have been calibrated using North American diesel fuel (DF-2) and Jet Propellant 8 (JP-8) compatibility wasn't given much consideration since any associated power loss due to the lower volumetric energy density was not an issue for most applications at then targeted climatic conditions. Furthermore, since the genesis of the ‘one fuel forward policy’ of using JP-8 as the single battlefield fuel there has been limited experience to truly assess fuel effects on diesel engine combustion systems until this decade.
Journal Article

Effect of Unburned Methyl Esters on the NOx Conversion of Fe-Zeolite SCR Catalyst

2009-11-02
2009-01-2777
Engine and flow reactor experiments were conducted to determine the impact of biodiesel relative to ultra-low-sulfur diesel (ULSD) on inhibition of the selective catalytic reduction (SCR) reaction over an Fe-zeolite catalyst. Fe-zeolite SCR catalysts have the ability to adsorb and store unburned hydrocarbons (HC) at temperatures below 300°C. These stored HCs inhibit or block NOx-ammonia reaction sites at low temperatures. Although biodiesel is not a hydrocarbon, similar effects are anticipated for unburned biodiesel and its organic combustion products. Flow reactor experiments indicate that in the absence of exposure to HC or B100, NOx conversion begins at between 100° and 200°C. When exposure to unburned fuel occurs at higher temperatures (250°-400°C), the catalyst is able to adsorb a greater mass of biodiesel than of ULSD. Experiments show that when the catalyst is masked with ULSD, NOx conversion is inhibited until it is heated to 400°C.
Technical Paper

The Influence of the Operating Duty Cycles on the Composition of Exhaust Gas Recirculation Cooler Deposits of Industrial Diesel Engines

2020-04-14
2020-01-1164
Exhaust Gas Recirculation (EGR) coolers are commonly used in on-road and off-road diesel engines to reduce the recirculated gas temperature in order to reduce NOx emissions. One of the common performance behaviors for EGR coolers in use on diesel engines is a reduction of the heat exchanger effectiveness, mainly due to particulate matter (PM) deposition and condensation of hydrocarbons (HC) from the diesel exhaust on the inside walls of the EGR cooler. According to previous studies, typically, the effectiveness decreases rapidly initially, then asymptotically stabilizes over time. Prior work has postulated a deposit removal mechanism to explain this stabilization phenomenon. In the present study, five field aged EGR cooler samples that were used on construction machines for over 10,000 hours were analyzed in order to understand the deposit structure as well as the deposit composition after long duration use.
Journal Article

The Effects of Temperature, Shear Stress, and Deposit Thickness on EGR Cooler Fouling Removal Mechanism - Part 2

2016-04-05
2016-01-0186
Exhaust gas recirculation (EGR) coolers are used on diesel engines to reduce peak in-cylinder flame temperatures, leading to less NOx formation during the combustion process. There is an ongoing concern with soot and hydrocarbon fouling inside the cold surface of the cooler. The fouling layer reduces the heat transfer efficiency and causes pressure drop to increase across the cooler. A number of experimental studies have demonstrated that the fouling layer tends to asymptotically approach a critical height, after which the layer growth ceases. One potential explanation for this behavior is the removal mechanism derived by the shear force applied on the soot and hydrocarbon deposit surface. As the deposit layer thickens, shear force applied on the fouling surface increases due to the flow velocity growth. When a critical shear force is applied, deposit particles start to get removed.
Journal Article

The Effects of Temperature, Shear Stress, and Deposit Thickness on EGR Cooler Fouling Removal Mechanism - Part 1

2016-04-05
2016-01-0183
Exhaust Gas Recirculation (EGR) coolers are commonly used in diesel and modern gasoline engines to reduce the re-circulated gas temperature. A common problem with the EGR cooler is a reduction of the effectiveness due to the fouling layer primarily caused by thermophoresis, diffusion, and hydrocarbon condensation. Typically, effectiveness decreases rapidly at first, and asymptotically stabilizes over time. There are several hypotheses of this stabilizing phenomenon; one of the possible theories is a deposit removal mechanism. Verifying such a mechanism and finding out the correlation between the removal and stabilization tendency would be a key factor to understand and overcome the problem. Some authors have proposed that the removal is a possible influential factor, while other authors suggest that removal is not a significant factor under realistic conditions.
Journal Article

An EGR Cooler Fouling Model: Experimental Correlation and Model Uses

2017-03-28
2017-01-0535
Thermal effectiveness of Exhaust Gas Recirculation (EGR) coolers used in diesel engines can progressively decrease and stabilize over time due to inner fouling layer of the cooler tubes. Thermophoretic force has been identified as the major cause of diesel exhaust soot fouling, and models are proposed in the literature but improvements in simulation are needed especially for the long-term trend of soot deposition. To describe the fouling stabilization behavior, a removal mechanism is required to account for stabilization of the soot layer. Observations from previous experiments on surrogate circular tubes suggest there are three primary factors to determine removal mechanisms: surface temperature, thickness, and shear velocity. Based on this hypothesis, we developed a 1D CFD fouling model for predicting the thermal effectiveness reduction of real EGR coolers. The model includes the two competing mechanisms mentioned that results in fouling balance.
Journal Article

