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In diesel engines the optimization of engine-out emissions, combustion noise and fuel consumption requires the experimental investigation of the effects of different injection strategies as well as of a large number of engine operating variables, such as scheduling of pilot and after pulses, rail pressure, EGR rate and swirl level. Due to the high number of testing conditions involved full factorial approaches are not viable, whereas Design of Experiment techniques have demonstrated to be a valid methodology. However, the results obtained with such techniques require a subsequent critical analysis, so as to investigate the cause and effect relationships between the set of engine operating variables and the combustion process characteristics that affect pollutant formation, noise of combustion and engine efficiency.

New methodologies have been developed to optimize EGR rate and injection timing in diesel engines, with the aim of minimizing fuel consumption (FC) and NOx engine-out emissions. The approach entails the application of a recently developed control-oriented engine model, which includes the simulation of the heat release rate, of the in-cylinder pressure and brake torque, as well as of the NOx emission levels. The engine model was coupled with a C-class vehicle model, in order to derive the engine speed and torque demand for several driving cycles, including the NEDC, FTP, AUDC, ARDC and AMDC. The optimization process was based on the minimization of a target function, which takes into account FC and NOx emission levels. The selected control variables of the problem are the injection timing of the main pulse and the position of the EGR valve, which have been considered as the most influential engine parameters on both fuel consumption and NOx emissions.

In this study, a new EGR control technique, based on the estimate of the oxygen concentration in the intake manifold, was firstly investigated through numerical simulation and then experimentally tested, both under steady state and transient conditions. The robustness of the new control technique was also tested and compared with that of the conventional EGR control technique by means of both numerical simulation and experimental tests. Substantial reductions of the NOx emissions under transient operating conditions were achieved, and useful knowledge for controlling the EGR flow rate more accurately was obtained.

La1-xAxNi1-yByO3 nanostructured perovskite-type oxides catalysts (where A = Na, K, Rb and B = Cu; x = 0, 0.2 and y = 0, 0.05, 0.1), also supporting 2% in weight of gold, were prepared via the so-called “Solution Combustion Synthesis (SCS)” method, and characterized by means of XRD, BET, FESEM-EDS and TEM analyses. The performance of these catalysts towards the simultaneous oxidation of soot and CO was evaluated. The 2 wt.% Au-La0.8K0.2Ni0.9Cu0.1O3 showed the best performance with a peak carbon combustion temperature of 367 °C and the half conversion of CO reached at 141 °C. The same nanostructured catalyst, deposited by in situ SCS directly over a SiC filter and tested on real diesel exhaust gases, fully confirmed the encouraging results obtained on the powder catalyst.

Different EGR system layouts (a Long Route, a Short Route, and a combination of the two) were evaluated by means of both numerical simulation and experimental tests. In particular, a one-dimensional fluid-dynamic engine model was built in order to evaluate the potential of a Long Route EGR system as well as the potential of different EGR combinations between Long and Short Route. By means of the one-dimensional model, used as a virtual test bench, the estimations of the NOx emissions, based on the Extended Zeldovich Mechanism (EZM), for the different solutions, were compared and valuable information for the calibration of the coordinated EGR LR, EGR SR and Variable Geometry Turbine (VGT) control systems was obtained.

In this work different internal and external EGR strategies, combined with extreme Miller cycles, were analyzed by means of a one-dimensional CFD simulation code for a Wärtsilä 6-cylinder, 4-strokes, medium-speed marine diesel engine, to evaluate their potential in order to reach the IMO Tier 3 NOx emissions target. By means of extreme Miller cycles, with Early Intake Valve Closures (up to 100 crank angle degrees before BDC), a shorter compression stroke and lower charge temperatures inside the cylinder can be achieved and thanks to the cooler combustion process, the NOx-specific emissions can be effectively reduced. EIVC strategies can also be combined with reductions of the scavenging period (valve overlap) to increase the amount of exhaust gases in the combustion chamber. However, the remarkably high boost pressure levels needed for such extreme Miller cycles, require mandatorily the use of two-stage turbocharging systems.

A quasi-dimensional multizone combustion model, that was previously developed by the authors, has been refined and applied for the analysis of combustion and emission formation in a EURO V diesel engine equipped with a piezo indirect-acting injection system. The model is based on the integration of the predictive non-stationary variable-profile 1D spray model recently presented by Musculus and Kattke, with a diagnostic multizone thermodynamic model specifically developed by the authors. The multizone approach has been developed starting from the Dec conceptual scheme, and is based on the identification of several homogeneous zones in the combustion chamber, to which mass and energy conservation laws have been applied: an unburned gas zone, made up of air, EGR (Exhaust Gas Recirculation) and residual gas, several fuel/unburned gas mixture zones, premixed combustion burned gas zones and diffusive combustion burned gas zones.

