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Previous research has shown that elevating fuel injection pressure results in better air-fuel mixture formation, allowing for a further increase in maximum exhaust gas recirculation (EGR) rate while consequently reducing NOx emissions. The aim of this paper is to find out whether there is an optimum injection pressure for lowest soot-NOx emissions at a given boost pressure in high-speed diesel engines. Experiments are carried out on a single-cylinder research engine with a prototype common-rail system, capable of more than 200 MPa injection pressure. The effect of injection pressure on soot-NOx formation is investigated for a variety of boost conditions, representing the conditions of single to multi-stage turbocharger systems. Analysis of the data is performed at the application relevant soot to NOx ratio of approximately 1:10. It is observed that above a critical injection pressure, soot-NOx emissions are not reduced any further.

In this article a new zero-dimensional model is presented for simulating the cylinder pressure in direct injection diesel engines. The model enables the representation of current combustion processes considering multiple injections, high exhaust gas recirculation rates, and turbocharging. In these methods solely cycle-resolved, scalar input variables from the electronic control unit in combination with empirical parameters are required for modeling. The latter are adapted automatically to different engines or modified applications using measured cylinder pressure traces. The verification based on measurements within the entire operating range from engines of different size and type proves the universal applicability and high accuracy of the proposed method.

Misfiring of the engine can cause damage to the catalyst within short time and increase emissions. Under misfiring conditions, unburned fuel and oxygen are pumped into the catalyst, where its combustion heavily increases the temperature. For this reason there is a demand for fast detection of misfiring. Once judged, one can take countermeasures to avoid further temperature rise. Two methods of misfire detection with the prospect of future use in series production are discussed. A first approach uses the trace shape of the λ-sensor signal for evaluation. The second approach uses the speed fluctuations of the engine for detection. Efficient algorithms give the possibility of misfire detection in the full load-speed range with reasonable effort to protect the catalyst. However there will remain some misfire conditions, increasing the emissions above regulation limits, that cannot be detected by those methods.

External Exhaust Gas Recirculation, EGR, is a central issue in controlling emissions in up-to-date diesel engines. An empirical model has been developed that calculates the EGR ratio as a function of the engine speed, the engine load and special characteristics of the heat release rate. It was found that three combustion characteristics correlate well with the EGR ratio. These characteristics are the ignition delay, the premixed combustion ratio and the mixing-controlled combustion ratio. The calculation of these characteristics is based on parameter subsets, which were determined using an optimization routine. The model presented was developed based on these optimized characteristics.

To fulfill future emission standards for diesel engines, combined after-treatment systems consisting of different catalyst technologies and diesel particulate filters (DPF) are necessary. For designing and optimizing the resulting systems of considerable complexity, effective simulation models of different catalyst and DPF technologies have been developed and integrated into a common simulation environment called ExACT (Exhaust After-treatment Components Toolbox). This publication focuses on a model for the NOx storage and reduction catalyst as a part of that simulation environment. A heterogeneous, spatially one-dimensional (1D), physically and chemically based mathematical model of the catalytic monolith has been developed. A global reaction kinetic approach has been chosen to describe reaction conversions on the washcoat. Reaction kinetic parameters have been evaluated from a series of laboratory experiments.

A numerical model describing the ammonia based SCR process of NOX on zeolite catalysts is presented. The model is able to simulate coated and extruded monoliths. The development of the reaction kinetics is based on a study which compares the activity of zeolite and vanadium based catalysts. This study was conducted in a microreactor loaded with washcoat powder and with crushed coated monoliths. A model for the SCR reaction kinetics on zeolite catalysts is presented. After the parameterization of the reaction mechanism the reaction kinetics were coupled with models for heat and mass transport. The model is validated with laboratory data and engine test bench measurement data over washcoated monolith catalysts. A numerical simulation study is presented, aiming to reveal the differences between zeolite and vanadium based SCR catalysts.

1 High precision high pressure diesel common rail fuel injection systems play a key role in emission control, fuel consumption and driving performance. Deposits have been observed on internal injector components, for example in the armature assembly, in the slots of the piston and on the nozzle needle. The brownish to colourless deposits can adversely impact driveability and result in non-compliance with the Euro 4 or Euro 5 emission limits. The deposits have been extensively studied to understand their composition and their formation mechanism. Due to the location of these deposits, the influence of combustion gas can be completely ruled out. In fact, their formation can be explained by interactions of certain diesel fuel additives, including di- and mono-fatty acids. This paper describes the methodology used and the data generated that support the proposed mechanisms. Moreover, approaches to avoid such interactions are discussed.

