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In this work, a quasi-dimensional, multi-zone combustion model is analytically presented, for the prediction of performance and nitric oxide (NO) emissions of a homogeneous charge spark ignition (SI) engine, fueled with biogas-H2 blends of variable composition. The combustion model is incorporated into a closed cycle simulation code, which is also fully described. Combustion is modeled on the basis of turbulent entrainment theory and flame stretch concepts. In this context, the entrainment speed, by which unburned gas enters the flame region, is simulated by the turbulent burning velocity of a flamelet model. A flame stretch submodel is also included, in order to assess the flame response on the combined effects of curvature, turbulent strain and nonunity Lewis number mixture. As far as the burned gas is concerned, this is treated using a multi-zone thermodynamic formulation, to account for the spatial distribution of temperature and NO concentration inside the burned volume.

This study investigates the impact of mid-high biodiesel blends on the criteria and PAH emissions from a modern pick-up diesel vehicle. The vehicle was a Euro 4 (category N1, subclass III) compliant common-rail light-duty goods pick-up truck fitted with a diesel oxidation catalyst. Emission and fuel consumption measurements were performed on a chassis dynamometer equipped with CVS, following the European regulations. All measurements were conducted over the certification New European Driving Cycle (NEDC) and the real traffic-based Artemis driving cycles. Aiming to evaluate the fuel impact on emissions, a soy-based biodiesel, a palm-based biodiesel, and an oxidized biodiesel obtained from used frying oils were blended with a typical automotive ultra-low-sulfur diesel at proportions of 30, 50 and 80% by volume. The experimental results revealed that CO₂ emissions and fuel consumption exhibited an increase with biodiesel over all driving conditions.

In this study, regulated, unregulated exhaust emissions and fuel consumption with ultra low sulphur diesel and soy-based biodiesel blends at proportions of 10 and 30% v/v have been investigated. A Euro 4 compliant SUV, equipped with a 2.2 litre common-rail diesel engine and an oxidation catalyst was tested on a chassis dynamometer with constant volume sampling (CVS) technique. Emission and fuel consumption measurements were performed over the New European Driving Cycle (NEDC) and the non-legislated Artemis driving cycles which simulate urban, rural, and highway driving conditions in Europe. The regulated pollutants were characterized by determined NOx, PM, CO, and HC. CO2 was also quantified in the exhaust. Overall, 16 PAHs, 4 nitro-PAHs, 6 oxy-PAHs, 13 carbonyl compounds and particulate alkanes ranged from C13 to C35 were determined in the exhaust.

Many incidents associated with filter plugging have extensively been reported in microbially contaminated diesel and biodiesel fuel systems, especially under long term storage conditions. In this study a quantitative assessment of the undesirable insoluble solids produced in contaminated biodiesel fuels was carried out in order to evaluate their evolution rate during biodeterioration. For this purpose, a series of contaminated biodiesel fuel microcosms were prepared and stored for six months under stable conditions. The quantity of the particulate contaminants was monitored during storage by a multiple filtration technique which was followed at the end by a comparison with the active bioburden per ATP bioluminescence protocol. Additionally, identical microcosms were treated with a commercially available biocide in order to examine the latter’s activity both on solids formation and the microbial proliferation.

During recent years, the deterioration of greenhouse phenomenon, in conjunction with the continuous increase of worldwide fleet of vehicles and crude oil prices, raised heightened concerns over both the improvement of vehicle mileage and the reduction of pollutant emissions. Diesel engines have the highest fuel economy and thus, highest CO2 reduction potential among all other thermal propulsion engines due to their superior thermal efficiency. However, particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines are comparatively higher than those emitted from modern gasoline engines. Therefore, reduction of diesel emitted pollutants and especially, PM and NOx without increase of specific fuel consumption or let alone improvement of diesel fuel economy is a difficult problem, which requires immediate and drastic actions to be taken.

In this study, the transesterification process of 4 different vegetable oils (sunflower, rapeseed, olive oil and used frying oil) took place utilizing ethanol, in order to characterize the ethyl esters and their blends with diesel fuel obtained as fuels for internal combustion engines. All ethyl esters were synthesized using calcium ethoxide as a heterogeneous solid base catalyst. The ester preparation involved a two-step transesterification reaction, followed by purification. The effects of the mass ratio of catalyst to oil, the molar ratio of ethanol to oil, and the reaction temperature were studied on conversion of sunflower oil to optimize the reaction conditions in both stages. The rest of the vegetable oils were converted to ethyl esters under optimum reaction parameters. The optimal conditions for first stage transesterification were an ethanol/oil molar ratio of 12:1, catalyst amount (3.5%), and 80 °C temperature, whereas the maximum yield of ethyl esters reached 80.5%.

