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To alleviate the shortage of petroleum resources and the air pollution caused by the burning of fossil fuels, the development of renewable fuels has attracted widespread attention. Among the various renewable fuels, ethanol can be produced from biomass and does not require much modification when applied to practical engines, so it has been widely used. However, ethanol fuel has a higher heat of vaporization than gasoline, it is difficult to evaporate and atomize under cold start conditions. Besides, the catalyst has not reached the conversion temperature at this time, resulting in lower conversion efficiency. These factors all lead to higher pollutant emission levels in ethanol-gasoline blends. To solve the above problems, this research used visualization techniques to compare the effects of flash boiling and high-energy ignition technologies on the in-cylinder combustion process and pollutant emission of ethanol-gasoline blends fuel.