Data Driven Calibration Approach

2017-03-28
2017-01-0607
Designing a control system that can robustly detect faulted emission control devices under all environmental and driving conditions is a challenging task for OEMs. In order to gain confidence in the control strategy and the values of tunable parameters, the test vehicles need to be subjected to their limits during the development process. Complexity of modern powertrain systems along with the On-Board Diagnostic (OBD) monitors with multidimensional thresholds make it difficult to anticipate all the possible scenarios. Finding optimal solutions to these problems using traditional calibration processes can be time and resource intensive. A possible solution is to take a data driven calibration approach. In this method, a large amount of data is collected by collaboration of different groups working on the same powertrain. Later, the data is mined to find the optimum values of tunable parameters for the respective vehicle functions.
Journal Article

Assessing a Hybrid Supercharged Engine for Diluted Combustion Using a Dynamic Drive Cycle Simulation

2018-04-03
2018-01-0969
This study uses full drive cycle simulation to compare the fuel consumption of a vehicle with a turbocharged (TC) engine to the same vehicle with an alternative boosting technology, namely, a hybrid supercharger, in which a planetary gear mechanism governs the power split to the supercharger between the crankshaft and a 48 V 5 kW electric motor. Conventional mechanically driven superchargers or electric superchargers have been proposed to improve the dynamic response of boosted engines, but their projected fuel efficiency benefit depends heavily on the engine transient response and driver/cycle aggressiveness. The fuel consumption benefits depend on the closed-loop engine responsiveness, the control tuning, and the torque reserve needed for each technology. To perform drive cycle analyses, a control strategy is designed that minimizes the boost reserve and employs high rates of combustion dilution via exhaust gas recirculation (EGR).
Journal Article

Influence of Injector Location on Part-Load Performance Characteristics of Natural Gas Direct-Injection in a Spark Ignition Engine

2016-10-17
2016-01-2364
Interest in natural gas as an alternative fuel source to petroleum fuels for light-duty vehicle applications has increased due to its domestic availability and stable price compared to gasoline. With its higher hydrogen-to-carbon ratio, natural gas has the potential to reduce engine out carbon dioxide emissions, which has shown to be a strong greenhouse gas contributor. For part-load conditions, the lower flame speeds of natural gas can lead to an increased duration in the inflammation process with traditional port-injection. Direct-injection of natural gas can increase in-cylinder turbulence and has the potential to reduce problems typically associated with port-injection of natural gas, such as lower flame speeds and poor dilution tolerance. A study was designed and executed to investigate the effects of direct-injection of natural gas at part-load conditions.
Journal Article

Analysis of High Mileage Gasoline Exhaust Particle Filters

2016-04-05
2016-01-0941
The purpose of this work was to examine gasoline particle filters (GPFs) at high mileages. Soot levels for gasoline direct injection (GDI) engines are much lower than diesel engines; however, noncombustible material (ash) can cause increased backpressure, reduced power, and lower fuel economy. In this study, a post mortem was completed of two GPFs, one at 130,000 mi and the other at 150,000 mi, from two production 3.5L turbocharged GDI vehicles. The GPFs were ceramic wall-flow filters containing three-way catalytic washcoat and located downstream of conventional three-way catalysts. The oil consumption was measured to be approaching 23,000 mpqt for one vehicle and 30,000 mpqt for the other. The ash contained Ca, P, Zn, S, Fe, and catalytic washcoat. Approximately 50 wt% of the collected ash was non-lubricant derived. The filter capture efficiency of lubricant-derived ash was about 50% and the non-lubricant metal (mostly Fe) deposition rate was 0.9 to 1.2 g per 10,000 mi.
Journal Article

Lubricant-Derived Ash Impact on Gasoline Particulate Filter Performance

2016-04-05
2016-01-0942
The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.
Journal Article

Effect of Syngas (H2/CO) on SI Engine Knock under Boosted EGR and Lean Conditions

2017-03-28
2017-01-0670
Syngas (synthesis gas) aided combustion from various fuel reforming strategies is of increasing interest in boosted lean burn SI engines due to its impact on dilution tolerance and knock resistance. Due to the interest in reformed fuels, more concrete understanding of how to leverage syngas supplementation under various lean conditions is essential to optimize engine performance and derive the most benefit from the availability of syngas in the combustion process. While the impact of syngas supplementation on combustion stability has been studied adequately, detailed understanding of the impact of syngas on knocking is still limited. Hence, this study investigates the effect of syngas (H2/CO) addition on knock tendency under boosted EGR (Exhaust Gas Recirculation) and air diluted conditions. Syngas amount is controlled on an energy basis from 0% to 15% to compare the difference between EGR and air dilution.
Journal Article

