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Effects of fuel cell material properties on water management were numerically investigated using Volume of Fluid (VOF) method in the FLUENT. The results show that the channel surface wettability is an important design variable for both serpentine and interdigitated flow channel configurations. In a serpentine air flow channel, hydrophilic surfaces could benefit the reactant transport to reaction sites by facilitating water transport along channel edges or on channel surfaces; however, the hydrophilic surfaces would also introduce significantly pressure drop as a penalty. For interdigitated air flow channel design, it is observable that liquid water exists only in the outlet channel; it is also observable that water distribution inside GDL is uneven due to the pressure distribution caused by interdigitated structure. An in-situ water measurement method, neutron imaging technique, was used to investigate the water behavior in a PEM fuel cell.

An ignition delay correlation was developed for a toluene reference fuel (TRF) blend that is representative of automotive gasoline fuels exhibiting two-stage ignition. Ignition delay times for the autoignition of a TRF 91 blend with an antiknock index of 91 were predicted through extensive chemical kinetic modeling in CHEMKIN for a constant volume reactor. The development of the correlation involved determining nonlinear least squares curve fits for these ignition delay predictions corresponding to different inlet pressures and temperatures, a number of fuel-air equivalence ratios, and a range of exhaust gas recirculation (EGR) rates. In addition to NO control, EGR is increasingly being utilized for managing combustion phasing in spark ignition (SI) engines to mitigate knock. Therefore, along with other operating parameters, the effects of EGR on autoignition have been incorporated in the correlation to address the need for predicting ignition delay in SI engines operating with EGR.

The effect of biodiesel on the Particulate emissions is gaining significant attention particularly with the drive for the use of alternative fuels. The particulate matter (PM), especially having a diameter less than 50 nm called the Nanoparticles or Nucleation mode particles (NMPs), has been raising concerns about its effect on human health. To better understand the effect of biodiesel and its blends on particulate emissions, steady state tests were conducted on a small-bore single-cylinder high-speed direct-injection research diesel engine. The engine was fueled with Ultra-Low Sulfur Diesel (ULSD or B-00), a blend of 20% soy-derived biodiesel and 80% ULSD on volumetric basis (B-20), B-40, B-60, B-80 and 100% soy-derived biodiesel (B-100), equipped with a common rail injection system, EGR and swirl control systems at a load of 5 bar IMEP and constant engine speed of 1500 rpm.

The current study focused on the effects B20 fuel (20% soybean-based biodiesel) and SCR entrance shapes on a light-duty, high-speed, 2.8L common-rail 4-cylinder diesel engine, at different exhaust temperatures. The results indicate that B20 has less deNOX efficiency at low temperature than ULSD, and that N₂O emission need to be characterized as well as NH₃ slip. If a mixer and enough mixing length are used, longer divergence section does not improve the deNOX efficiency significantly under the speed ranges tested.

In view of the new regulations for diesel engine emissions, EGR is used to reduce the NOx emissions. Diluting the charge with EGR affects the autoignition, combustion as well as the regulated and unregulated emissions of diesel engines, under different operating conditions. This paper presents the results of an investigation on the effect of EGR on the global activation energy and order of the autoignition reactions, premixed and mixing-controlled combustion fractions, the regulated (unburned hydrocarbons, NOx, CO and particulates), aldehydes, CO2 and HC speciation. The experiments were conducted on two different direct injection, four-stroke-cycle, single-cylinder diesel engines over a wide range of operating conditions and EGR ratios.

The flow structure inside the catalytic converter of gasoline engines is very important for consideration of the catalyst light-off condition, converter durability and conversion efficiency. However, the available experimental data under actual engine exhaust conditions are quite limited due to its complicated configuration, critical operating conditions and difficult optical access. Therefore, an experimental study was performed, using laser Doppler velocimetry technique, to measure the velocity distributions inside two production dual-monolith catalytic converters fitted on a firing gasoline engine over several engine operating conditions. This paper reports the normal velocity characteristics measured in a plane 1 mm away from the front surface of first monolith. A small fraction of titanium (IV) isopropoxide was dissolved in gasoline for generating titanium dioxide seeding particles during the engine combustion.

