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A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.

The objectives of this project were to investigate the corrosivity of condensate in a stoichiometric spark-ignited (SI) engine when running exhaust gas recirculation (EGR) and to determine the effects of sulfur-in-fuel on corrosion. A 2.0 L turbocharged direct-injected SI engine was operated with low-pressure EGR for this study. The engine was instrumented for visual, thermodynamic, and electrochemical analyses to determine the potential for corrosion at locations where condensation was deemed likely in a low-pressure loop EGR (LPL-EGR) engine. The electrochemical analysis was performed using multi-electrode array (MEA) corrosion probes. Condensate was also collected and analyzed. These analyses were performed downstream of both the charge air cooler (CAC) and the EGR cooler. It was found that while conditions existed for sulfuric acid to form with high-sulfur fuel, no sulfuric acid was detected by any of the measurement methods.

This paper describes a hybrid robust nonlinear control approach for modern diesel engines running low temperature combustion and conventional diesel combustion modes. Using alternative combustion modes has become a promising approach to reduce engine emissions. However, due to very different in-cylinder conditions and fueling parameters for different combustion modes, control of engines operating multiple combustion modes is very challenging. It becomes difficult for conventional calibration / mapping based approaches to produce satisfactory results in terms of engine torque responses and emissions. Advanced control techniques are then demanded to accomplish the tasks. An innovative hybrid control system is designed to track different key engine operating variables at different combustion modes as well as avoid singularity which is inherent for turbocharged diesel engines running multiple combustion modes.

Atmospheric corrosion of steels, aluminum alloys, and Al-clad aluminum alloys is a problem for many civil engineering structures, commercial and military vehicles, and aircraft. Paint is usually the primary means to prevent the corrosion of steel bridge components, automobiles, trucks, and aircraft. Under ideal conditions, the coating provides a continuous layer that is impervious to moisture. At present, maintenance cycles for commercial and military aircraft and ground vehicles, as well as engineered structures, is based on experience and appearance rather than a quantitative determination of coating integrity. To improve the maintenance process and reduce costs, sensors are often used to monitor corrosion. The present suite of sensors designed to detect corrosion and marketed to predict the lifetime of the engineered components, however, are not useful for determining the condition of the protective paint coatings.

The measurement of piston temperature in a reciprocating engine has historically been a very time-consuming and expensive process. Several conditions exist in an engine that measurement equipment must be protected against. Acceleration forces near 2000 G's occur at TDC in automotive engines at rated speed. Operating temperatures inside the crankcase can range to near 150°C. To allow complete mapping of piston temperature, several measuring locations are required in the piston and data must be obtained at various engine operating conditions. Southwest Research Institute (SwRI) has developed a telemetry-based system that withstands the harsh environments mentioned above. The device is attached to the underside of a piston and temperature data is transmitted to a receiving antenna in the engine crankcase. The key element of this device is a tiny power generator which utilizes the reciprocating motion of the piston to generate electricity thus allowing the transmitter to be self-powered.

Tests were conducted on a variety of commercially available spark plugs to determine the influence of igniter design on initial kernel formation and overall performance. Flame kernel formation was investigated using high-speed schlieren visualization. The flame growth rate was quantified using the area of the burned gas region. The results showed that kernel growth rate was heavily influenced by electrode geometry and configuration. The igniters were also tested in a bomb calorimeter to determine the levels of supplied and delivered energy. The typical ratio of supplied to delivered energy was 20% and igniters with a higher internal resistance delivered more energy and had faster kernel formation rates. The exception was plugs with large amounts of conductive mass near the electrodes, which had very slow kernel formation rates despite relatively high delivered energy levels.

The optical spark plug probe and ionization head gasket probe developed at Sandia Laboratories were applied to one cylinder of a production multicylinder automotive gasoline engine. The purpose of this application is to eventually study combustion phenomena leading to high emissions under cold start and cold idle conditions. As a first step in studying cold start combustion and emissions issues, diagnostic instrumentation was simultaneously applied to a production engine under steady state idle, road load and an intermediate load-speed condition. The preliminary application of such instrumentation is the subject of the present paper. The spark plug probe was redesigned for ease of use in production engines and to provide a more robust design. The two probes were geometrically oriented to obtain radial line-up between the optical windows and ionization probes. Data were taken simultaneously with both probes at the three load-speed conditions mentioned above.

Copper ion exchange procedures were used to prepare zeolite-based catalysts for NOx reduction in lean (oxygen-rich) exhaust. Energy dispersive x-ray fluorescence and scanning electron microscopy analyses confirmed the presence of copper in the zeolite matrix. Zeolites were applied onto honeycomb and foam substrates, and evaluated for catalytic NOx reduction efficiency using engine exhaust. Copper-exchanged zeolite catalysts prepared for this study revealed NOx reduction of 95 percent for a period of seven minutes using previously adsorbed exhaust hydrocarbons as the reducing agent. Experiments using ethylene injection to supplement the exhaust suggest long-term and sustained NOx reduction, initially observed at 52 percent. Experimental results and performance comparisons of ZSM-5, mordenite, and Y-type zeolites are discussed. Zeolite catalysts based on Cu-mordenite showed high levels of initial NOx reduction, while results using Cu-ZSM-5 suggested better long-term activity.

