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Due to the principle of direct injection, which is applied in modern homogeneously operated gasoline engines, there are various operation points with significant particulate emissions. The spray droplets contact the piston surface during the warm-up and early injections, in particular. The fuel wall films and the resulting delayed evaporation of the liquid fuel is one of the main sources of soot particles. It is therefore necessary to carry out investigations into the formation of wall film. The influence of the spray impact angle is of special interest, as this is a major difference between engines with side-mounted injectors and centrally positioned injectors. This paper describes an infrared thermography-based method, which we used to carry out a systematic study of fuel deposits on the walls of the combustion chamber. The boundary conditions of the test section were close to those of real GDI engines operated with homogeneous charge.