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SCR Deactivation Study for OBD Applications

2012-06-18
Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.
Journal Article

Multi-Vehicle Evaluation of Gasoline Additive Packages: A Fourth Generation Protocol for the Assessment of Intake System Deposit Removal

2009-11-02
2009-01-2635
Building on two decades of expertise, a fourth generation fleet test protocol is presented for assessing the response of engine performance to gasoline additive treatment. In this case, the ability of additives to remove pre-existing deposit from the intake systems of port fuel injected vehicles has been examined. The protocol is capable of identifying real benefits under realistic market conditions, isolating fuel performance from other effects thereby allowing a direct comparison between different fuels. It is cost efficient and robust to unplanned incidents. The new protocol has been applied to the development of a candidate fuel additive package for the North American market. A vehicle fleet of 5 quadruplets (5 sets of 4 matched vehicles, each set of a different model) was tested twice, assessing the intake valve clean-up performance of 3 test fuels relative to a control fuel.
Journal Article

Feasibility of Using Full Synthetic Low Viscosity Engine Oil at High Ambient Temperatures in Military Vehicles

2010-10-25
2010-01-2176
The US Army is currently assessing the feasibility and defining the requirements of a Single Common Powertrain Lubricant (SCPL). This new lubricant would consist of an all-season (arctic to desert), fuel-efficient, multifunctional powertrain fluid with extended drain capabilities. As a developmental starting point, diesel engine testing has been conducted using the current MIL-PRF-46167D arctic engine oil at high temperature conditions representative of desert operation. Testing has been completed using three high density military engines: the General Engine Products 6.5L(T) engine, the Caterpillar C7, and the Detroit Diesel Series 60. Tests were conducted following two standard military testing cycles; the 210 hr Tactical Wheeled Vehicle Cycle, and the 400 hr NATO Hardware Endurance Cycle. Modifications were made to both testing procedures to more closely replicate the operation of the engine in desert-like conditions.
Technical Paper

Development of a Novel Dynamically Loaded Journal Bearing Test Rig

2021-09-21
2021-01-1218
In this work, a dynamically loaded hydrodynamic journal bearing test rig is developed and introduced. The rig is a novel design, using a hydraulic actuator with fast acting spool valves to apply load to a connecting rod. This force is transmitted through the connecting rod to the large end bearing which is mounted on a spinning shaft. The hydraulic actuator allows for fully variable control and can be used to apply either static load in compression or tension, or dynamic loading to simulate engine operation. A variable speed electric motor controls shaft speed and is synchronized to the hydraulic actuator to accurately simulate loading to represent all four engine strokes. A high precision torque meter enables direct measurements of friction torque, while shaft position is measured via a high precision encoder.
Technical Paper

Combination of Mixed Metal Oxides with Cu-Zeolite for Enhanced Soot Oxidation on an SCRoF

2021-09-05
2021-24-0071
A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.
Journal Article

Extension of Analytical Methods for Detailed Characterization of Advanced Combustion Engine Emissions

2016-10-17
2016-01-2330
Advanced combustion strategies used to improve efficiency, emissions, and performance in internal combustion engines (IC) alter the chemical composition of engine-out emissions. The characterization of exhaust chemistry from advanced IC engines requires an analytical system capable of measuring a wide range of compounds. For many years, the widely accepted Coordinating Research Council (CRC) Auto/Oil procedure[1,2] has been used to quantify hydrocarbon compounds between C1 and C12 from dilute engine exhaust in Tedlar polyvinyl fluoride (PVF) bags. Hydrocarbons greater than C12+ present the greatest challenge for identification in diesel exhaust. Above C12, PVF bags risk losing the higher molecular weight compounds due to adsorption to the walls of the bag or by condensation of the heavier compounds. This paper describes two specialized exhaust gas sampling and analytical systems capable of analyzing the mid-range (C10 - C24) and the high range (C24+) hydrocarbon in exhaust.
Journal Article

Understanding the Octane Appetite of Modern Vehicles

2016-04-05
2016-01-0834
Octane appetite of modern engines has changed as engine designs have evolved to meet performance, emissions, fuel economy and other demands. The octane appetite of seven modern vehicles was studied in accordance with the octane index equation OI=RON-KS, where K is an operating condition specific constant and S is the fuel sensitivity (RONMON). Engines with a displacement of 2.0L and below and different combinations of boosting, fuel injection, and compression ratios were tested using a decorrelated RONMON matrix of eight fuels. Power and acceleration performance were used to determine the K values for corresponding operating points. Previous studies have shown that vehicles manufactured up to 20 years ago mostly exhibited negative K values and the fuels with higher RON and higher sensitivity tended to perform better.
Journal Article

Development of a Solid Exhaust Particle Number Measurement System Using a Catalytic Stripper Technology