After-treatment systems (ATS) consisting of new catalyst technologies and particulate filters will be necessary to meet increasingly stringent global regulations limiting particulate matter (PM) and NOx emissions from heavy duty and light duty diesel vehicles. Fuels and lubes contain elements such as sulfur, phosphorus and ash-forming metals that can adversely impact the efficiency and durability of these systems. Investigations of the impact of lubricant formulation on the transfer of ash-forming elements to diesel particulate filters (DPF) and transfer of sulfur to NOx storage catalysts were conducted using passenger car diesel engine technology. It was observed that for ATS configurations with catalyst(s) upstream of the DPF, transfer of ash-forming elements to the DPF was significantly lower than expected on the basis of oil consumption and lube composition. Sulfur transfer strongly correlated with oil consumption and lubricant sulfur content.

High vacuum purge enhances the performance of an automotive vapor canister by increasing working capacity and decreasing Diurnal Breathing Loss (DBL) emissions. These improvements are significant because high vacuum purge can potentially be adapted for use in an automotive evaporative emissions system. These benefits were demonstrated by conducting multiple aging cycles at ambient, low, medium, and high vacuum levels. Effects on gasoline working capacity, butane capacity, accumulated hydrocarbon heel, and DBL performance were then compared and discussed.

To meet future emission levels the industry is trying to reduce tailpipe emissions by both, engine measures and the development of novel aftertreatment concepts. The present study focuses on a joint development of aftertreatment concepts for gasoline engines that are optimized in terms of the exhaust system design, the catalyst technology and the system costs. The best performing system contains a close-coupled catalyst double brick arrangement using a new high thermal stable catalyst technology with low precious metal loading. This system also shows an increased tolerance against catalyst poisoning by engine oil.

This paper describes the results of a joint development program focussing on the introduction of the new generation of Pt/Rh-technology for current and future emission standards as a cost effective alternative to the in serial Pd/Rh based exhaust gas concepts. In the initial phase of the program combinations of Pd- and Pt-based three-way catalyst technologies were evaluated on vehicles equipped with a 8 cylinder engine. One goal in this portion of the study was to achieve technical equivalence between a viable Pd-based technology and the new Pt/Rh technology in the underfloor position at lower precious metal loading. A combination of a close-coupled Pd/Rh technology and the new Pt/Rh in the underfloor position was able to meet the emission targets at significant lower costs of the system after a catalyst aging that resembles more than 100.000 km of vehicle German highway driving.

The present paper concentrates on the option of catalytic autothermal reforming of gasoline for fuel cell applications. Major parameters of this process are the “Steam to Carbon Ratio” S/C and the air to fuel ratio λ. Computations assuming thermodynamic equilibrium in the autothermal reactor outlet (ATR) were carried out to attain information about their proper choice, as failure in adjusting the parameters within narrow limits has severe consequences on the reforming process. In order to quantify velocity distribution just ahead the catalyst and to evaluate mixing uniformity we designed an ATR featuring an optical access: Thus flow visualization using PIV (Particle Image Velocimetry) and LIF (Laser Induced Fluorescence) technique is possible. Preliminary PIV-results are presented and compared with CFD computations (Computational Fluid D ynamics).

The study presented in this paper focuses on measures to minimize exhaust gas emissions to meet SULEV targets on a V6 engine by using a cost efficient system configuration. The study consists of three parts. A) In the first stage, the influence of engine management both on raw emissions and catalyst light off performance was optimized. B) Afterwards, the predefined high cell density catalyst system was tested on an engine test bench. In this stage, thermal data and engine out emissions were used for modeling and prediction of light-off performance for further optimized catalyst concepts. C) In the final stage of the program, the emission performance of the test matrix, including high cell density as well as multifunctional single substrate systems, are studied during the FTP cycle. The presented results show the approach to achieve SULEV emission compliance with innovative engine control strategies in combination with a cost effective metallic catalyst design.

