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In recent years, catalyst systems such as a lean NOx trap (LNT) catalyst system and a urea selective catalytic reduction (SCR) system have been developed to obtain cleaner diesel emissions. At Nissan, we developed an emission control system for meeting Tier 2 Bin 5 requirements in 2003. On the basis of that technology, a new HC-NOx trap catalyst system has now been developed that complies with the SULEV standards without increasing the catalyst volume and precious metal loading. Compliance with the SULEV standards requires a further reduction of HC (NMHC) emissions by 84% and NOx by 60% compared with the emission performance Tier 2 Bin 5 compliant catalyst system. Consequently high conversion performance for both HCs and NOx is needed. An investigation of HC emission behavior under the FTP75 mode showed that a reduction of cold-phase HCs was critical for meeting the standard. Large quantities of HCs above C4 are emitted in the cold state.

This paper presents an improved exhaust emission simulation model that takes into account fuel transportation behavior in order to obtain more precise air-fuel ratio control, which is needed to meet stringent exhaust emission standards. This simulation model is based on experimental formulas for air and fuel behavior in the intake manifold, especially during transient engine operation. Fuel behavior, including the effect of wall flow on the air-fuel ratio, is obtained analytically. Predictions are then made of the exhaust emissions from a car operated under official driving schedules. The new simulation model is a useful tool in the design and development of fuel supply control systems. An outline of the new model is presented first along with a comparison of the calculated and experimental results. The air-fuel ratio control strategy derived with this model is then described.

A new method for measuring unregulated substances in the exhaust gas is being investigated to clarify the influence of the vehicles' exhaust emissions into the environment. This paper explains our work on developing an analysis method for detecting and quantifying trace substances in the exhaust gas. A new analysis method was examined that uses thermal desorption to analyze trace amounts of polycyclic aromatic hydrocarbons (PAHs) in vehicle exhaust gas. This technique is faster than conventional methods and does not require any preconditioning of the samples before analysis. While lead and chloromethane were detected in the exhaust gas samples, it was made clear that these substances did not originate in the engine system. Accordingly, the results of this study indicate that careful attention must be paid to the test environment and the presence of measurement interfering substances in exhaust samples when measuring trace constituents in the exhaust gas from low-emission vehicles.

Nissan Motor has put on the European SUV market a 2.2-L direct-injection diesel engine with a diesel particulate filter (DPF) system that complies with the EURO IV emission regulations. This paper describes the DPF system, cooperative control of a variable geometry turbo (VGT) and exhaust gas recirculation (EGR), and a high-accuracy lambda control adopted for this engine. In order to achieve a compact DPF, the high-accuracy lambda control was developed to reduce variation in engine-out particulate matter (PM) emissions. Moreover, the accuracy of the technique for predicting the quantity of PM accumulation was improved for reliable detection of the DPF regeneration. Prediction error for PM accumulation increases during transient operation. Control logic was adopted to correct the PM prediction according to lambda fluctuation detected by an observer for lambda at cylinder under transient operating conditions. The observer is corrected lambda sensor output.

A variable compression ratio (VCR) technology, that has a new piston-crankshaft mechanism with multi links, has been patented and developed by Nissan for some years (This technology has been detailed in previous SAE paper 2003-01-0921 and 2005-01-1134). This paper will present the use of this VCR technology for Diesel engine. The objective set with the use of VCR for Diesel engine is mainly to reduce as much as possible engine out emission to prepare for long-term, more strict emission standards. Results presented will include the description of the 2l Diesel VCR engine and its VCR mechanism adapted to Diesel constraints. Combustion tests have been performed with the use of HCCI (Homogeneous Charge Compression Ignition) combustion. This technology is still in a research phase in Renault: the adaptation of VCR technology to a Diesel engine consists in the modification of several parts with the addition of lower links, control links and control shaft.

The Diesel Particulate Filter (DPF) system has been developed as one of key technologies to comply with tight diesel PM emission regulations. For the DPF control system, it is necessary to maintain temperature inside the DPF below the allowable service temperature, especially during soot regeneration to prevent catalyst deterioration and cracks. Therefore, the evaluation of soot regeneration is one of the key development items for the DPF system. On the other hand, regeneration evaluation requires a lot of time and cost since many different regeneration conditions should be investigated in order to simulate actual driving. The simulation tool to predict soot regeneration behavior is a powerful tool to accelerate the development of DPF design and safe regeneration control strategies. This paper describes the soot regeneration model applied to fuel additive and catalyzed types, and shows good correlation with measured data.

Generally, cobalt-contained sintered materials have mainly been applied for exhaust valve seat inserts (VSI). However, there is a trend to restrict the use of cobalt as well as lead environmental law, and cobalt is expensive. To solve these problems, a new exhaust VSI on the assumption of being cobalt and lead free, applicable for conventional engines, having good machinability, and with a reduced cost was developed. The new exhaust VSI is a material dispersed with two types of hard particles, Fe-Cr-C and Fe-Mo-Si, in the matrix of an Fe-3.5mass%Mo at the ratio of 15 mass % and 10 mass % respectively.

