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The need for a consistent and reliable calculation of thermodynamic property of refrigerants has been a topic of research since the past decade. This paper reports a study of various cubic equations of state for a refrigerant being used in automotive air-conditioning applications. The thermodynamic property of refrigerant 1,1,1,2 tetrafluoroethane (commercially known as R134a) is estimated for this purpose. A comparative analysis is made on three sets of equations of state. They are Redlich Kwong equation (RK), Peng Robinson equation (PR) and Patel Teja equation. It is found that the Patel-Teja and Peng-Robinson equations are accurate in the operating region of automotive air-conditioning system. Using these literature based equations and Maxwell correlations, thermodynamic models are developed. They estimate thermodynamic properties of saturated liquid/vapor, sub-cooled liquid and superheated vapor phases.

Air-cooled fin and tube heat exchangers are used as a condenser in the conventional automotive Heating Ventilation & Air-Conditioning (HVAC) systems. In this study, the use of liquid cooled plate heat exchanger as a condenser in the automotive HVAC systems has been investigated. In the proposed configuration, the cabin heat absorbed by the refrigerant in HVAC system is rejected to the coolant through a liquid cooled condenser and then to the ambient air through a low temperature radiator. Hence, the proposed configuration combines heat rejection from HVAC system with a low temperature radiator circuit of power train cooling. Mixture of Ethylene glycol & Water (coolant), which is used in power train cooling system, is used as secondary fluid in the condenser.