Swirl plane Particle Image Velocimetry (PIV) measurements were performed in a single-cylinder optically accessible gasoline direct injection (DISI) engine using a borescope introduced through the spark plug hole. This allowed the use of a contoured piston and the visualization of the flow field in and around the piston bowl. The manifold absolute pressure (MAP) was fixed at 90 kPa and the engine speed was varied in increments of 250 rpm from 750 rpm to 2000 rpm. Images were taken from 270° to 320° bTDC of compression at 10° intervals to study the evolution of the velocity fluctuations. Measurements were performed with and without fuel injection to study its effect on the in-cylinder flow fields. Fuel was injected at 10 MPa and 5 MPa. The 2-D spatial mean velocities of individual flow fields and their decompositions were averaged over 100 cycles and used to investigate the effects of engine speed and image timing on the flow field.

An experimental program was designed to determine friction characteristics between brake pads and metal rotors that could indicate a brake fluid's propensity to cause chatter in wet-brakes. Friction was measured on a bench version of the John Deere wet-brake qualification system. Rotor and pad supports were made very rigid to avoid chatter in the simulator. One type of pad was run on cast-iron and mild steel rotors using two reference oils, one giving unacceptable levels of chatter and the other giving acceptable levels as previously determined in full-scale tests on the Deere system. The outstanding discriminating characteristic was the drop in friction from breakaway of the pad from the rotor. The ratio of the initial drop in the friction coefficient between unacceptable and acceptable oils for all conditions of the testing ranged from 1.7 to 2.0

Excessive interior noise and vibration in propeller driven general aviation aircraft can result in poor pilot communications with ground control personnel and passengers, and, during extended flights, can lead to pilot and passenger fatigue. Noise source/path identification technology applicable to single engine propeller driven aircraft were employed to identify interior noise sources originating from structure-borne engine/propeller vibration, airborne propeller transmission, airborne engine exhaust noise, and engine case radiation. The approach taken was first to conduct a Principal Value Analysis (PVA) of an in-flight noise and vibration database acquired on a single engine aircraft to obtain a correlated data set as viewed by a fixed set of cabin microphones.

SCR-on-filter, or SCRoF, is an emerging technology for different market segments and vehicle applications. The technology enables simultaneous particulate matter trapping and NOX reduction, and provides thermal management and aftertreatment packaging benefits. However, there is little information detailing the lubricant derived exposure effects on functional SCR performance. A study was conducted to evaluate the impact of various oil consumption pathways on a light duty DOC and SCRoF aftertreatment system. This aftertreatment system was aged utilizing an engine test bench modified to enable increased oil consumption rates via three unique oil consumption pathways. The components were characterized for functional SCR performance, ash morphology, and ash deposition characteristics. This included utilizing techniques, such as SEM / EDS, to evaluate the ash structures and quantify the ash elemental composition.

A physics-based spark ignition model was developed and integrated into a commercial CFD code. The model predicted the spark discharge process based on the electrical parameters of the secondary ignition circuit, tracked the spark motion as it was stretched by in-cylinder gas motion, and determined the resulting energy deposition to the gas. In concert with the existing kinetic solver in the CFD code, the resulting ignition and flame propagation processes were simulated. The model results have been validated against both imaging rig experiments of the spark in moving air and against engine experimental data. The model was able to replicate the key features of the spark and to capture the cyclic variability of high-dilution combustion when multiple engine cycles were simulated.

The Department of Transportation (DOT) National Highway Traffic Safety Administration (NHTSA) awarded a contract to Southwest Research Institute (SwRI) to conduct research and testing in the interest of motorcoach fire safety. The goal of this program was to develop and validate procedures and metrics to evaluate current and future detection, suppression, and exterior fire-hardening technologies that prevent or delay fire penetration into the passenger compartment of a motorcoach - in order to increase passenger evacuation time. The program was initiated with a literature review and characterization of the thermal environment of motorcoach fires and survey of engine compartments, firewalls, and wheel wells of motorcoaches currently in North American service. These characterizations assisted in the development of test methods and identification of the metrics for analysis. Test fixtures were designed and fabricated to simulate a representative engine compartment and wheel well.

This project’s objective was to generate experimental data to evaluate the impact of metals doped B20 on diesel particle filter (DPF) ash loading and performance compared to that of conventional petrodiesel. The effect of metals doped B20 vs. conventional diesel on a DPF was quantified in a laboratory controlled accelerated ash loading study. The ash loading was conducted on two DPFs – one using ULSD fuel and the other on B20 containing metals dopants equivalent to 4 ppm B100 total metals. Engine oil consumption and B20 metals levels were accelerated by a factor of 5, with DPFs loaded to 30 g/L of ash. Details of the ash loading experiment and on-engine DPF performance evaluations are presented in the companion paper (Part I). The DPFs were cleaned, and ash samples were taken from the cleaned material. X-ray Fluorescence (XRF), X-Ray Photoelectron Spectroscopy (XPS) and X-Ray Diffraction (XRD) were conducted on the ash samples.