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Biodiesel-fueled engine simulations were performed using the KIVA3v-Release 2 code coupled with Chemkin-II for detailed chemistry. The model incorporates a reduced mechanism that was created from a methyl decanoate/methyl-9-decenoate mechanism developed at the Lawrence Livermore National Laboratory. A combination of Directed Relation Graph, chemical lumping, and limited reaction rate tuning was used to reduce the detailed mechanism from 3299 species and 10806 reactions to 77 species and 209 reactions. The mechanism was validated against its detailed counterpart and predicted accurate ignition delay times over a range of relevant operating conditions. The mechanism was then combined with the ERC PRF mechanism to include n-heptane as an additional fuel component. The biodiesel mechanism was applied in KIVA using a discrete multi-component model with accurate physical properties for the five common components of real biodiesel fuel.

A laser sheet imaging system with Mie-scattering and Laser Induced Fluorescence (LIF) was used to investigate the spray characteristics of gasoline, methanol and ethanol fuels. A range of conditions found in today's gasoline engines were investigated including that observed during engine cold-start. Both a swirl injector and a multi-hole fuel injector were examined for each of the three fuels. A combination of the second harmonic (532 nm) and the fourth harmonic (266 nm) was generated simultaneously using a Nd:YAG laser system to illuminate the spray. The Mie-scattering technique was used to characterize the liquid phase of the spray while the LIF technique was used to detect a combination of liquid and vapor phases. While gasoline naturally fluoresced, the dopant TEA was added to the methanol and ethanol fuels as a fuel tracer. The Mie-scattering and LIF signals were captured simultaneously using a CCD camera along with an image doubler.

The SAE Fuel Cell Vehicle (FCV) Safety Working Group has been addressing FCV safety for over 11 years. In the past couple of years, significant attention has been directed toward a revision to the standard for vehicular hydrogen systems, SAE J2579(1). In addition to streamlining test methodologies for verification of Compressed Hydrogen Storage Systems (CHSSs) as discussed last year,(2) the working group has been considering the effect of vehicle fires, with the major focus on a small or localized fire that could damage the container in the CHSS and allow a burst before the Pressure Relief Device (PRD) can activate and safely vent the compressed hydrogen stored from the container.

This study provides an LCA of coal derived DME vehicle fuel cycle. Two DME production systems were evaluated, one is single DME production system, and the other is DME/IGCC cogeneration (polygeneration) system. The effects of CCS technology on energy use and GHG emissions were analyzed. For single DME production design, WTW total energy use and fossil energy is about 80% larger than that for petroleum diesel production, and increases life-cycle GHG emissions by more 200% relative to petroleum diesel. Results for DME/IGCC production design pathway from displacement method are almost the same with the petroleum diesel pathway. CCS incurs an energy penalty of 7-16%.

As a renewable energy source, the ethanol fuel was employed with a diesel fuel in this study to improve the cylinder charge homogeneity for high load operations, targeting on ultra-low nitrogen oxides (NOx) and smoke emissions. A light-duty diesel engine is configured to adapt intake port fuelling of the ethanol fuel while keeping all other original engine components intact. High load experiments are performed to investigate the combustion control and low emission enabling without sacrificing the high compression ratio (18.2:1). The intake boost, exhaust gas recirculation (EGR) and injection pressure are independently controlled, and thus their effects on combustion and emission characteristics of the high load operation are investigated individually. The low temperature combustion is accomplished at high engine load (16~17 bar IMEP) with regulation compatible NOx and soot emissions.

A fuel cell (FC) powerplant is an electrochemical engine that converts fuel and an oxidant electrochemically into electric energy, water and other chemical byproducts. When hydrogen is used as the fuel, the only products of the electrochemical reactions are water and electric power. Other conventional and advanced powerplants for transportation, such as the internal combustion (IC) engine, the Diesel engine and others, are thermal combustion engines. The theoretical or thermodynamic efficiency of a fuel cell or electrochemical engine is much higher than the thermodynamic efficiency of a heat engine. The practical efficiency of a fuel cell is highest at partial load, whereas the practical efficiency of a heat engine is highest at maximum power. A survey is presented of the different fuel cell types and their characteristics. The proton-exchange-membrane (PEM) fuel cell is shown to be the best available fuel cell for transportation applications.

A mini-dilution tube to measure particulate emissions is described and results obtained in an application are presented. The application selected is a study of fuel effects on stratified charge engine emission and combustion characteristics. The mini-dilution tube was developed to provide a capability for particulate measurements with dynamometer engines. The device has been demonstrated to yield particulate mass results agreeing to within 10 percent of those with a full scale tunnel in steady state tests with diesel powered vehicles. A PROCO engine modified by incorporation of Torch Ignition was used in the study. Fuels were a wide cut gasoline, methanol and Indolene Clear gasoline. The engine was operated at a speed of 1250 rpm with an indicated mean effective pressure of 390 kPa. Spark timing, injection timing, EGR and equivalence ratio were varied.

In-line hydrocarbon (HC) traps are not widely used to reduce HC emissions due to their limited durability, high platinum group metal (PGM) concentrations, complicated processing, and insufficient hydrocarbon (HC) retention temperatures required for efficient conversion by the three-way catalyst component. New trapping materials and system architectures were developed utilizing an engine dynamometer test equipped with dual Fourier Transform Infrared (FTIR) spectrometers for tracking the adsorption and desorption of various HC species during the light-off period. Parallel laboratory reactor studies were conducted which show that the new HC trap formulations extend the traditional adsorption processes (i.e., based on physic-sorption and/or adsorption at acid sites) to chemical reaction mechanisms resulting in oligomerized, dehydro-cyclization, and partial coke formation.

Because of its cleanness and renewability, biodiesel has a great potential as the alternative of diesel fuel to confront with the increasing energy crisis and environment pollution. In this study, diesel oxidation catalyst (DOC) was used to reduce the typical regulated emission and particulate emission. The combined method of fuel design concept with diesel oxidation catalyst was applied in this study. DOC with Pt catalyst was equipped in the engine test bench in this study. The effects of DOC on diesel engine particulate emission fueled with Euro V diesel fuel, biodiesel and ethanol-biodiesel blends were investigated in this study. It was found that DOC seemed have no effects on NOx emission, while it could improve the oxidation reaction from NO to NO2. In the section of particulate emission, DOC could reduce the particulate mass and number concentration, especially in the range of smaller diameter particles. The SOF could be reduced effectively with DOC.

An experimental study was conducted on the combustion and emissions characteristics of duel fuel sequential combustion (DFSC) mode on a single-cylinder engine, applying port injection of n-heptane combined with in-cylinder direct injection of commercial gasoline, ethanol and n-butyl alcohol, respectively. Three-stage combustion, which consists of low- and high-temperature combustion of premixed n-heptane and high temperature combustion of directly injected gasoline-like fuels were observed. The effects of the premixed ratio and overall heating values per cycle on the combustion characteristics and emissions were investigated. The experimental results show that: with the increasing of premixed ratio and overall heating values per-cycle, the ignition timing of the directly injected fuels advances and the maximum pressure and maximum mass-averaged temperature increase.