Homogeneous Charge Compression Ignition (HCCI) engines have the potential of reducing NOx emissions as compared to conventional Diesel or SI engines. Soot emissions are also very low due to the premixed nature of combustion. However, the unburned hydrocarbon emissions are relatively high and the same holds for CO emissions. The formation of these pollutants, for a given fuel, is strongly affected by the temperature distribution as well as by the charge motion within the engine cylinder. The foregoing physical mechanisms determine the local ignition timing and burning rate of the charge affecting engine efficiency, performance and stability. Obviously the success of any model describing HCCI combustion depends on its ability to describe adequately both the chemistry of combustion and the physical phenomena, i.e. heat and mass transfer within the cylinder charge. In the present study a multi-zone model is developed to describe the heat and mass transfer mechanism within the cylinder.

Thermodynamic, dynamic and design parameters have a significant and often conflicting impact on the transient response of a compression ignition engine. Knowing the contribution of each parameter on transient operation could direct the designer to the appropriate measures for better engine performance. To this aim an explicit simulation program developed is used to study the performance of a turbocharged diesel engine operating under transient load conditions. The simulation developed, based on the filling and emptying approach, provides various innovations as follows: Detailed analysis of thermodynamic and dynamic differential equations, on a degree crank angle basis, accounting for the continuously changing nature of transient operation, analysis of transient mechanical friction, and also a detailed mathematical simulation of the fuel pump. Each equation in the model is solved separately for every cylinder of the 6-cylinder diesel engine considered.

Simulation models are widely used from research engineers to investigate the combustion mechanism of DI diesel engines. These models can be used, as tools to either comprehend information provided by experimental data or to perform predictions and assist the development process. As widely recognized a valuable source of information for engine performance and emissions studies is the cylinder pressure trace. It can provide after processing information concerning the combustion rate of fuel injected inside the combustion chamber. Often it is also used to calibrate simulation models or even to derive correlations to represent the combustion rate of fuel inside the combustion chamber. The present research team has during the development process of a simulation model for the description of DI diesel engine performance and emissions realized that there exists a serious problem.

The direct injection diesel engine is one of the most efficient thermal engines known to man. For this reason DI diesel engines are widely used for heavy-duty applications and especially for the propulsion of trucks. Even though the efficiency of these engines is currently at a high level there still exist possibilities for further improvement. One way to accomplish this is by increasing the injection timing which usually improves, depending on the operating conditions, the indicated efficiency of the engine. On the other hand advanced injection timing has a negative effect on peak pressure causing a serious increase of its value, a negative effect on NO emissions which are also seriously increased and a positive effect on Soot emissions which are reduced. In the present work a theoretical and experimental investigation is presented to determine the effect of more advanced injection timing on engine performance and pollutant emissions.

Pollutant emissions and specifically NO and soot are one of the most important problems that engineers have to face when developing heavy duty DI diesel engines. Two main strategies exist as options for their control, reduction inside the engine cylinder using advanced combustion and fuel injection technologies and use of after-treatment systems. In the present work it is examined the use of EGR to control the formation of NO inside the cylinder of an engine with extremely high peak pressure. The work is applied on a single cylinder truck test engine developed under a project funded by the European Community focusing on the improvement of heavy duty DI diesel engine efficiency using increased injection timing. Use is made of a simulation model to predict the effect of more advanced injection timing on engine performance and emissions. The model has been modified to include the effect of EGR used to c ontrol the formation of NO which is considerably increased at high injection timings.

The current work uses a method developed by the authors for both combustion irreversibility and working medium availability computations in a high speed, naturally aspirated, four stroke, internal combustion engine cylinder. The objective of the study was to extrapolate already published results of the second-law analysis of diesel engine operation by studying parametrically the effect of main operating parameters such as engine speed of rotation, injection timing, and fuel composition. Extensive experimental data were available for the case of dodecane injection, which were used for the determination of the fuel reaction rate. Computationally, the same reaction rates were used for methane and methanol injection. The production rate of irreversibility during combustion was analytically calculated as a function of the fuel reaction rate with the combined use of first and second-law arguments and a chemical equilibrium hypothesis.

Contemporary vehicles have to satisfy high ride comfort criteria. In order to determine appropriate human body model in driving condition field and laboratory investigations on passenger cars have been performed. In field research, dominant vibrations loading of passenger was determined by variance analysis of experimental results. The highest loading is in vertical and the lowest is in lateral direction. These results were base for further laboratory investigations. Group of thirty volunteer subjects was tested. We examined the influence of broadband random vibrations on human body behavior by Seat To Head Transmissibility (STHT) function. The influence of vertical and fore and aft vibrations on occupants were examined separately. In addition to, the influence of multi directional vibration was investigated.