Nano-structured perovskite-type oxides catalysts La1-xAxFe1-yByO3 (where A = Na, K, Rb and B = Cu), prepared by the Solution Combustion Synthesis (SCS) method and characterized by BET, XRD, FESEM, AAS and catalytic activity tests in microreactors and engine bench, proved to be effective in the simultaneous removal of soot and NO, the two prevalent pollutants in diesel exhaust gases in the temperature range 350-450°C. The best compromise between soot and nitrogen oxide abatement was shown by La-K-Cu-FeO3 catalyst which displayed the highest catalytic activity towards carbon combustion and the highest NO conversion activity.

Although the use of Exhaust Gas Recirculation (EGR) is nowadays mandatory for automotive diesel engines to achieve NOx emissions levels complying with more and more stringent legislation requirements, electronically controlled EGR systems still represent an expensive technology, often unsuitable for small diesel engines for off-road applications or for two/three wheelers. An interesting option for these categories of small diesel engines is the so-called “internal EGR”, which is obtained by modifying the intake or the exhaust valve lift profile, in order to increase the fraction of exhaust residuals at the end of the intake stroke. Different valve lift profiles were therefore evaluated for a 2 cylinders, 700 cc, Lombardini IDI diesel engine, equipping a light 4 wheelers vehicle.

The unsteady flow effects in two different close coupled catalytic converters were investigated in order to achieve a better understanding of the steady state experimental tests which are usually performed to evaluate a flow distribution. Firstly the validity of a CFD model was achieved through a comparison of some steady state simulations with the results of HWA experimental measurements. Several different formulations of the uniformity index, that were found in literature, were then compared, trying to highlight the strengths and shortcomings of each one. Further information was derived from a comparison of the two catalysts that were tested to achieve a general methodology that would be useful for future analysis. Finally, a new approach to evaluate the flow distribution using a steady state analysis was proposed by comparing the results of a transient simulation that was obtained for a whole engine cycle.

The aim of this work was to obtain a reduction in pollutant emissions, in particular for NOx and Soot, in an “Off-Road” DI Diesel Engine, equipped with a common rail injection system, by means of exhaust gas recirculation (EGR). First, an engine simulation was performed using a one-dimensional code, and the model was then calibrated with experimental results obtained from a previous research work conducted on bench tests. Thanks to the engine model, specific emissions were then determined in all conditions, that is, in “eight modes” pertaining to engine loads and speeds. Both the injection advance and EGR amount were changed for all of these conditions in order to obtain the best compromise between fuel consumption and emissions and to respect standard regulations. The investigation was performed using both the Wiebe and a more complex combustion models; this latter allows in fact to determine the soot emission through the Nagle-Strickland model.

Nowadays stringent emission regulations are pushing towards new air management strategies like LP-EGR and HP/LP mix both for passenger car and heavy duty applications, increasing the engine control complexity. Within a project in collaboration between Kohler Engines EMEA, Politecnico di Torino, Ricardo and Denso to exploit the potential of EGR-Only technologies, a 3.4 liters KDI 3404 was equipped with a two stage turbocharging system, an extremely high pressure FIS and a low pressure EGR system. The LP-EGR system works in a closed loop control with an intake oxygen sensor actuating two valves: an EGR valve placed downstream of the EGR cooler that regulates the flow area of the bypass between the exhaust line and the intake line, and an exhaust flap to generate enough backpressure to recirculate the needed EGR rate to cut the NOx emission without a specific aftertreatment device.

The need for achieving a fast warm up of the exhaust system has raised in the recent years a growing interest in the adoption of Variable Valve Actuation (VVA) technology for automotive diesel engines. As a matter of fact, different measures can be adopted through VVA to accelerate the warm up of the exhaust system, such as using hot internal Exhaust Gas Recirculation (iEGR) to heat the intake charge, especially at part load, or adopting early Exhaust Valve Opening (eEVO) timing during the expansion stroke, so to increase the exhaust gas temperature during blowdown. In this paper a simulation study is presented evaluating the impact of VVA on the exhaust temperature of a modern light duty 4-cylinder diesel engine, 1.6 liters, equipped with a Variable Geometry Turbine (VGT).