Experimental investigations were conducted with a direct-injection diesel engine to improve exhaust emission, especially nitrogen oxide (NOx) and particulate matter (PM), without increasing fuel consumption. As a result of this work, a new combustion concept, called Modulated Kinetics (MK) combustion, has been developed that reduces NOx and smoke simultaneously through low-temperature combustion and premixed combustion, respectively. The characteristics of a new combustion concept were investigated using a single cylinder DI diesel engine and combustion photographs. The low compression ratio, EGR cooling and high injection pressure was applied with a multi-cylinder test engine to accomplish premixed combustion at high load region. Combustion chamber specifications have been optimized to avoid the increase of cold-start HC emissions due to a low compression ratio.

Impact of oil-derived ash on the pressure drop of continuous regeneration-type diesel particulate filter (CR-DPF) was investigated through 600hrs running test at maximum power point on a 6.9L diesel engine, which meets the Japanese long-term emission regulations enacted in 1998, using approximately 50ppm sulfur content fuel. Sulfated ash content of test oils were varied as 0.96, 1.31, and 1.70 mass%, respectively. During the running test, the exhaust pressure drop through CR-DPF was measured. And after the test, the ventilation resistance through CR-DPF was also evaluated before and after the baking process, which was applied to eliminate the effect of soot accumulated in CR-DPF. The results revealed that the less sulfated ash in oil gave rise to lower pressure drop across CR-DPF. According to microscope examination of the baked DPF, ash was mainly accumulated on the wall surface of CR-DPF, and that seemed to be related to the magnitude of pressure drop caused by ash.

Experimental investigations were previously conducted with a direct-injection diesel engine with the aim of reducing exhaust emissions, especially nitrogen oxides (NOx) and particulate matter (PM). As a result of that work, a combustion concept, called Modulated Kinetics (MK) combustion, was developed that reduces NOx and smoke simultaneously through low-temperature combustion and premixed combustion to achieve a cleaner diesel engine. In subsequent work, it was found that applying a low compression ratio was effective in expanding the MK combustion region on the high-load side. The MK concept was then combined with an exhaust after-treatment system and applied to a test vehicle. The results indicated the attainment of ULEV emission levels, albeit in laboratory evaluations. In the present work, the combination of the MK combustion concept and certain fuel properties has been experimentally investigated with the aim of reducing exhaust emissions further.

This paper describes the third generation of the partial zero emission vehicle (P-ZEV) technology originally adopted on the Nissan Sentra CA sold in California. The 2000 Nissan Sentra CA became the world's first gasoline-fueled car to qualify for P-ZEV credits from the California Air Resources Board (CARB). The third-generation P-ZEV system has been substantially reduced in size and cost, compared with the Sentra CA system, enabling it to be used on high-volume models. This system complies with the P-ZEV requirements, including those for zero evaporative emissions and Onboard Diagnostics II (OBD-II). To achieve a more compact and lower-cost system, an ultra-thin-walled catalyst substrate, the world's first to attain a 1.8-mil wall thickness, has been adopted along with catalysts that display excellent low-temperature activity. As a result, low-temperature catalyst activity has been significantly improved.

This paper describes the emission reduction technologies applied to 4- and 6-cylinder engines used on Japanese market models certified as ultra-low emission vehicles (U-LEVs) in Japan. To qualify for this rigorous U-LEV certification, a vehicle must reduce hydrocarbon (HC) and nitrogen oxide (NOx) emissions by an additional 75% from the levels mandated by Japan's 2000 exhaust emission regulations. Nearly all Nissan Japanese models fitted with a gasoline engine, ranging from in-line 4-cylinder engines to V6 engines, have now been certified as U-LEVs. This has been accomplished by further improving the emission reduction technologies that were developed for the Sentra CA, which was launched in the U.S. market in 2000 as the world's first gasoline-fueled vehicle to qualify for Partial Zero Emission Vehicle (P-ZEV) credits from the California Air Resources Board. The specific new technologies involved are as follows.

HC emission standards will be tightened during the 1990's in the US. A key issue in reducing HC emission is improving the warm-up characteristics of catalysts during the cold start of engines. For this purpose, studies are under way on reduction of heat mass of ceramic substrates. Reduction of cell walls in substrates to thickness smaller than the current thickness of 12mil or 6mil has resulted in reduced heat mass, and also reduced flow restriction of substrates. The warm-up characteristics of low bulk density catalysts are better than those of high bulk density, i.e., the warm-up characteristics of thinner wall or lower cell density catalysts are better than those of thicker wall or higher cell density catalysts. A relationship between geometric surface area and warm-up characteristics is observed.