Analysis of Ash in Low Mileage, Rapid Aged, and High Mileage Gasoline Exhaust Particle Filters

2017-03-28
2017-01-0930
To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.
Journal Article

Enhanced Durability of a Cu/Zeolite Based SCR Catalyst

2008-04-14
2008-01-1025
Passenger and light duty diesel vehicles will require up to 90% NOx conversion over the Federal Test Procedure (FTP) to meet future Tier 2 Bin 5 standards. This accomplishment is especially challenging for low exhaust temperature applications that mostly operate in the 200 - 350°C temperature regime. Selective catalytic reduction (SCR) catalysts formulated with Cu/zeolites have shown the potential to deliver this level of performance fresh, but their performance can easily deteriorate over time as a result of high temperature thermal deactivation. These high temperature SCR deactivation modes are unavoidable due to the requirements necessary to actively regenerate diesel particulate filters and purge SCRs from sulfur and hydrocarbon contamination. Careful vehicle temperature control of these events is necessary to prevent unintentional thermal damage but not always possible. As a result, there is a need to develop thermally robust SCR catalysts.
Journal Article

Combined Fe-Cu SCR Systems with Optimized Ammonia to NOx Ratio for Diesel NOx Control

2008-04-14
2008-01-1185
Selective catalytic reduction (SCR) is a viable option for control of oxides of nitrogen (NOx) from diesel engines. Currently, copper zeolite (Cu-zeolite) SCR catalysts are favored for configurations where the exhaust gas temperature is below 450°C for the majority of operating conditions, while iron zeolite (Fe-zeolite) SCR catalysts are preferred where NOx conversion is needed at temperatures above 450°C. The selection of Cu-zeolite or Fe-zeolite SCR catalysts is based on the different performance characteristics of these two catalyst types. Cu-zeolite catalysts are generally known for having efficient NOx reduction at low temperatures with little or no NO2, and they tend to selectively oxidize ammonia (NH3) to N2 at temperatures above 400°C, leading to poor NOx conversion at elevated temperatures.
Journal Article

An Evaluation of Residual Gas Fraction Measurement Techniques in a High Degree of Freedom Spark Ignition Engine

2008-04-14
2008-01-0094
Stringent fuel economy and emissions regulations have driven development of new mixture preparation technologies and increased spark-ignition engine complexity. Additional degrees of freedom, brought about by devices such as cam phasers and charge motion control valves, enable greater range and flexibility in engine control. This permits significant gains in fuel efficiency and emission control, but creates challenges related to proper engine control and calibration techniques. Accurate experimental characterization of high degree of freedom engines is essential for addressing the controls challenge. In particular, this paper focuses on the evaluation of three experimental residual gas fraction measurement techniques for use in a spark ignition engine equipped with dual-independent variable camshaft phasing (VVT).
Journal Article

Selective Catalytic Reduction for Treating the NOx Emissions from Lean-Burn Gasoline Engines: Durability Assessment

2008-04-14
2008-01-0811
A laboratory study was performed to assess the potential of using selective catalytic reduction (SCR) with NH3 to treat the NOx emissions from lean-burn gasoline engines. A primary concern was the potential for hot rich exhaust conditions on the vehicle, as such conditions could degrade the zeolite-based SCR catalysts being developed for automotive applications. Samples of an iron/zeolite formulation were aged for 34 hours behind samples of a three-way catalyst (TWC) on a pulse-flame combustion reactor using different A/F ratio schedules that exposed the catalysts to either continuously lean operation, mostly stoichiometric operation, or mostly rich operation. For each A/F ratio schedule, separate SCR samples were aged with inlet temperatures of 750°C, 800°C, or 850°C. The aged SCR samples were evaluated for NOx conversion at 25K hr-1 during lean temperature ramps with 500 ppm NO and NH3.
Journal Article

Detection, Origin and Effect of Ultra-Low Platinum Contamination on Diesel-SCR Catalysts

2008-10-06
2008-01-2488
This paper discusses the poisoning of a selective catalytic reduction (SCR) catalyst by trace levels of platinum originating from an upstream diesel oxidation catalyst (DOC). A diesel aftertreatment system consisting of a DOC, urea based SCR Catalyst and a DPF was aged and evaluated on a 6.4 liter diesel engine dynamometer. The SCR catalyst system consisted of an Fe-zeolite catalyst followed by a Cu-zeolite catalyst. After approximately 400 hours of engine operation at varied exhaust flow rates and temperatures, deactivation of the SCR catalyst was observed. A subsequent detailed investigation revealed that the Cu catalyst was not deactivated and the front half of the Fe-based catalyst showed severe deactivation. The deactivated portion of the catalyst showed high activity of NH3 conversion to NOx and N2O formation. The cause of the deactivation was identified to be the presence of trace Pt contamination.
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