In this work, several nanostructured ceria-based catalysts were prepared by the hydrothermal technique varying two synthesis parameters (namely, temperature and pH). Then, cerias with different shapes (i.e., cubes, rods, combination of them, other polyhedra) and structural properties were obtained. The prepared materials were tested for the CO oxidation and soot oxidation efficiency. The results have shown that, for the CO oxidation, activities depend on the surface properties of the catalysts. Conversely, for the soot oxidation, the most effective catalysts exhibit better soot-catalyst contact conditions.

A precise estimation of the recirculated exhaust gas rate and oxygen concentration as well as a predictive evaluation of the possible EGR unbalance among cylinders are of paramount importance, especially if non-conventional combustion modes, which require high EGR flow-rates, are implemented. In the present paper, starting from the equation related to convergent nozzles, the EGR mass flow-rate is modeled considering the pressure and the temperature upstream of the EGR control valve, as well as the pressure downstream of it. The restricted flow-area at the valve-seat passage and the discharge coefficient are carefully assessed as functions of the valve lift. Other models were fitted using parameters describing the engine working conditions as inputs, following a semi-physical and a purely statistical approach. The resulting models are then applied to estimate EGR rates to both conventional and non-conventional combustion conditions.

Molybdenum sulfide nanoparticles have been successfully obtained, for lubricant applications, by means of a wet chemical synthesis in an aqueous solution employing ammonium molybdate, citric acid and ammonium sulfide as the reactants. Some molybdenum-citrate complexes were formed and they reacted with the ammonium sulfide to form MoS₂ nanoparticles. Mo:citrate molar ratio was identified as being the most relevant of the synthesis parameters that affected the phase and morphology of the final products. The optimized nanopowders were softly agglomerated and amorphous, with a mean size of the primary particles of about 30 nm. The compatibility between the thus obtained MoS₂ nanopowders and some commercial after-treatment catalysts for diesel vehicle engines was tested. Diesel oxidation, soot combustion and ammonia-SCR de-NOx catalysts were considered as were the possible effects on the catalytic activity and their possible reaction to the MoS₂ additive.

A new procedure for the real-time estimation of the EGR rate and charge oxygen concentration has been developed, assessed and applied to a low-compression ratio GMPT-E EURO V diesel engine. High EGR rates are usually employed in modern diesel engines to reduce combustion temperatures and NOx emissions, especially at medium-low load and speed conditions. The EGR rate is usually calibrated in steady-state conditions, but, under transient conditions, it can be responsible for misfire occurrence or non optimal combustion cycles, if not properly controlled. In other words, combustion instabilities can occur, especially during tip-in maneuvers, which imply transition from high EGR (low load) to low EGR (high load) rates. Misfire is determined by a temporary reduction in the intake charge oxygen concentration during the closure of the EGR valve.

An innovative approach to the study of combustion and emission formation in modern diesel engines has been applied to a EURO V diesel engine equipped with an indirect-acting piezo injection system. The model is based on the joint use of a predictive non-stationary 1D spray model, which has recently been presented by Musculus and Kattke, and a diagnostic multizone thermodynamic model developed by the authors. The combustion chamber content has been split into homogeneous zones, to which mass and energy conservation laws have been applied: an unburned gas zone, made up of air, EGR and residual gas, several fuel/unburned gas mixture zones, premixed combustion burned gas zones and diffusive combustion burned gas zones. The 1D spray model enables the mixing process dynamics of the different fuel parcels with the unburned gas to be estimated for each injection pulse; therefore, the equivalent ratio time-history of each mixture zone can be estimated.

The present work has the aim of developing a fast approach for the predictive calculation of in-cylinder combustion temperatures and NOx formation in diesel engines, under steady state and transient conditions. The model has been tested on a PC, and found to require very little computational time, thus suggesting it could be implemented in the ECU (Engine Control Unit) of engines for model-based control tasks. The method starts with the low-throughput predictive combustion model that was previously developed by the authors, which allows the predictive estimation of the heat-release rate and of the in-cylinder pressure trace to be made on the basis of the injection parameters and of a few quantities measured by the ECU, such as the intake manifold pressure and temperature.

The effects of using blended renewable diesel fuel (30% vol.), obtained from Rapeseed Methyl Ester (RME) and Hydrotreated Vegetable Oil (HVO), in a Euro 5 small displacement passenger car diesel engine have been evaluated in this paper. The hydraulic behavior of the common rail injection system was verified in terms of injected volume and injection rate with both RME and HVO blends fuelling in comparison with commercial diesel. Further, the spray obtained with RME B30 was analyzed and compared with diesel in terms of global shape and penetration, to investigate the potential differences in the air-fuel mixing process. Then, the impact of a biofuel blend usage on engine performance at full load was first analyzed, adopting the same reference calibration for all the tested fuels.