2011-04-12
2011-01-0635
A solid particle number measurement system (SPNMS) was developed using a catalytic stripper (CS) technology instead of an evaporation tube (ET). The ET is used in commercially available systems, compliant with the Particle Measurement Program (PMP) protocol developed for European Union (EU) solid particle number regulations. The catalytic stripper consists of a small core of a diesel exhaust oxidation catalyst. The SPNMS/CS met all performance requirements under the PMP protocol. It showed a much better performance in removing large volatile tetracontane particles down to a size well below the PMP lower cut-size of 23 nm, compared to a SPNMS equipped with an ET instead of a CS. The SPNMS/CS also showed a similar performance to a commercially available system when used on a gasoline direct injection (GDI) engine exhaust.
Technical Paper

Evaluation of Possible Methanol Fuel Additives for Reducing Engine Wear and/or Corrosion

1990-10-01
902153
The use of fuel additives is one possible approach to reduce wear and corrosion in methanol fueled automobile engines. One hundred and six compounds added to M100 fuel in modest concentrations (1%) were tested in a Ball on Cylinder Machine (BOCM) for their ability to improve lubricity. The most promising candidates were then tested in an engine using a modified ASTM Sequence V-D wear screening test. Additive performance was measured by comparing the buildup of wear metals in the oil to that obtained from an engine fueled with neat M100. The BOCM method of evaluating the additive candidates proved inadequate in predicting abrasive engine wear under the test conditions utilized for this research program.
Technical Paper

A Regenerative Active Suspension System

1991-02-01
910659
Active automotive suspension systems have been under development for a number of years with recent introductions of various versions. A suspension system can be considered “active” when an outside power source is used to alter its characteristics, and these systems can be placed into one of three (3) different categories: semi-active damping, fully active, and low frequency active. A regenerative pump concept can minimize the power requirement for the low frequency active system. It utilizes four (4) independent variable displacement pump/motor combinations on a common shaft to actuate each individual suspension unit. This paper overviews the system configuration, describes the power and energy-saving features of the system, and discusses possible pump configurations and control strategies.
Journal Article

Scuderi Split Cycle Fast Acting Valvetrain: Architecture and Development

2011-04-12
2011-01-0404
The Scuderi internal combustion engine is characterized by a split cycle that divides the four strokes of a conventional combustion cycle over two paired cylinders, one intake/compression cylinder and one power/exhaust cylinder, connected by a crossover port. This split cycle also has an additional high pressure “crossover” gas transfer phase versus the conventional 4-stroke cycle, during which the charge air is moved from the first to the second cylinder. The intake/compression, power/exhaust and crossover events are repeated every revolution, i.e. over two cycles, with a small phase angle between the two cylinders. The separate cylinders enable opportunities for improved combustion and the possibility for pneumatic hybridization of the engine. This paper describes the technical challenges posed by the actuation of the crossover valves in the Scuderi Split Cycle research engine.
Journal Article

Visual, Thermodynamic, and Electrochemical Analysis of Condensate in a Stoichiometric Spark-Ignited EGR Engine

2018-04-03
2018-01-1406
The objectives of this project were to investigate the corrosivity of condensate in a stoichiometric spark-ignited (SI) engine when running exhaust gas recirculation (EGR) and to determine the effects of sulfur-in-fuel on corrosion. A 2.0 L turbocharged direct-injected SI engine was operated with low-pressure EGR for this study. The engine was instrumented for visual, thermodynamic, and electrochemical analyses to determine the potential for corrosion at locations where condensation was deemed likely in a low-pressure loop EGR (LPL-EGR) engine. The electrochemical analysis was performed using multi-electrode array (MEA) corrosion probes. Condensate was also collected and analyzed. These analyses were performed downstream of both the charge air cooler (CAC) and the EGR cooler. It was found that while conditions existed for sulfuric acid to form with high-sulfur fuel, no sulfuric acid was detected by any of the measurement methods.
Technical Paper

A Laboratory-Scale Test to Predict Intake Valve Deposits

1997-10-01
972838
The performance of modern spark ignition engines with electronically controlled fuel injection systems may be adversely affected by formation of deposits around the intake valve. The rate of deposit formation is sensitive to fuel composition and boiling point distribution, as well as engine design and operating conditions. Deposit control additives are available, and full-scale engine and vehicle tests have been developed to rate fuel deposition characteristics. However, the expense associated with full-scale testing, combined with the many variables affecting repeatability, create a need for a well controlled laboratory-scale bench test. This paper describes the development of both the test apparatus and methodology to accurately reproduce the conditions present at the intake valve of an operating engine. Procedures were developed to simulate both a “keep clean” sequence, with neat or additized fuel, and also a “clean-up” sequence, using fuel that contains a deposit control additive.
Technical Paper

Filtration Requirements and Evaluation Procedure for a Rotary Injection Fuel Pump

1997-10-01
972872
A cooperative research and development program was organized to determine the critical particle size of abrasive debris that will cause significant wear in rotary injection fuel pumps. Various double-cut test dusts ranging from 0-5 to 10-20 μm were evaluated to determine which caused the pumps to fail. With the exception of the 0-5-μm test dust, all other test dust ranges evaluated caused failure in the rotary injection pumps. After preliminary testing, it was agreed that the 4-8-μm test dust would be used for further testing. Analysis revealed that the critical particle size causing significant wear is 6-7 μm. This is a smaller abrasive particle size than reported in previously published literature. A rotary injection pump evaluation methodology was developed. During actual operation, the fuel injection process creates a shock wave that propagates back up the fuel line to the fuel filter.
Technical Paper