The influence of adsorption and desorption processes on the non-thermal plasma enhanced catalytic reduction of NOx on NaZSM5- and Al2O3-based lean-NOx catalysts (Pt-NH4ZSM5, Cu-NaZSM5, Fe-NaZSM5, Pt-Al2O3, Pd-Al2O3, CuO-Al2O3, Ag-Al2O3) was investigated by temperature programmed reaction experiments in the temperature range from 100 °C to 600 °C. Dodecane was used as a reducing agent. Strong HC adsorption- and desorption effects were observed on the zeolite catalysts, which were not influenced by plasma-pretreatment. Adsorption of NO2 and desorption of NO occurred on Al2O3-based catalysts. By plasma-pretreatment adsorption of NO2 was induced at low temperatures. NOx-reduction rates of the catalysts Cu-NaZSM5, Fe-NaZSM5, and the Ag-Al2O3 were increased substantially by plasma-pretreatment. Both plasma-induced and catalytic oxidation of HCs were limiting factors of the NOx-reduction obtained on these catalysts.

The Bosch Common Rail Fuel Injection System with the new technologies developed for the Duramax 6600 engine offer numerous performance advantages including exhaust emissions control and noise. The layout of the fuel system components and electrical parts is specifically designed to control fuel injection characteristics. The new injector and nozzle technology was integrated to achieve the required system performance. The new 1600bar fuel pump is also a prerequisite for required system performance.

The tightening of Heavy Duty Diesel (HDD) emissions legislation throughout the world is leading to the development of emission control devices to enable HDD engines to meet the new standards. NOx and Particulate Matter (PM) are the key pollutants which these emission control systems need to address. Diesel Particulate Filters (DPFs) are already in use in significant numbers to control PM emissions from HDD vehicles, and Selective Catalytic Reduction (SCR) is a very promising technology to control NOx emissions. This paper describes the development and performance of the Compact SCR-Trap system - a pollution control device comprising a DPF-based system (the Continuously Regenerating Trap system) upstream of an SCR system. The system has been designed to be as easy to package as possible, by minimising the total volume of the system and by incorporating the SCR catalysts on annular substrates placed around the outside of the DPF-based system.

The launching of direct injection gasoline engines is currently one of the major challenges for the automotive industry in the European Union. Besides its potential for a notable reduction of fuel consumption, the engine with direct gasoline injection also offers increased power during stoichiometric and stratified operation. These advantages will most probably lead to a significant market potential of the direct injection concept in the near future. In order to meet the increasingly more stringent European emission levels (EURO IV), new strategies for the exhaust gas aftertreatment are required. The most promising technique developed in recent years, especially for NOx conversion in lean exhaust gases, is the so-called NOx storage catalyst.

Meeting current exhaust emission standards requires rapid catalyst light-off. Closed-coupled catalysts are commonly used to reduce light-off time by minimizing exhaust heat loss between the engine and catalyst. However, this exhaust gas system design leads to a coupling of catalyst heating and engine operation. An engine-independent exhaust gas aftertreatment can be realized by combining a burner heated catalyst system (BHC) with an underfloor catalyst located far away from the engine. This paper describes some basic characteristics of such a BHC system and the results of fitting this system into a Volkswagen Touareg where a single catalyst was located about 1.8 m downstream of the engine. Nevertheless, it was possible to reach about 50% of the current European emission standard EU 4 without additional fuel consumption caused by the BHC system.

Novel Combustion technologies and strategies show high potential in reducing the fuel consumption of gasoline spark ignition (SI) engines. In this paper, a comparison between various gasoline combustion concepts at two representative engine operating points is shown. Advantages of the combustion concepts are analyzed using thermodynamic split of losses method. In this paper, a tool for thermodynamic assessment (Split of Losses) of conventional and new operating strategies of SI engine and its derivatives is used. Technologies, like variable valve actuation and/or gasoline direct injection, allow new strategies to run the SI engine unthrottled with early inlet valve closing (SI-VVA) combined with high EGR, charge stratification (SI-STRAT) and controlled auto ignition (CAI), also known as gasoline homogeneous charge compression ignition (HCCI). These diverse combustion concepts show thermodynamic gains that stem from several, often different sources.

In this article model-based controller design techniques are investigated for the transient operation of a common-rail diesel engine in order to optimize driveability and to reduce soot emissions. The computer-aided design has benefits in reducing controller calibration time. This paper presents a nonlinear control concept for the coordinated control of the exhaust gas recirculation (EGR) valve and the variable geometry turbocharger (VGT) in a common-rail diesel engine. The overall controller structure is set up to regulate the total cylinder air-charge with a desired fresh air-charge amount by means of controlling the intake manifold pressure and estimating the fresh air-charge inducted into the cylinders. During varying engine operating conditions the two control loops are coordinated by a compensation of the EGR valve action through the VGT controller.