Emission regulations for diesel-powered vehicles have been gradually tightening. Installation of after-treatment devices such as diesel particulate filters (DPF), NOx storage reduction (NSR) catalysts, and so on is indispensable to satisfy rigorous limits of particulate matter (PM) and nitrogen oxides (NOx). Japan Clean Air Program II Oil Working Group (JCAPII Oil WG) has been investigating the effect of engine oil on advanced diesel after-treatment devices. First of all, we researched the impact of oil-derived ash on continuous regeneration-type diesel particulate filter (CR-DPF), and already reported that the less sulfated ash in oil gave rise to lower pressure drop across CR-DPF [1]. In this paper, impact of oil-derived sulfur and phosphorus on NSR catalyst was investigated using a 4L direct injection common-rail diesel engine with turbo-intercooler. This engine equipped with NSR catalyst meets the Japanese new short-term emission regulations.

With the aim of improving the air quality in large cities, the California Air Resources Board (CARB) has stipulated that non-methane organic gas (NMOG) composed of carbon numbers from C1 to C12 must be reduced for vehicle categories designated as Transitional Low Emission Vehicles (TLEVs), Low Emission Vehicles (LEVs), Ultra low Emission Vehicles (ULEVs), and Zero Emission Vehicles (ZEVs). Although considerable research work has been done on this issue to date, the entire picture is still not clear. Studies done by the authors have been aimed at providing a better understanding of the potential for reducing automotive tailpipe emissions by using several clean fuel candidates. The major questions of concern are the extent to which emissions of certain species can actually be reduced and what fuel can provide the best performance under a reduced NMOG condition.

Nissan has developed a non-methane organic gas (NMOG) emission measuring method based on California Air Resources Board (CARB) procedures.1) In addition, a system to analyze the chemical species present in the exhaust gases at Low Emission Vehicles (LEV) and Ultra Low Emission Vehicles (ULEV) levels has been created. It was found that when using an electrically heated catalyst (EHC) to achieve the low emissions for LEV and ULEV levels, the interference between exhaust HC species and the contamination of the analyzing system are a serious problem for the measurement of speciated emissions. The methyl tertiary butyl ether (MTBE) contained in reformulated gasoline can interfere with HC speciation in the Chromatogram, requiring that the automatically speciated results be checked by a trained operator. The low exhaust HC emissions of bags 2 and 3 in the Federal Test Procedure (FTP) are nearly equal to that of the background air utilized in the constant volume sampler (CVS) dilution.

The California Low-Emission Vehicle (LEV) standards mandate a reduction in non-methane organic gases (NMOG). With the aim of analyzing NMOG emissions, a comparison was made of the hydrocarbon species found in the exhaust gas when different types of catalyst systems and fuel specifications were used. NMOG emissions are usually measured by removing methane from the total hydrocarbon (THC) emissions and adding aldehyde and ketone emissions. The NMOG level found in this way is thus influenced by the rate of methane in THC emissions. Another important factor in the LEV standards is specific reactivity (SR), indicating the formation potential of ozone, which is one cause of photochemical smog. Specific reactivity is expressed by the amount of ozone generated per unit weight of NMOG emissions, and is affected by the respective proportion of hydrocarbon species in the total NMOG emissions.

This paper presents a new-generation, lightweight, 3-liter V6 engine that has been developed for use in the next Nissan Maxima. The distinctive features of this new engine, VQ30DE, is its compact, lightweight design and excellent fuel economy. The basic construction of the engine is characterized by its 60-degree V6 configuration, chain-driven DOHC and high-pressure die cast aluminum cylinder block. A two-way cooling system was adopted with the aim of shortening the warm-up time of the cylinder liners. The new engine has been designed to comply with the tougher emission standards, the OBD-II requirements and California's new evaporative emission standard.

In 1994, the California Air Resources Board implemented low-emission vehicle (LEV) standards with the aim of improving urban air quality. One feature of the LEV standards is the increasingly tighter regulation of non-methane organic gases (NMOG), taking into account ozone formation, in addition to the existing control of non-methane hydrocarbons (NMHC). Hydrocarbons and other organic gases emitted by S.I. engines have been identified as a cause of atmospheric ozone formation. Since the reactivity of each chemical species in exhaust emissions differs, the effect on ozone formation varies depending on the composition of the exhaust gas components. This study examined the effect of different engine types, fuel atomization conditions, turbulence and emission control systems on emission species and specific reactivity. This was done using gas chromatographs and a high-performance liquid chromatograph to analyze exhaust emission species that affect ozone formation.

The effect of the introduction of low-emission vehicles on potential air quality improvement in the Los Angeles area was predicted using a three-dimensional airshed simulation model. The simulations were based on ozone concentration estimates made on the basis of data released by the California Air Resources Board concerning projected quantities of emissions from various sources in 2010. Analyses were made of three scenarios. One assumed that LEV, ULEV and ZEV regulations were enforced as planned, a second assumed that these planned regulations were modified; and a third assumed that emission levels from various sources were reduced in line with the goals of the Air Quality Management Plan formulated by the South Coast Air Quality Management District.