Monitoring of Ring Face, Ring Side and Liner Wear in a Mack T-10 Test, using Surface Layer Activation

2007-10-29
2007-01-4002
The API has established lubricant specifications, which include standard tests for ring and liner wear. The Mack T-10 is one such test, performed on a prototype engine with Exhaust Gas Recirculation (EGR). At EOT, the liner wear is measured by profilometry, while the ring wear is measured by weight loss. It was decided to monitor the wear of the rings and liners during a full-length T10 test in order to observe the evolution of the wears and wear rates over the course of the test, by using the Surface Layer Activation (SLA) and Bulk Activation (BA) techniques. Three different radioisotopes were created, one in the liners at the turnaround zone, one in the chromium-containing coating on the ring faces, and one in the iron bulk of the rings. This enabled us to observe the wear characteristics of these three components separately. In particular, we were able to separate the face and side ring wears, which cannot be done with simple weight-loss measurements.
Technical Paper

High-Pressure Injection Fuel System Wear Study

1998-02-23
980869
The critical particle size for a high-pressure injection system was determined. Various double-cut test dusts ranging from 0 to 5 μm to 10 to 20 μm were evaluated to determine which test dust caused the high-pressure system to fail. With the exception of the 0- to 5-μm test dust, all test dust ranges caused failure in the high-pressure injection system. Analysis of these evaluations revealed that the critical particle size, in initiating significant abrasive wear, is 6 to 7 μm. Wear curve formulas were generated for each evaluation. A formula was derived that allows the user to determine if the fuel filter effluent will cause harmful damage to the fuel system based on the number of 5-, 10-, and 15-μm particles per milliliter present. A methodology was developed to evaluate fuel filter performance as related to engine operating conditions. The abrasive methodology can evaluate online filter efficiency and associated wear in a high-pressure injection system.
Technical Paper

The 1989 Formula SAE Student Design Competition

1990-02-01
900840
Forty-five cars were entered from 37 universities across the U.S. and Canada in the ninth annual Formula SAE Student Design Competition held on May 25, 26 and 27 at the University of Texas at San Antonio (UTSA). Thirty-six cars from 31 schools actually competed, but only 22 cars finished. The event included many firsts in Formula SAE. The SAE South Texas Section set a precedent by co-hosting the competition with the UTSA. The GM Sunraycer display and demonstration exhibited high technology and corporate support of Formula SAE. Total award funds (from various sponsors) exceeded those of previous events. New awards were given by new sponsors in 1989.
Technical Paper

Fuel Economy Benefits of Electric and Hydraulic Off Engine Accessories

2007-04-16
2007-01-0268
This paper will describe the fuel economy benefits that can be obtained when traditionally engine-driven accessories such as water pumps, oil pumps, power steering pumps, radiator cooling fans and air conditioning compressors are decoupled from the engine and are remotely driven and controlled. Simulation results for different vehicle configurations such as heavy duty trucks operated over urban and highway driving cycles and light duty vehicles such as mini vans will be presented. These results will quantify the heavy dependence of fuel economy benefits associated with different types of driving cycles.
Technical Paper

Characteristics of a Small Engine Equipped with an Electromagnetic Valve Actuation System

1998-08-11
981908
An electromagnetic valve actuation (EVA) system was developed and applied to a Kohler Command Series engine. Engine development and testing was conducted for the purpose of evaluating the performance of the EVA-equipped engine, running on natural gas, in an engine-test laboratory environment. As part of this effort, a personal computer-based engine control system, which managed the fueling, ignition, throttling, and intake/exhaust valve control functions, was developed. The evaluation included an investigation into increasing engine power output and full load efficiency, as well as increased part load efficiency. Techniques including optimized valve events as a function of operating condition, and throttleless operation using early and late intake valve closing are presented. Engine simulation results are compared with actual engine data and presented in this paper.
Technical Paper

Lower Explosion Limits and Compositions of Middle Distillate Fuel Vapors

1998-10-19
982485
Lower explosion limits (LEL) and the chemical compositions of JP-8, Jet A and JP-5 fuel vapors were determined in a sealed combustion vessel equipped with a spark igniter, a gas-sampling probe, and sensors to measure pressure rise and fuel temperature. Ignition was detected by pressure rise in the vessel. Pressure rises up to 60 psig were observed near the flash points of the test fuels. The fuel vapors in the vessel ignited from as much as 11°F below flash-point measurements. Detailed hydrocarbon speciation of the fuel vapors was performed using high-resolution gas chromatography. Over 300 hydrocarbons were detected in the vapors phase. The average molecular weight, hydrogen to carbon ratio, and LEL of the fuel vapors were determined from the concentration measurements. The jet fuel vapors had molecular weights ranging from 114 to 132, hydrogen to carbon ratios of approximately 1.93, and LELs comparable to pure hydrocarbons of similar molecular weight.
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