The fuel supply chain faces challenges associated with microbial contamination symptoms. Microbial growth is an issue usually known to be associated with middle distillate fuels and biodiesel, however, incidents where microbial populations have been isolated from unleaded gasoline storage tanks have also been recently reported. Alcohols are employed as gasoline components and the use of these oxygenates is rising, especially ethanol, which can be a renewable alternative to gasoline, as well. Despite their alleged disinfectant properties, a number of field observations suggests that biodeterioration could be a potential issue in fuel systems handling ethanol-blended gasoline. For this reason, in this study, the effect of alcohols on microbial proliferation in unleaded gasoline fuel was assessed. Ethanol (EtOH), iso-propyl alcohol (IPA) and tert-butyl-alcohol (TBA) were evaluated as examples of alcohols utilized in gasoline as oxygenates.

FAME is the most common renewable component of conventional automotive diesel. Despite the advantages, biodiesel is more susceptible to oxidative deterioration and due to its chemical composition as well as its higher affinity to water, is considered to be a favorable substrate for microorganisms. On the other hand, apart from biodiesel, alcohols are considered to be promising substitutes to conventional diesel fuel because they can offer higher oxygen concentration leading to better combustion characteristics and lower exhaust emissions. More specifically, n-butanol is a renewable alcohol demonstrating better blending capabilities and properties when it is added to diesel fuel, as its composition is closer to conventional fuel, when compared ethanol to for example. Taking into consideration the alleged disinfectant properties of alcohols, it would be interesting to examine also the microbial stability of blends containing n-butanol in various concentrations.

Cylinder pressure measurements are common practice for internal combustion reciprocating engines during field or lab applications for the purpose of combustion analysis, condition monitoring etc. The most accurate method is to measure cylinder pressure using a crank angle encoder as a trigger source to guarantee cylinder pressure measurement at predefined crank angle events. This solution, even though favorable, presents a number of practical difficulties for field applications and increased cost, for this reason its use is practically restricted to lab applications. Therefore a commonly used approach for ad hoc measurements is to digitize samples at fixed time intervals and then convert time into crank angle assuming a constant rotational speed. But if engine rotational speed is not constant within the engine cycle this may result to incorrect cylinder pressure CA referencing.

The ability of a catalyst to enhance the performance of synthesized biobased lubricant basestock was investigated in this study. Pomace olive oil, cottonseed oil, used frying oil and methyl oleate were utilized as starting materials for the production of the biobased lubricants and a two stages transesterification methodology was followed. Initially the oils were converted to their corresponding fatty acid methyl esters via methanolysis. The resulting methylesters were subsequently transesterified with TMP producing the desired oleochemical ester. These syntheses were carried out in the presence of either sodium methoxide or Ca/TEA alkoxide as catalysts. Following the purification phase, the synthesized esters were evaluated as potential biolubricants regarding their physicochemical properties such as viscosity index, pour point and acid value.

High efficiency, power concentration and reliability are the main requirements from Diesel Engines that are used in most technical applications. This becomes more important with the increase of engine size. For this reason the aforementioned characteristics are of significant priority for both marine and power generation applications. To guarantee efficient engine operation and maximum power output, both research and commercial communities are increasingly interested in methods used for supervision, fault-detection and fault diagnosis of large scale Diesel Engines. Most of these methods make use of the measured cylinder pressure to estimate various critical operating parameters such as, brake power, fuel consumption, compression status, etc. The results obtained from the application of any diagnostic technique, used to assess the current engine operating condition and identify the real cause of the malfunction or fault, depend strongly on the quality of these data.

During the last years a great effort has been made by many NATO nations to move towards the use of one military fuel for all the land-based military aircraft, vehicles and equipment employed on the military arena. This idea is known to as the Single Fuel Concept (SFC). The fuel selected for the idea of SFC is the JP-8 (F-34) military aviation fuel which is based upon the civil jet fuel F-35 (Jet A-1) with the inclusion of military additives possessing anti-icing and lubricating properties. An extended experimental investigation has been conducted in the laboratory of Thermodynamic and Propulsion Systems at the Hellenic Air Force Academy. This investigation was conducted with the collaboration of the respective laboratories of National Technical University of Athens and Hellenic Naval Academy as well.

A transient analysis simulation program is developed for studying the response of an indirect injection, naturally aspirated, diesel engine after a rapid increase in load when this is equipped with various types of indirect acting governors. Analytical expressions are presented for the better simulation of engine mechanical friction, inertia moments and heat loss to the walls under transient conditions, governor dynamics for both the sensing element and the servopiston, soot emissions and the fuel pump operation. Various types of governor sensing elements (i.e. mechanical, electrical, two-pulse) and feedbacks (i.e. unity and vanishing) for the servomechanism are studied. Explicit diagrams are given to show how each combination of governor type and technical parameters (i.e. mass and number of flyweights, geometrical dimensions, amplification factors) affects the speed response as well as the speed droop and the recovery period of the particular engine.