One of the gray areas in the implementation of regulations limiting the generation of pollutants from mobile sources is the actual effectiveness of the exhaust gas emissions control strategy in vehicles that have been in use for some time. While it is possible today to conduct limited diagnostics with the on-board engine computer by performing periodic checks to verify the validity of the signals measured by the on-board sensors, and to measure tailpipe emissions during routine inspection and maintenance, the task of correlating these measurements with each other to provide an on-line, accurate diagnosis of critical malfunctions has thus far proven to be a very challenging task, especially in the case of misfire.

More stringent regulations have been enforced over the past few years on diesel exhaust emissions. White smoke emission, a characteristic of diesel engines during cold starting, needs to be controlled in order to meet these regulations. This study investigates the sources and constituents of white smoke. The effects of fuel properties, design and operating parameters on the formation and emissions of white smoke are discussed. A new technique is developed to measure the real time gaseous hydrocarbons (HC) as well as the solid and liquid particulates. Experiments were conducted on a single cylinder direct injection diesel engine in a cold room. The gaseous HC emissions are measured using a high frequency response flame ionization detector. The liquid and solid particulates are collected on a paper filter placed upstream of the sampling line of the FID and their masses are determined.

A number of automotive diagnostic equipment and procedures have evolved over the last two decades, leading to two generations of on-board diagnostic requirements (OBDI and OBDII), increasing the number of components and systems to be monitored by the diagnostic tools. The goal of On-Board Diagnostic is to alert the driver to the presence of a malfunction of the emission control system, and to identify the location of the problem in order to assist mechanics in properly performing repairs. The aim of this paper is to suggest a methodology for the development of an Integrated Powertrain Diagnostic System (EPDS) that can combine the information supplied by conventional tailpipe inspection programs with onboard diagnostics to provide fast and reliable diagnosis of malfunctions.

This paper presents a concept for enhancing catalytic removal of pollutant species from an exhaust stream by placing placing the plasma adjacent to the catalyst surface. Model calculations of the behavior of the electron energy distribution function (EEDF), which influences the chemistry and ionization levels near the surface, are performed and analyzed. Preliminary experiments attempting to reduce these theoretical ideas to practice in N2/NO mixtures, are discussed. Although removal of NO is observed, this is due to gas phase effects alone. The present experimental arrangement is not able to produce the requisite conditions outlined by theory to enact plasma-enhanced catalysis.

The evolution of the diagnostic equipment for automotive application is the direct effect of the implementation of sophisticated and high technology control systems in the new generation of passenger cars. One of the most challenging issues in automotive diagnostics is the ability to assess, to analyze, and to integrate all the information and data supplied by the vehicle's on-board computer. The data available might be in the form of fault codes or sensors and actuators voltages. Moreover, as environmental regulations get more stringent, knowledge of the concentration of different species emitted from the tailpipe during the inspection and maintenance programs can become of great importance for an integrated powertrain diagnostic system. A knowledge-based diagnostic tool is one of the approaches that can be adopted to carry out the challenging task of detecting and diagnosing faults related to the emissions control system in an automobile.

An experimental investigation was conducted on a small-bore, high-speed diesel engine to study the effect of different operating parameters on combustion and engine-out emissions in the conventional and low temperature regimes. For the conventional diesel combustion, the spray behavior is analyzed and a differentiation is made between the conditions in the small-bore and the larger bore quiescent chamber engines. The effects of the injection pressure, exhaust gas recirculation (EGR), injection timing and swirl ratio (SR) on combustion and engine-out emission are investigated. The trade-off between NOx and smoke, measured in Bosch smoke unit, (BSU), is investigated with a special attention to the low temperature combustion regime, (LTC). The results showed that the LTC regime could be reached at fairly high EGR rates under all the injection pressures investigated in this work. The margin for the variation in EGR was limited just before the misfiring EGR.

A hot and cold water mixing process with a steam condenser and a chilled water heat exchanger is set up for an engine EGR fouling test. The test rig has water recycled in the loop of a pump, heat exchangers, a three-way mixing valve, and a test EGR unit. The target unit temperature is controlled by a heating, cooling and mixing process with individual valves regulating the flow-rate of saturated steam, chilled water and mixing ratio. The challenges in control design are the dead-time, interaction, nonlinearity and multivariable characteristics of heat exchangers, plus the flow recycle in the system. A systems method is applied to extract a simple linear model for control design. The method avoids the nonlinearity and interaction among different temperatures at inlet, outlet and flow-rate. The test data proves the effectiveness of systems analysis and modeling methodology. As a result, the first-order linear model facilitates the controller design.