Search Results

U.S. federal vehicle emission standards effective in 2007 require tight control of NOx and hydrocarbon emissions. For light-duty vehicles, the current standard of Tier 2 Bin 5 is about 0.07 g/mi NOx and 0.09 g/mi NMOG (non-methane organic gases) at 120,000 mi. However, the proposed future standard is 0.03 g/mi for NMOG + NOx (~SULEV30) at 150,000 mi. There is a significant improvement needed in catalyst system efficiencies for diesel vehicles to achieve the future standard, mainly during cold start. In this study, a less than 6000 lbs diesel truck equipped with an advanced urea Selective Catalytic Reduction (SCR) system was used to pursue lower tailpipe emissions with an emphasis on vehicle calibration and catalyst package. The calibration was tuned by optimizing exhaust gas recirculation (EGR) fuel injection and cold start strategy to generate desirable engine-out emissions balanced with reasonable temperatures.

Alkali and alkaline earth metal impurities found in diesel fuels are potential poisons for diesel exhaust catalysts. Using an accelerated aging procedure, a set of production exhaust systems from a 2011 Ford F250 equipped with a 6.7L diesel engine have been aged to an equivalent of 150,000 miles of thermal aging and metal exposure. These exhaust systems included a diesel oxidation catalyst (DOC), selective catalytic reduction (SCR) catalyst, and diesel particulate filter (DPF). Four separate exhaust systems were aged, each with a different fuel: ULSD containing no measureable metals, B20 containing sodium, B20 containing potassium and B20 containing calcium. Metals levels were selected to simulate the maximum allowable levels in B100 according to the ASTM D6751 standard. Analysis of the aged catalysts included Federal Test Procedure emissions testing with the systems installed on a Ford F250 pickup, bench flow reactor testing of catalyst cores, and electron probe microanalysis (EPMA).

A great deal of current automotive engineering effort involves the development of three-way catalyst-based emission control systems that seek to minimize fuel consumption while simultaneously meeting stringent exhaust emission standards. Mitigation of emissions is enhanced in a three-way catalyst system when the system air-fuel ratio (A/F) is in proximity to ideal burning or stoichiometry. This paper is concerned with extending methods used for determining engine calibrations to closed-loop systems with three-way catalysts. The paper presents a simulation model that employs experimentally obtained data to characterize the A/F control loop.

In-line hydrocarbon (HC) traps are not widely used to reduce HC emissions due to their limited durability, high platinum group metal (PGM) concentrations, complicated processing, and insufficient hydrocarbon (HC) retention temperatures required for efficient conversion by the three-way catalyst component. New trapping materials and system architectures were developed utilizing an engine dynamometer test equipped with dual Fourier Transform Infrared (FTIR) spectrometers for tracking the adsorption and desorption of various HC species during the light-off period. Parallel laboratory reactor studies were conducted which show that the new HC trap formulations extend the traditional adsorption processes (i.e., based on physic-sorption and/or adsorption at acid sites) to chemical reaction mechanisms resulting in oligomerized, dehydro-cyclization, and partial coke formation.

Because of its cleanness and renewability, biodiesel has a great potential as the alternative of diesel fuel to confront with the increasing energy crisis and environment pollution. In this study, diesel oxidation catalyst (DOC) was used to reduce the typical regulated emission and particulate emission. The combined method of fuel design concept with diesel oxidation catalyst was applied in this study. DOC with Pt catalyst was equipped in the engine test bench in this study. The effects of DOC on diesel engine particulate emission fueled with Euro V diesel fuel, biodiesel and ethanol-biodiesel blends were investigated in this study. It was found that DOC seemed have no effects on NOx emission, while it could improve the oxidation reaction from NO to NO2. In the section of particulate emission, DOC could reduce the particulate mass and number concentration, especially in the range of smaller diameter particles. The SOF could be reduced effectively with DOC.